1. Direct fabrication of ZrC/ZrSi composite fibers from ZrSiO4/C precursors in molten chlorides by electrochemical method
- Author
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Wen Ma, Hongxia Liu, Yu Bai, Qian Xu, and Weihao Song
- Subjects
010302 applied physics ,Electrolysis ,Materials science ,Carbonization ,Process Chemistry and Technology ,Composite number ,02 engineering and technology ,engineering.material ,021001 nanoscience & nanotechnology ,01 natural sciences ,Cathode ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,law.invention ,Chemical engineering ,Coating ,law ,Nanofiber ,0103 physical sciences ,Materials Chemistry ,Ceramics and Composites ,engineering ,Fiber ,Molten salt ,0210 nano-technology - Abstract
ZrC/ZrSi composite fibers were directly electro-synthesized from inexpensive and abundantly available ZrSiO4/C precursors in molten CaCl2–NaCl at 850 °C. Electrolysis was conducted at a constant voltage of 2.8 V using a graphite anode and a cathode composed of ZrSiO4/carbon mixture. The reaction mechanism of electro-synthesis process was systematically investigated by examination of partially and fully reduced samples. Results show that as-synthesized nanofiber is composed of ZrSi single crystal core and ZrC outer coating. The mechanism of composite fiber formation is a complex reaction pathway involving decomposition, electro-deoxidation and in situ carbonization. The electrochemical route in molten salt is a new promising method for simple fabrication of Zr-based composite fibers.
- Published
- 2020
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