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Visualization of the oxygen partial pressures was carried out at the surface of a gas diffusion layer (GDL) for the first time together with the upper part of the gas-flow channel of the cathode of a running polymer electrolyte fuel cell (PEFC) using two different oxygen-sensitive luminescent dye films. The visualized distributions of the oxygen partial pressures at the GDL and the upper gas-flow channel during the PEFC operation were very different in a conventional test cell. The change in the distribution of the oxygen partial pressures was observed by changing the oxygen utilization, which should be connected with the reactive locations in the membrane-electrode assembly (MEA). A numerical calculation was carried out to understand the distributions of water and current density inside the MEA. The water distribution inside the MEA was confirmed to strongly affect the distributions of the current density and the oxygen /partial pressure.

During start-up/shut-down processes of a polymer electrolyte fuel cell, platinum particles are lost from the catalyst layer at the cathode due to corrosion of the carbon supports. We simulated the start-up/shut-down cycle by exchanging gases at the anode between hydrogen and air. During the gas exchange, the distribution of oxygen partial pressures at the anode was visualized by our real-time/space visualization system, which clearly showed the location of H2- and O2-rich areas along the gas-flow channel from the inlet to the outlet. The gas exchange rate was found to be much slower than that predicted from the simple replacement and to be correlated to the proton transfer derived from carbon corrosion of the cathode catalyst layer. By the visualization results, it was found that the shut-down process gives more serious effect than the start-up process. After the degradation, the oxygen partial pressure at the cathode was visualized during the cell operation. Oxygen was consumed mainly in the middle of the MEA because the MEA was degraded mainly near the inlet and outlet of reactant gases in the cell.

Luminescent oxygen-sensory polymer-coatings composed of platinum tetrakis(pentafluorophenyl)-porpholactone (PtPL) and -porphyrin (PtPP) with poly(trimethylsilylpropyne) (PMSP) were prepared for visualization of the oxygen partial pressure on two parallel planes or a biplanar surface. PMSP formed a smooth and tough coating as a high oxygen-permeable polymer matrix with a thickness of ca. 2 μm, which homogeneously contained the luminescent dye probe, PtPL or PtPP. Under UV light (395 nm) irradiation, the coatings displayed strong magenta and red luminescence with maximum peaks at 750 and 650 nm ascribed to the PtPL and PtPP, respectively. The luminescence of the two coatings was efficiently quenched by oxygen which allowed the development of engineering curve to analyze the oxygen partial pressure. The luminescence intensities of the two coatings were separately monitored in order to allow the simultaneous measurement of the oxygen partial pressure distribution upon two planar surfaces.