1. The effect of thermal cycling on the fracture toughness of metallic glasses
- Author
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Benjamin Sol Schroers, Rui Yamada, Wojciech Dmowski, Derek Kuldinow, Hui Wang, Jan Schroers, Takeshi Egami, and Jittisa Ketkaew
- Subjects
010302 applied physics ,Amorphous metal ,Materials science ,Polymers and Plastics ,Thermal signature ,Metals and Alloys ,02 engineering and technology ,Temperature cycling ,021001 nanoscience & nanotechnology ,01 natural sciences ,Homogenization (chemistry) ,Electronic, Optical and Magnetic Materials ,Fracture toughness ,0103 physical sciences ,Thermal ,Ceramics and Composites ,Composite material ,0210 nano-technology ,Cycling - Abstract
A wide range of behaviors, including non-monotonic rejuvenation and relaxation, and the ability to qualitatively change the effect by varying the structural state of the glass was observed during thermal cycling of bulk metallic glasses. For this, we considered various bulk metallic glasses, Zr44Ti11Cu10Ni10Be25, Pd43Cu27Ni10P20, Pt57.5Cu14.7Ni5.3P22.5, and La55Al25Ni20, at various fictive temperatures to study the effect of thermal cycling on structure, thermal signature, and fracture toughness. For some BMGs and conditions considered here, thermal cycling results in a looser structure and an increase in fracture toughness. We found that for certain other BMGs and conditions, thermal cycling results in relaxation, reflected in a denser structure, and a decrease in fracture toughness. All these responses are non-monotonic and reveal a pronounced extremum with fracture toughness values of ± 50% of the original value, before approaching a value similar to the original value prior to thermal cycling. Such richness in response to thermal cycling suggests incompleteness of the previous picture where monotonically decreasing local stresses resulting in a homogenization of the structure with increasing cycle number. Our finding suggests that relative comparisons of various contributions including activation barriers for α-relaxation have to be considered which are also constantly changing, to decide if further cycling results in an increase or a decrease in fracture toughness. The fracture toughness’ response to thermal cycling can be correlated with the average atomic structures’ response to thermal cycling, while the thermal response does not exhibit an obvious correlation.
- Published
- 2020