1. Alkyl side-chain dependent self-organization of small molecule and its application in high-performance organic and perovskite solar cells
- Author
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Chang Eun Song, Huyen Tran, Seon-Mi Jin, Eunji Lee, Sora Oh, Hang Ken Lee, Won Suk Shin, Sang-Jin Moon, Jong-Cheol Lee, Sang Kyu Lee, Namsun Yoon, and Nasir Khan
- Subjects
chemistry.chemical_classification ,Materials science ,Fullerene ,Organic solar cell ,Renewable Energy, Sustainability and the Environment ,business.industry ,Doping ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Small molecule ,Effective nuclear charge ,0104 chemical sciences ,Organic semiconductor ,chemistry ,Optoelectronics ,General Materials Science ,Electrical and Electronic Engineering ,0210 nano-technology ,business ,Alkyl ,Perovskite (structure) - Abstract
The molecular self-organization of organic semiconductors, which is mainly determined by the structural design, film processing, and device configuration, is one of the crucial factors for achieving high-performance organic photovoltaics (OPVs) and perovskite solar cells (PvSCs). In this study, we newly synthesized and developed strongly self-organized small molecules via alkyl side-chain engineering. Replacing “H” to “C6H13” on the thienyl group, SM2 showed a well-ordered face-on orientation. Due to favorable self-organization leading to effective charge carrier dynamics, including enhanced charge transfer/transport and suppressed recombination, SM2-based OPVs and PvSCs exhibited improved device performance compared to the devices based on SM1 without an additional hexyl side-chain. The best fullerene-based OPV and planar PvSC with SM2 as a small-molecule donor and as a hole transport layer (HTL) achieved an unprecedentedly high efficiency of 9.38% and 20.56%, in contrast with SM1-based devices showing lower efficiency of 8.70% and 15.37%. Furthermore, the planar PvSCs based on undoped-SM2 HTL exhibited comparable efficiency but provided excellent heat and humidity stability compared with doped spiro-OMeTAD-based devices. These results clearly indicated that SM2 with highly-ordered and favorable self-organization is a promising organic semiconductor for future applications of high-performance organic and inorganic-organic hybrid electronics.
- Published
- 2020