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Your search keyword '"Kooistra, T. Martijn"' showing total 2 results
Start Over Author "Kooistra, T. Martijn" Publisher elsevier bv
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2. Chemical ligand non-innocence in pyridine diimine Rh complexes

Author

Dennis G. H. Hetterscheid, Erik Schwartz, Peter H. M. Budzelaar, Anton W. Gal, Quinten Knijnenburg, T. Martijn Kooistra, Kooistra, T. Martijn, Hetterscheid, Dennis G. H., Schwartz, Erik, Knijnenburg, Quinten, Budzelaar, P. H. M., and Gal, Anton W.

Subjects
Materials Chemistry2506 Metals and Alloys, chemistry.chemical_classification, Pyridine diimine, Ligand, Molecular Materials, chemistry.chemical_element, Photochemistry, Medicinal chemistry, Decomposition, Rhodium, Inorganic Chemistry, chemistry.chemical_compound, chemistry, Pyridine, Materials Chemistry, Reactivity (chemistry), Physical and Theoretical Chemistry, Ligand non-innocence, Cobalt, Alkyl, Diimine
Abstract

Item does not contain fulltext The formation and reactivity of pyridine diimine rhodium(l) alkyl complexes without beta-hydrogens (Me, Bz, CH2SiMe3) is described. In contrast to the corresponding cobalt complexes, the rhodium complexes could not be activated to polymerise ethene. Rh ethyl complexes could not be prepared. Examples of hydrogen transfer to and from the ligand were observed, illustrating the active role the pyridine diimine ligand can play in the reactions of its complexes. Decomposition via loss of free ligand was observed in many cases, indicating that the pyridine diimine ligand is not a very suitable one for Rh-I. (C) 2004 Elsevier B.V. All rights reserved.

Published
2004
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