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Your search keyword '"Kiener, D."' showing total 54 results
Start Over Author "Kiener, D." Publisher elsevier bv
54 results on '"Kiener, D."'

11. Correlation between fracture characteristics and valence electron concentration of sputtered Hf-C-N based thin films

Author

Glechner, T., Lang, S., Hahn, R., Alfreider, M., Moraes, V, Primetzhofer, Daniel, Ramm, J., Kolozsvari, S., Kiener, D., Riedl, H., Glechner, T., Lang, S., Hahn, R., Alfreider, M., Moraes, V, Primetzhofer, Daniel, Ramm, J., Kolozsvari, S., Kiener, D., and Riedl, H.

Abstract

Hard protective coating materials based on transition metal nitrides and carbides typically suffer from limited fracture tolerance. To further tune these properties non-metal alloying - substituting C with N - has been proven favorable for magnetron sputtered Hf-C-N based thin films. A theoretically predicted increase in valence electron concentration (from 8.0 to 9.0 e/f.u. from Hf-C to Hf-N) through nitrogen alloying lead to an increase in fracture toughness (K-IC obtained during in-situ SEM cantilever bending) from 1.89 +/- 0.15 to 2.33 +/- 0.18 MPa.m(1/2) for Hf0.43C0.57 to Hf0.35C0.30N0.35, respectively. The hardness remains close to the super-hard regime with values of 37.8 +/- 2.1 to 39.9 +/- 2.7 GPa for these specific compositions. Already the addition of small amounts of nitrogen, while sputtering a ceramic Hf-C target, leads to a drastic increase of nitrogen on the non-metallic sublattice for fcc single phased structured HfC1-xNx films, where x = N/(C + N). The here obtained results also provide experimental proof for the correlation between fracture characteristics and valence electron concentration.

Published
2020
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15. Interface dominated mechanical properties of ultra-fine grained and nanoporous Au at elevated temperatures

Author

Leitner, A., Maier-Kiener, V., Jeong, J., Abad, M.D., Hosemann, P., Oh, S.H., and Kiener, D.

Subjects
Ultra-fine grained Au, Nanoporous Au, Polymers and Plastics, Deformation mechanisms, Metals and Alloys, Ceramics and Composites, High-temperature deformation, Nanoindentation, Electronic, Optical and Magnetic Materials
Abstract

Modern design and engineering of highly efficient devices and machines demand innovative materials to satisfy requirements such as high strength at low density. The purpose of this study was to oppose the mechanical properties and deformation behavior of ultra-fine grained Au to those of nanoporous Au, to study the influence of different types of interfaces. Microstructural investigations of the foam surrendered a ligament size of ∼100 nm which themselves consist of 70 nm grains in average, while the ultra-fine grained gold features a mean grain size of 325 nm. Nanoindentation lends itself as a convenient technique to obtain material properties at ambient as well as high temperature conditions. In this work, a substantial indentation test series was performed in order to determine hardness, Young's modulus, strain-rate sensitivity and activation volume at room and elevated temperatures up to 300 °C. On account of the small characteristic dimensions, high hardness values were noted for both materials, which rapidly drop at elevated temperature. Additionally, an enhanced strain-rate sensitivity accompanied by low activation volumes was determined at room temperature, which further increased at elevated temperatures. This behavior is associated with thermally activated interactions between dislocations and interfaces. For nanoporous Au, due to the presence of free surfaces, a considerable increase of hardness was observed upon annealing. This can be attributed to a reduced number of mobile dislocations in the material after annealing, as supported by implemented porosity maps on indent cross-sections, showing distinct differences for tests at varying temperature.

Published
2016
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