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Ordovician chitinozoans are as yet inadequately documented from the western Yangtze Platform, South China. Here we present a systematic study on chitinozoans from a Middle–Upper Ordovician succession at Songliang of Qiaojia, northestern Yunnan, southwestern China. Altogether 34 species of 12 genera are identified from the upper Hungshihyen and the Huadan formations. The top of the Hungshihyen Formation yields typical Early and Middle Ordovician forms, for instance, Lagenochitina obeligis and Belonechitina chenjiawuensis, with the latter only known from the lower Darriwilian in South China, thus suggesting an early Darriwilian age for this interval. The chitinozoans recovered from the Huadan Formation include Lagenochitina prussica and Spinachitina fossensis, both are mainly confined in Katian and sometimes ranging into younger strata. This indicates an age younger than the middle to late Darriwilian previously determined for the Huadan Formation. However, conflicts exist in age assignment of the Huadan Formation based on chitinozoan and other evidence, and further work is required.

This study reports four species belonging to two genera of clathrodictyid stromatoporoids from the Sanqushan Formation (Katian, Upper Ordovician), Changshan County, Zhejiang Province, East China: Clathrodictyon cf. mammillatum (Schmidt), C. plicatum Webby and Banks, C. cf. microundulatum Nestor and Labyrinthodictyon cascum (Webby and Morris). Of these, three species (C. cf. mammillatum, C. plicatum and L. cascum) show a wide range of skeletal variation, representing the variation from the normal skeletal phase to abnormal Ecclimadictyon-like crumpled skeletal phase, especially in the axial part of the columnar growth forms. It is uncertain whether the skeletal variation in early clathrodictyids was the result of environmental stress (such as abrupt sediment influxes that often cause growth interruptions of the stromatoporoids) or genetic inheritance. These characteristics suggest that this group had greater environmental tolerance than the earlier labechiids and increased ecological complexity during Late Ordovician by providing a stable, solid and elevated substrate for the other benthic organisms. This may imply that the labechiids and clathrodictyids are quite different groups, probably independently derived during the early evolution of stromatoporoids.

Accumulations of cephalopods in the Late Ordovician (Katian [Ka4]) Troutbeck Siltstone Member of the Ash Gill Mudstone Formation at Skelghyll Beck in the Lake District and in the Keisley Limestone Formation of the Cross Fell Inlier contribute toward an understanding of their respective depositional environments as well as the palaeogeography of the southeastern margins of the Lakesman Terrane. The accumulation present in the Troutbeck Siltstone Member is interpreted as having been deposited in a shallow, near-shore lagoon that supported stromatolite growth. The shore lay to the north of this site. Geopetals infilling cephalopods forming concentrations in the Keisley Limestone Formation indicate that the conchs came to rest on angles of 30–40° to horizontal. The lithologies of the matrix suggest that they were deposited in cavities or fissures from which fine-grained carbonate was either excluded or winnowed away. Both observations accord with hypotheses that the Keisley Limestone Formation represents the remnants of a carbonate mud mound, and facilitate comparison with the contemporaneous Boda mounds of Siljan, Sweden. Comparison with local late Katian – Hirnantian successions indicate that the Keisley mound would have formed a prominent feature on the sea floor, becoming largely buried by argillaceous sediments during the Hirnantian.

The biodiversity changes of trilobites in the middle Yangtze region of South China in the Great Ordovician Biodiversification Event and the end-Ordovician mass extinction have been analysed. The Ordovician trilobites in this region originated in the early Tremadocian and radiated from the late Floian to the early Katian. Two peaks of diversity appeared in the late Dapingian to the early Darriwilian and the early Katian. The extinction occurred in the late Katian, followed by a survival period in the Hirnantian. The Whiterock fauna began to surpass the Ibex fauna during the early Katian and were dominant by the late Katian to the Hirnantian, indicating that Cambrian Evolutionary Fauna was gradually replaced. The study once again confirms the view that the effects of factors such as sea level, climate, oxygen content, nutrient supply, and tectogenesis differ temporally and to different degrees in different regions, resulting in differences in the vertical sequence and horizontal combination of ecosystems, which is the reason for the different evolution patterns of Ordovician trilobites in different regions.

The Ordovician stratigraphy of southern-central Xizang (Tibet) has been revised based on new conodont data recovered from 43 samples in four stratigraphic units and their integration with existing nautiloid and graptolite data. The Histiodella holodentata and Pygodus serra biozones have been identified respectively in the Alai and Jiaqu formations of the Chiatsun Group exposed near Alai village in Nyalam County within the Himalayan terrane, and the Yangtzeplacognathus foliaceus Subbiozone (lower part of the Pygodus serra Biozone) in the Sangqu Formation exposed at the Guyu section within Zayu County in the Lhasa terrane. Recognition of these biozones has increased the precision of correlation of the middle-upper Darriwilian strata in the region. Regional reassessment of the Ordovician stratigraphy permitted by new biostratigraphic data has allowed revised definitions for the Chiatsun and Keerduo groups and the Sangqu and Xainza formations. The Chiatsun Group is defined herein to include three lithologically distinctive formations in descending order, the Jiaqu, the Alai and the Adang formations. The stratigraphic age for the Jiaqu and Alai formations in the type area ranges from the middle Darriwilian (Histiodella holodentata Biozone) to middle Katian (Hamarodus brevirameus Biozone), but the age of the Adang Formation remains less certain.

The Wufeng organic-rich shale is widespread in the Upper Yangtze platform, and it is one of the most advantageous shale gas producers in China. Its deposition commenced with the onset of the Boda warming event in the late Katian and terminated at the Hirnantian glacial maximum. The depositional mechanism of the Wufeng Formation was poorly understood owing to its relatively thin thickness, being interpreted as the result of organic matter (OM) accumulation in a shelf setting under anoxic conditions. This study integrated detailed geochemical analyses based on the core samples from three boreholes which are located in the outer-, middle- and inner-shelf of the Upper Yangtze platform, in order to investigate the depositional environments during the deposition of the Wufeng Formation. Geochemical redox proxies (Mo-EF, U-EF, and V/Cr) and productivity proxies (P, Baxs, Sixs) indicate that the deposition of the Wufeng Formation was associated with four intervals (WF1 to WF4), each characterized by its unique geochemical features related to sea-level fluctuations. Black siliceous mudstones deposited during WF1 and WF2 are relatively organic-lean due to low productivity, less favorable preservation conditions, and terrestrial dilution. Whereas black siliceous mudstone deposited during WF3 and WF4 is organic-rich due to high paleoproductivity and conducive preservation conditions. The geochemical proxies (Cd/Mo, Co x Mn) associated with the modern upwelling settings were replicated in the Wufeng Formation, revealing that the outer-shelf of the Upper Yangtze platform was dominated by persistent upwelling. The upwelling-driven primary productivity is considered as the first-order control for the OM enrichment at the outer-shelf of the Upper Yangtze platform. Seasonal upwelling may influence the middle-shelf of the Upper Yangtze Platform, where both primary productivity and preservation played essential roles in the OM accumulation. In contrast, the OM accumulation at the inner-shelf was fundamentally driven by good preservation conditions.

Upper Ordovician (Katian) to Lower Silurian (Rhuddanian) strata in the Middle–Upper Yangtze Block, South China contain extensive chert beds, although the origin of microcrystalline silica in these cherts is largely unknown. In this study, the mineralogy and structure of chert as well as major, trace, and rare earth elements are used to determine the origin of microcrystalline silica in 29 chert samples from Longmaxi Formation (Rhuddanian) in Baizitian outcrop, west of Kangdian Uplift (KU). Results show that 21 of the 29 chert samples have a biogenic origin, 2 indicate a hydrothermal origin, and 6 show a mixed origin. Cherts from Baizitian outcrop are compared to contemporaneous cherts deposited east of KU. Cherts both east and west of KU are mainly biogenic in origin, which is attributed to high productivity in the paleo-seaway. Hydrothermal microcrystalline silica is relatively uncommon in the Longmaxi Formation across the Middle-Upper Yangtze Block, and only occurs in Baizitian outcrop. Terrigenous influx contributed to chert accumulation both east and west of KU; however, cherts east of KU received much more clastic material than those in Baizitian outcrop. A comparison of chert composition and geochemistry to geological reconstructions of the Middle-Upper Yangtze Block reveal that accumulation of hydrothermal chert is closely linked to tectonic evolution. During the Early Silurian, the Middle-Upper Yangtze Block was in a compressional tectonic regime with limited heat supply, and hence, low hydrothermal circulation; this is manifested in the paucity of hydrothermal microcrystalline silica in cherts east of KU. In contrast, hydrothermal microcrystalline silica in cherts west of KU is interpreted to have formed in an extensional tectonic regime with sufficient heat supply. This research demonstrates that chert source is, in part, tectonic controlled, and chert geochemistry can be used in reconstructing paleoenvironments.

Core samples from the Huaying well, Sichuan Province, have been analyzed for both graptolite biostratigraphy and carbon isotope chemostratigraphy. The result shows a stratigraphic sequence of Lituigraptus convolutus, Stimulograptus sedgwickii and Spirograptus guerichi biozones, and records a strong positive shift of δ13Corg at the base of the Stimulograptus sedgwickii Biozone, which coincides with those from Cornwallis Island (Arctic Canada), Arisaig (Nova Scotia, Canada), and the Barrandian area (Bohemia). Two outcrops were also studied in the Huaying region. The Yanwanggou section shows a continuous, but complicated, stratigraphical sequence, from the upper Katian to the lower–middle Rhuddanian, then a sedimentary hiatus of ∼3.26 Ma, and finally a continuous sequence from the upper Aeronian to the lower Telychian, whereas the Liziya section and the Huaying well exhibit significant hiatus, which lasted from Hirnantian to middle Rhuddanian or early Aeronian times. Therefore, the eastern boundary of the Central Sichuan Oldland during the Ordovician and Silurian transition can be precisely constrained to a narrow area between the Huaying well-Liziya section and the Yanwanggou section, which indicates that the Central Sichuan Oldland was much larger than previously considered. The present data also indicate the existing of a so far unidentified stage of the Kwangsian Orogeny, which resulted in the uplift of some portions of the Yangtze Platform region and the consequent delay of the transgression in those places. The multi-stage hiatus, spanning at least from the upper Katian to middle Aeronian in the study area, resulted from a combined effect of the Hirnantian glacio-eustatic sea-level fall and the regional tectonic activity of the Kwangsian Orogeny.

Hardgrounds from the Upper Ordovician strata of eastern Laurentia exhibit a wide range of morphologies, though the development of their complex surface topographies remains poorly understood. These early lithified seafloors, which can be laterally very extensive, may provide key information about basin dynamics and global ocean fluctuations. Based on spectacular exposures and newly-excavated material, we examined a suite of hardgrounds from the Upper Ordovician (Katian) of southern Ontario and the Cincinnati Arch region and documented the processes of genesis, development, and modification of simple, complex, and block hardgrounds. In this study, we used extensive field work, petrology, and cathodoluminescence to determine the evolution and shaping of hardgrounds as a result of intense submarine erosion and prolonged exposure of these surfaces and reveal a progression from simple to complex hardgrounds and ultimately to isolated cobble- to boulder-sized block hardgrounds. We survey the distribution of hardgrounds in a sequence stratigraphic framework to determine allocyclic controls on hardground development, highlight the important role that mixed siliciclastic-carbonate environments play in promoting the development of heterogeneous hardground topographies, and analyze the effects of high surface reliefs on local depositional and erosional regimes. In addition, we interpret the impact of increasingly abundant complex hardgrounds throughout the Ordovician on hard-substrate community diversification and their contribution to the Great Ordovician Biodiversification Event. We also discuss time-specific aspects of the Late Ordovician that made it a peak interval of hardground proliferation.

Deposition of the organic-rich shales of the Wufeng and lowermost Longmaxi formations (late Katian through Hirnantian) occurred in a relatively stable tectonic setting and commenced at approximately 4.5 Myr prior to the end-Ordovician glacial maximum. These organic-rich shales are important because they provide a continuous sedimentary record of high-frequency eustatic changes associated with ice-sheet expansion and shrinkage. Here, we carried out a high-resolution cyclostratigraphic study of Fe3+ series and associated geochemical analysis of the Wufeng and lowermost Longmaxi shales in order to better understand sea-level cyclicity in the late Katian through Hirnantian ocean. The organic-rich shales deposited during this interval in the EHD1 drill core (Yichang, China) record four major Myr-scale eustatic cycles, which were associated with third-order sea-level fluctuations. Within each of these major cycles, 3–4 minor eustatic cycles corresponding to 405-kyr long eccentricity astronomical cycles were recognized and representing fourth-order eustatic changes. The cyclostratigraphic age of this study is generally in agreement with the radiometric dates in GTS2012, although the duration of the Hirnantian stage is ~0.5 Myr longer than previously thought. This study also infers glacial controls on the depositional environment of the organic-rich shales, as enhanced cooling triggered ice-sheet expansion and concurrent sea-level fall, leading to higher thermohaline circulation intensity and enhanced paleoproductivity through upwelling and terrestrial influx. In contrast, warming intervals led to ice-sheet shrinkage and concurrent deepening characterized by water column stratification and reduced nutrient supply. The results provide evidence in support of continuous continental glaciation in the late Katian through Hirnantian.

A diverse benthic fauna containing exceptionally preserved soft-bodied organisms is described from the new Vaureal Konservat-Lagerstatte from the Upper Ordovician Vaureal Formation (Katian) of Anticosti Island, Canada. These fossils occur as pyritic (or goethitic, if weathered), calcitic aggregates or sediment-filled voids on micritic bedding planes of a marlstone-limestone alternation originated on a shallow tropical carbonate ramp. Many organisms are preserved in association with their traces (e.g. burrows, trails), whose changing shapes indicate increasing cohesiveness of the substrate. Rapid burial (obrution) under dysoxic bottom conditions must have favoured exceptional preservation. Although anatomical details of the organisms are often lacking due to recrystallization, members of different groups of organisms could be interpreted based on their shape and other characteristic features, including those of which represent their oldest fossil record (i.e. Acoelomorpha, Turbellaria, Nemertea, Nematoda), beside Polychaeta, Sipuncula, Ostracoda and other Arthropoda. In parallel with molecular data, which recently have changed the phylogenetic status of some clades, this soft-bodied fauna and their traces not only record their appearance but add to the understanding of their body plan and behaviour. The new Konservat-Lagerstatte provides important information about a diverse benthic community in the Late Ordovician after the Great Ordovician Biodiversification Event (GOBE), and represents a calibration point for comparison across the Late Ordovician mass extinction. Moreover, comparable Fossil-Lagerstatten are probably more common in shallow-marine carbonates than currently known but might have been simply overlooked.

The end-Ordovician mass extinction (EOME) is widely interpreted as consisting of two pulses associated with the onset and demise of the Gondwana glaciation, respectively, with the second pulse eradicating the distinctive, glacially related Hirnantian benthic biota (HBB). A global review of occurrence data of latest Ordovician benthic marine organisms reveals that virtually all warm-water benthic assemblages previously assigned to the HBB comprise two distinct and clearly postglacial faunas, both younger (middle and late Hirnantian, respectively) than the cool-water Hirnantia fauna (latest Katian to early Hirnantian). The newly recognised three Transitional Benthic Faunas (i.e., TBFs 1–3) can be closely tied to graptolite, conodont, and chitinozoan biozonations, the Hirnantian Isotope Carbon Excursion (HICE), and the glaciation, thereby providing an integrated, much higher-resolution timescale for understanding the tempo and nature of the EOME. At this finer resolution, we postulate a more profound impact of the first pulse of the EOME than hitherto envisaged, as evidenced by opportunistic expansion of the Hirnantia fauna globally and the complete absence of metazoan reefs in its immediate aftermath. We also argue, based on high-quality data from well-documented benthic groups in South China (i.e., brachiopods, tabulate and rugose corals, trilobites, and sponges), that the magnitude of the second pulse of the EOME caused by the deglaciation has been overestimated because the two postglacial faunas (i.e., TBFs 2–3) were part of a subsequent recovery phase of marine ecosystems rather than contributing to biodiversity decline. Thus, it is more plausible to reinterpret the EOME as a single-pulse, rapid event that was followed by a prolonged initial recovery intermittently impeded by climatic shocks through the Hirnantian, prior to the onset of a progressive reestablishment of marine ecosystems during the early Silurian (Rhuddanian and Aeronian) associated with an overall amelioration of climatic conditions.

There is no doubt that organic matter plays an important role in shale gas accumulation and storage. Thus, successful evaluation and production strategies of organic-rich shale deposits require an understanding of the range of factors that contribute to the accumulation and preservation of organic matter in these deposits. This paper reports results of a multi-faceted study of two Ordovician–Silurian transition sections of the Upper Yangtze Platform of South China. Organic and inorganic geochemical data are used to reconstruct paleoenvironmental changes across this critical interval of Earth history and to identify those factors that were most important to organic matter accumulation. Deposition of organic-rich shale of the Katian lower Wufeng Formation was favored by rising sea level and diminished clastic sediment content. Black shale of the upper Wufeng preceded Hirnantian glaciation whereas the overlying lower Longmaxi Formation accumulated in association with a post-glacial rise of sea level as well as the peak of Caledonian tectonism. The carbonaceous deposits appear to reflect the combined effects of elevated primary productivity as suggested by Si/Al and Ti/Al ratios, especially in the upper Wufeng, and consequent depletion of water column oxygen (preservation). Consideration of the relationships of redox-sensitive trace element concentrations and total organic carbon content suggest that bottom water conditions fluctuated between anoxic and euxinic during this period, perhaps related to rapid oscillations of sea level. Moreover, the basin appears to have remained connected with the global ocean in spite of Caledonian uplift of bordering areas. Thus, black shale sedimentation on the Upper Yangtze Platform at the Ordovician-Silurian boundary reflects the interplay of climate change and tectonism and their influences on sea level, clastic sediment content, and paleo-productivity.

Integrating phylogenetic biology with paleoecology can provide a valuable context for understanding patterns of community structure and niche partitioning in ancient ecosystems. However, the lack of robust phylogenies for many fossil taxa precludes studies of this nature, particularly among marine invertebrates. Fossil Crinoidea (Echinodermata) comprise an ideal model system for phylogenetic community paleoecology for three reasons: (1) they preserve anatomical features that directly relate to feeding ecology, (2) assemblages of well-preserved specimens represent “ecological snapshots” in time, and (3) recent advances in resolving the crinoid tree of life have produced high-resolution phylogenies for Ordovician lineages. Here, we apply multivariate and phylogenetic comparative methods to investigate patterns of paleocommunity structure, niche partitioning, and ecomorphospace occupation in one of the earliest known complex crinoid paleocommunities, the Brechin Lagerstatte (Upper Ordovician, Katian). Results indicate niche differences among species were determined primarily by characters related to filtration fan morphology. Filtration fan density and body size distributions support phylogenetic niche conservatism, but traits related to the size of the feeding area are more labile and exhibit greater divergence than expected among closely related species. Finally, we compare changes in the shape and phylogenetic structure of niche distributions between the Brechin Lagerstatte and the Edwardsville crinoid fauna, a well-studied Mississippian (Visean) paleocommunity, to examine patterns of community change across the Early to Middle Paleozoic Crinoid Macroevolutionary Faunas.

A revised conodont biozonal scheme for the Ordovician of South China is presented herein based on extensive studies following the pioneer work by the late Professor An and his co-workers in the 1980s. This new classification of 33 biozones and subbiozones includes the conodont succession of the Yangtze Platform (29 biozones and subbiozones), the Jiangnan Slope (17 biozones), and a unique succession in the Qinling Orogen (four Katian biozones). The proposed biozone scheme provides more accurate correlations of the Ordovician strata in South China. As the best known and most detailed Ordovician conodont biozone succession in eastern Gondwana and peri-Gondwana, it will serve as a standard reference for correlation not only in this region but also for comparisons with the well-established biozone successions in Baltoscandia and North America. Furthermore, this new scheme has the potential to improve the precision in reconstruction of the conodont biofacies architecture in space and time. It will also assist in advancing our understanding of the timing and magnitude of biodiversification, oceanographic, and geological events at both the local and global scale.

Species migration events are common features of the fossil record, but the impacts of immigration events vary. In this paper, the pattern and impact of two types of immigration events are compared: ephemeral invasion and biotic immigration events (BIMEs). Specifically, this study focuses on biotic patterns preserved in Edenian, Maysvillian, and Richmondian (Late Ordovician, Katian) age strata in the Cincinnati, USA region. New Edenian occurrences of rhynchonelliformean brachiopod taxa belonging to the classic “Richmondian Fauna” are documented, and the ecological and evolutionary impacts of these short-lived pre-Richmondian invasions and the sustained Richmondian Invasion are compared. The Richmondian Invasion produced substantial ecological changes and evolutionary impacts within the Cincinnatian paleocommunity; however, the ephemeral invasions that occurred in the Kope Formation did not produce a marked or lasting impact on ecological relationships within Cincinnatian paleocommunities. In each instance, an Edenian novel immigration or biotic event was limited in temporal duration and did not exceed the time to deposit a single sedimentary package. Although such ephemeral invasions do not result in community-scale changes, they nevertheless provide important information about basin connectivity, provide insight into abiotic environmental conditions, and can be useful stratigraphic indicators.

The trepostome bryozoans Diplotrypa abnormis, D. bicornis, D. petropolitana, Esthoniopora communis, E. subsphaerica, Mesotrypa excentrica, M. expressa, M. raritabulata, and Monotrypa jewensis have symbiotic associations with the conulariid Climacoconus bottnicus in the Upper Ordovician of Estonia. All bryoimmured conulariids are very small and oriented perpendicular (or nearly so) to the growth surface of the host trepostome colony. Muddy seafloors may have promoted this symbiosis between conulariids and bryozoans because the former required a hard substrate for attachment. It is possible that the numerous smaller specimens among endobiotic conulariids usually died as juveniles together with their bryozoan host, or alternatively, the smaller endobiotic conulariids may have been Lilliput forms of free-living conulariids that died at a mature age. Conulariid-trepostome associations were likely not a result of accidental intergrowth of two organisms. Additional protection against predators provided by the calcitic bryozoan skeleton may have been among the benefits for the conulariid symbionts. Usually trepostomes with conulariid symbionts do not contain other invertebrates, but in the Katian in some cases they also hosted Anoigmaichnus bioclaustrations. The exact type of symbiosis between trepostomes and conulariids remains unresolved, but most likely the associations were slightly parasitic or commensal. The available data suggest that bryozoans preferred cnidarians over the other invertebrates as symbionts.

The Late Ordovician mass extinction (LOME) was a severe biocrisis during the Phanerozoic and in this extinction, trilobites, brachiopods, mollusks, graptolites, conodonts and other types suffered severe mortality, and 85% of marine invertebrate species were eliminated. The potential cause of this mass extinction remains unclear, although glaciation and marine anoxia have received the greatest attention. Herein, we present findings on pyrite morphology, pyritic sulfur isotopic composition and total organic carbon content (TOC) to analyze the evolution of redox conditions across the Ordovician-Silurian boundary in the Yangtze area of South China. Our results show that long-term euxinic conditions interrupted by episodic dysoxic/oxic events occurred from the upper Katian stage to the lower Rhuddanian stage. The two extinction pulses of LOME were coincident with euxinic conditions, suggesting that marine euxinia may have been the main cause of this mass extinction event.

The bryozoan fauna from the Xiazhen Formation (Katian, Upper Ordovician) of northeast Jiangxi Province, southeast China is reported here. Seventeen species of bryozoans belonging to fifteen genera and four orders are identified: Homotrypa yushanensis, Homotrypa sp., Prasopora yushanensis, Trematopora sp., Monotrypella sp., Rhombotrypa sp., Orbignyella sp., Constellaria jiangxiensis, Constellaria sp., Stictopora nicholsoni, Trigonodictya parvula, Ptilodictya ensiformis, Stictoporella sp., Pseudopachydictya sp., Nematopora sp., Arthrostylidae sp. indet., and Chasmatoporidae sp. indet. Four of these genera have been reported previously but nine genera (Trematopora, Monotrypella, Rhombotrypa, Orbignyella, Trigonodictya, Ptilodictya, Stictoporella, Pseudopachydictya, and Nematopora), one rhabdomesine and one fenestrate are found for the first time in the Late Ordovician strata of South China. Our palaeogeographical analysis suggests that the bryozoan association is typical for the Katian, which is mostly widespread in Laurentia, Siberia, Baltica and Mediterranean, and displays palaeobiogeographical relationships to the Laurentia–Siberia Province.

The Hirnantian glaciation, which was the first in the Phanerozoic to occur with elevated CO2 levels, caused severe mass extinctions and disrupted biogeochemical cycling in the latest Ordovician. Previous research that aimed at exploring the triggers and consequences (both abiotic and biotic) of this glacial event have largely been based on condensed or incomplete sections. However, there is much debate over the detailed glacio-eustatic processes, and especially over the possible existence and characterization of multiple glacial cycles. Herein we conduct high-resolution geochemical analyses (via XRF core scanning and ICP-OES/MS) and a sedimentological study of three continuous upper Katian – lower Rhuddanian drill cores (Well Huangge-1, Well Shuanghe-1 and Well Yiwan-1), which represent a combination of nearshore and offshore facies in South China. The geochemical and sedimentological evidences reveal for the first time three glacio-eustatic cycles encompassed within a major sea level cycle through the upper Katian and Hirnantian. Each glacio-eustatic cycle comprises a combination of regressive and transgressive systems tracts, with the third one denoting the largest sea level fall and the glacial maximum. This pattern of sea level changes can be correlated with both the glacial sedimentary records and geochemical signals in North Gondwana, Laurentia and Baltica. These glacio-eustatic changes likely led to perturbations in regional marine nutrient cycling and formed a redox landscape that is depicted herein as somewhat different from previous models. We also present the glacio-eustatic effects at a basin scale, and a refined constraint for the tempo of polar ice sheet advances and retreats. It also calls for a re-evaluation of the mechanisms whereby a multi-cycle glaciation led to the Hirnantian biotic crisis, a relationship that may be much more complicated than the simplified cause-and-effect relationship proposed before.

The late Ordovician was an important transition interval between the mid-Ordovician biological radiation and end-Ordovician extinction. Marine red beds (MRB) of Late Ordovician are distributed worldwide, including in the Americas, South Africa, England, and China. Among them, the conditions that contributed to the widespread Katian MRB was a combination of terrigenous input, cool-water settings, sediment oxidation, volcanic material input, and seasonal aridity. In contrast, Hirnantian MRB have a more limited distribution, and their occurrence might be related to regional tectonic settings and icehouse conditions. Sandbian MRB are distributed worldwide, but are relatively poorly studied. Even though Sandbian MRB are very similar in some characteristics to the Katian MRB, we don't know which factors were important to their formation and how these were related to marine environmental change and tectonic evolution. The Dawangou section near Kalping in the Tarim Basin of northwest China is an important global reference section for the auxiliary GSSP of the Middle–Late Ordovician boundary and for Sandbian through early Katian biostratigraphy and chronostratigraphy. Diffuse reflection spectroscopy, major and trace element analysis, rare earth element analysis, and sedimentology were employed to study the interval of Sandbian MRB in the Kanling Formation (within the N. gracilis graptolite zone) relative to underlying and overlying deposits. The red-colored strata have elevated total Fe and hematite contents, whereas the grey and grey-green samples have much a lower total Fe and a significant lack of hematite and goethite. The total Fe content for strata within the Sandbian MRB varies with the clay content. The Al Fe correlation within the Sandbian MRB is 0.9, whereas it is 0.6 for the non-red sediments. The Th/U ratio is much higher in the red-colored beds (averaging 7.0) relative to the underlying and overlying sediments (averaging 4.4). However, a redox proxy of Ni/Co ratios does not exhibit a significant difference between the underlying and overlying sediments (averages of 2.6 and 2.8) and the reddish Sandbian MRB interval (average of 2.6). The results indicated that the Sandbian marine red beds of the Tarim were formed during conditions of marine oxygenation that helped form and preserve the iron oxide. However, the regional distribution and aspects of the sediment geochemistry imply that another essential process for the formation of these Sandbian MRB was the influx of terrestrial iron-rich sediments from the exposed uplifts into the mixed shelf regions; and that this influx was partly governed by the regional patterns of southward subduction of the South Tianshan ocean and of northward subduction of the Altyn to the margins of the Tarim block.

The Ordovician-Silurian (O/S) transition was a critical geological interval, during which significant biological events and dramatic environmental changes occurred. Extensive research has proven that changes in the ocean environment are one of the main causes of events that affect the biosphere. However, the redox structure and related geochemical evolution of the ocean during the O/S transition remain under debate. N isotopes are thought to have significant potential for further elucidating the oceanic redox structure and related geochemical evolution during the O/S transition, and are an effective supplement to the former environmental proxies of bottom sediments. This study presents high-resolution N isotope data from a well-sequenced drill core across the O/S transition from the Lower Yangtze Platform, South China, showing an interesting isotopic variation with high δ15N values (+1‰ to +4‰) during the Late Katian to Hirnantian ages of the Ordovician and much lower values (−1‰ to +1‰) during the Rhuddanian Age of the earliest Silurian. This δ15N variation is mostly controlled by ocean redox conditions and the corresponding changes in the nitrate reservoir. Combined with previously reported δ15N data, a redox-stratified ocean with a relatively deep redox transition zone was reconstructed according to the distribution of δ15N profiles across different palaeogeographic locations. The lower δ15N values and more reducing conditions in deep water sections demonstrate that glacio–eustatic fall, rather than increased upwelling, was likely the main driver of the global redox change during the Late Ordovician. Furthermore, a global δ15N decrease during the Late Katian may be associated with the debated Boda warm event, and the up to six positive δ15N excursions observed during the Hirnantian might suggest the cyclicity of the glaciation process.

The chemical composition of the clay fraction separated from the carbonate rock of the north-eastern Baltoscandian Basin was analysed and interpreted. Increased contents of Rb, Zr, Nb, Ti and their Al 2 O 3 -normalised ratios were detected at several stratigraphical levels in the geological sections of the Middle Ordovician–Upper Llandovery. In the weathering areas, Rb, Zr, Nb, Ti and Al are sensitive to moist conditions in the clay-forming process. In the sedimentary basin, the contents of these elements in clay are preserved and allow to infer past climates. Humid events occurred in the Dapingian, Sandbian, early Katian and Hirnantian (Ordovician) and in the Middle and Late Llandovery (Silurian). Juxtaposition with the sea-level curve shows correlation of five humid climate intervals with eustatic transgressions, suggesting global causes for these climatic changes. The warm and humid events, lasting one to two million years, occurred as climaxes between ice ages. An exceptional humid event within the Hirnantian glacial time occurs during mid-Hirnantian transgression, i.e . at a time of relative warming, as well.

During the late Sandbian and early to middle Katian, a major marine transgression flooded the intracratonic basins and platforms of eastern North America, allowing brachiopods to disperse into the newly formed epicontinental seas. Two main brachiopod faunas can be differentiated using multivariate analysis of faunal data from localities across Laurentia during this time: a relatively diverse Scoto-Appalachian Fauna confined to the eastern margin of North America and peri-Laurentian terranes, and a less diverse but more widely distributed Epicontinental Fauna that expanded into the remainder of the flooded continent. The Epicontinental Fauna can be divided into four subfaunas with subtle compositional differences that correspond to different paleoenvironmental settings of eastern North America, influenced by such paleoecological factors as nutrient-rich cool-water upwelling onto the continent through the Sebree Trough, a greater range of habitable environments on the continental margin and in the adjacent deep Taconic foreland basin, and the interactions between pericratonic and intracratonic water masses of different physical and chemical properties. The Epicontinental brachiopod faunas dominated basins and platforms of continental interior until the Hirnantian extinction event.

The early Paleozoic sediments document two major biological events: the Great Ordovician Biodiversification Event (GOBE) and Late Ordovician mass extinction (LOME). Many investigations have focused on taxonomic richness patterns during these major diversification and extinction events, providing insights into their timings and potential causes. However, the coarse temporal resolutions used in previous investigations hampered their ability to document fine-scale patterns. To address these issues, we employed CONOP analysis to data collected from a large suite of southern Chinese stratigraphic successions to construct a high-resolution (temporal resolution of ~21.0 Kyr) regional chronostratigraphy and document species richness dynamics during the middle–late Cambrian to early Silurian interval. Our results showed that the GOBE began in the early Tremadocian and ended at the Dapingian–Darriwilian boundary and consisted of two major radiation phases. The main pulse of GOBE, which lasted from the late Floian to the earliest Darriwilian, exhibited a species richness increase with elevated origination and extinction rates. Major marine groups showed no significant diachroneity during the GOBE, with most presenting richness peaks in this event's main pulse of the GOBE. Plankton demonstrated a significant diversification from the late Cambrian to the GOBE climax and subsequently dominated the marine realm in South China. Marine life experienced two extinction events in the Late Ordovician, the Katian extinction and Hirnantian extinction, which resulted in a regional species loss of ~67%.

Acritarchs and chitinozoans were documented from Ordovician strata and miospores from Lower Permian beds in the Zardkuh area. Ninety-one palynomorph species, comprising acritarchs (63 species of 31 genera), chitinozoans (16 species of 12 genera), and miospores (12 species of 10 genera) were recognized that form 10 local assemblage zones, comprising Zones A–F = acritarchs, G–I = chitinozoans, and J = miospores. Zone A occurs in the uppermost Ilebeyk Formation, indicating Late Cambrian; Zones B–E are present in the Zardkuh Formation, suggesting Early Ordovician (Tremadocian–Floian)–Middle Ordovician (Dapingian) and Zone F occurs in the Seyahou Formation, presenting Late Ordovician (Hirnantian). Likewise, three Gondwanan chitinozoan Zones G–I were established in this succession. Zones G–H occur in the Upper Shale Member of the Zardkuh Formation, supporting an Early-Middle Ordovician (Floian–Dapingian), and Zone I is restricted to the Seyahou Formation, suggesting Late Ordovician (Hirnantian) age. Finally, Zone J occurs in the Faraghan Formation, confirming Early Permian. Based on palynomorph zones, two hiatuses are present within the Paleozoic sequences of the study area. The first hiatus occurs between the Zardkuh and Seyahou formations, encompassing the Middle Ordovician (Dapingian) and much of the Late Ordovician (Sandbian and Katian). The second hiatus appears between the Seyahou and Faraghan formations, spanning the Silurian, Devonian, Carboniferous, and earliest Permian (Asselian). The palynomorph taxa, including Arbusculidium, Striatotheca, Coryphidium, Vavrdovella, Eremochitina, Velatachitina, and miospore taxa, confirm that the study area belongs to peri-Gondwana paleoprovince. Four new species are Vavrdovella mawlawii sp.nov., Vogtlandia zardkuhensis sp.nov, Pseudocoryphidium zagrosensis gen et sp.nov, and Pterospermella saadii sp.nov.

Quantifying the relative stability of ecological niches of taxa during intervals of environmental change including determining the environmental controls of niche expansion, stability, and contraction is important for understanding of how taxa and communities change through time. In this study, we used ecological niche modeling to quantify trends in niche dynamics and the stability of eastern Laurentian brachiopod genera during the Sandbian through Katian Stages of the Late Ordovician Epoch. Niche dynamics were quantified using ordination methods to assess niche stability, expansion, and unfilling between time slices, and D and I statistics were calculated to assess niche similarity and equivalency between time slices. Brachiopod genera exhibited substantial niche expansion and limited niche stability between their reconstructed Sandbian and early Katian niches. Conversely, comparisons between early Katian and late Katian niches indicated high levels of niche stability, similarity, and equivalency but limited niche expansion or unfilling. No singular abiotic or biotic causal driver is consistent with the observed patterns. Patterns of niche dynamics and stability are best explained by a feedback loop linking tectonics, sea level, and climate with geographic connection and disconnection of depositional basins, speciation, and dispersal processes. During the Sandbian to early Katian interval, intermittent dispersal events between basins alternated with basin isolation; this cycle fostered increased diversification, which manifests as niche expansion at the genus level. During the late Katian, basin connectivity increased facilitating widespread regional dispersal events. The lack of isolation and spread of invasive taxa hindered speciation. This diminished niche expansion, and genera exhibited niche conservation as the primary niche response. These results indicate that generic niche analysis can be a useful proxy for underlying diversity dynamics and emphasize the importance of incorporating dispersal and isolation when considering evolutionary patterns and processes. Investigations of niche response over long intervals should consider both broader ecological and geographic context that incorporates the influence of diversity and dispersal.

We present new high-resolution carbonate carbon isotope data (δ13Ccarb) from four sections in the Yangtze Platform, South China, ranging in age from Tremadocian to early Katian. The data have five distinct characteristics: 1) A prominent δ13Ccarb increase from −2.79‰ to 0.13‰ at the base of the Ordovician within the Tremadocian Cordylodus angulatus-Rossodus manitouensis Zone. 2) A positive δ13Ccarb excursion from −2.56‰ to 0.58‰ in the Paltodus deltifer Zone during the late Tremadocian. 3) A gradual increase in δ13Ccarb from −1.16‰ at the top of the Oepikodus communis Zone to a peak of ~0.74‰ in the Baltoniodus triangularis Zone at the Floian-Dapingian boundary. 4) A moderate rise in δ13Ccarb from 0.59‰ to 1.24‰ in the middle Darriwilian Dzikodus tablepointensis Zone. 5) A distinct positive δ13Ccarb excursion from 0.86‰ to 2.32‰ at the base of the Amorphognathus superbus-Hamarodus europaeus Zone during the early Katian. These excursions can be correlated with C-isotopic trends identified in age-equivalent successions in South China, Argentine Precordillera, North America, and Central Sweden, demonstrating their potential for global correlations and providing a composite, high-resolution chemostratigraphic framework for sedimentary records of the Lower-Upper Ordovician in South China. Besides, our data demonstrate a temporal coincidence between the long-term rise in δ13Ccarb and the Great Ordovician Biodiversification Event, suggesting that enhanced organic matter burial and accompanied climatic cooling and oxygenation may have played an important role in promoting the increases in biodiversity during the Ordovician.

The end-Ordovician has received wide attention because it hosts major global events including mass extinctions, glaciations, significant sea-level fluctuations, and large-scale perturbations of the Earth's carbon cycle. Knowing the order and timing of these events and their components is crucial for understanding these environmental changes. Here, we use stable carbon isotope stratigraphy in combination with chitinozoan biostratigraphy to correlate the Upper Ordovician Belonechitina gamachiana chitinozoan Biozone. Its position has long been a matter of debate; some argue that it is of late Katian age and others that it is of early Hirnantian age. The Skogerholmen Formation from the Oslo-Asker District in Norway has been correlated with the lower-middle Pirgu Baltic Stage, hitherto believed to correspond to the international upper Katian Stage. Our study, however, reveals the presence of B . gamachiana , diagnostic of the eponymous Biozone, in the descending trend of a modest carbon isotope excursion in the lower part of this formation. This is strikingly similar to data from coeval end-Ordovician sections in North America, where the prevailing evidence suggests an early Hirnantian age for the B . gamachiana chitinozoan Biozone. This new correlation suggests that the lower Hirnantian boundary may be positioned within the Pirgu Baltic Stage.

Here we report and describe for the first time the Foliomena Fauna fossil record from Portugal (Kralodvorian, upper Katian). This deep-water brachiopod association originates from the uppermost beds of the Porto de Santa Anna Formation (uppermost Katian), cropping out in several localities of the Portuguese Bucaco-Penacova region (Central Iberian Zone). The three studied localities have yielded different associations, composed of 15 species of brachiopods and two trilobites, including both key elements of the deep water Foliomena Fauna and taxa typically from shallower benthic biotas, e.g. the Nicolella Fauna. The mixed character of the associations indicates that they are probably representatives of the atypical Foliomena Fauna, characteristic of relatively shallow benthic assemblages. The Portuguese associations represent the highest-latitude occurrences of the Foliomena Fauna so far and one of the youngest. In the analyses carried out, the two Portuguese associations are grouped together with the other peri-Gondwanan associations (Sardinia and Carnic Alps) and are included within a major grouping including associations previously interpreted as inhabiting deep-water environments and also predominantly late Katian in age. According to these results, the association of Locality 2 may have inhabited a slightly deeper environment than the one present in Locality 3. This agrees with the presence in the former of a greater number of deep-water genera. Despite of the occurrence of a great number of deep-water taxa in the association of Locality 2, the co-occurrence of several elements related to the shallower water Nicolella Fauna, probably transported offshore as a result of the slope of the inclined shelf, suggest that this association probably inhabited slightly shallower environments than those expected for a typical Foliomena Fauna (BA5-6) with no shallow-water elements represented. This inference is also supported by the absence from the association of cyclopygid trilobites.

The author examined the high-latitude Hirnantian diamictites of the Ghelli Formation and the early Silurian olive-gray shales of the Niur Formation exposed in the northeastern Alborz Mountains, Iran. These 404 m thick glacial deposits can be divided into three progradational-retrogradational cycles, each potentially controlled by the regional advance and retreat of the Hirnantian ice sheet. The glaciated source area was west of the study area, in the Arabian Shield region, where numerous tunnel valleys have been reported. Time calibration was performed based on a high-quality biostratigraphic control, mainly derived from the chitinozoan biozones Tanuchitina fistulosa , Acanthochitina barbata , Armoricochitina nigerica , Ancyrochitina merga , Tanuchitina elongata , Spinachitina oulebsiri , and Spinachitina fragili s. The land-derived miospores present in most chitinozoan assemblages, often abundant, seem associated with global sea-level changes during the Late Ordovician glaciation. The Ghelli Formation's high abundance of terrestrial miospores and low abundance of marine palynomorphs suggests its deposition in a shallow marine environment. Additionally, rhythmic bedded tidalites of claystone and sandstone indicate the growth of early land plants producing cryptospores on adjacent flooded areas. Based on marine palynomorphs (chitinozoans and acritarchs), the northeastern Alborz Mountains glacial deposits were dated as Hirnantian; the Niur Formation was assigned to the earliest Llandovery (Rhuddanian). Glacial deposits and marine palynomorphs suggest the presence of Hirnantian ice caps in the Alborz Mountains, at the margin of the Arabian Plate, and indicate the peripheral extension of the Late Ordovician ice sheet. Several biostrome beds forming pelmatozoan-bryozoan mud-mounds, mainly comprising bryozoans, echinoderms, tentaculites, and subordinate trilobites, were found in the glacial deposits of the Ghelli Formation, suggesting carbonate deposition during the Hirnantian. These carbonate beds are not related to the Boda warming event, which happened over the Gondwana landmass in the Katian interval; the glacial deposits of the Alborz Mountain Ranges are thus not correlated to those of the Gondwana paleocontinent. Climatic amelioration is more likely than local reduction of clastic input to be responsible for the biostrome beds in the Glacial Member of the Ghelli Formation, namely a short-lived episode of global warming during the Hirnantian interval (the Milankovitch cycles). Four new chitinozoan species, namely Armoricochitina persianense n. sp., Tanuchitina alborzensis n. sp., Spinachitina iranense n. sp., and Hyalochitina jajarmensis n. sp., are described and illustrated. Biometric data are also provided for the Iranian S . oulebsiri and A . nigerica .

Well-preserved miospore assemblages are recorded from the Late Ordovician (Katian–Hirnantian) Ghelli Formation in the Pelmis Gorge, located in the Alborz Mountain Range, Northeastern Iran. The palynomorphs were extracted from siliciclastic deposits that are accurately dated using marine palynomorphs (acritarchs and chitinozoans). The spore assemblages consist of 14 genera and 28 species (26 cryptospores and 2 trilete spore species). Six new cryptospore species are described: Rimosotetras punctata n.sp., Rimosotetras granulata n.sp., Dyadospora asymmetrica n.sp., Dyadospora verrucata n.sp., Segestrespora iranense n.sp., and Imperfectotriletes persianense n.sp. The study furthers knowledge of the development of the vegetative cover during the Late Ordovician. Various and abundant cryptospores in the Late Ordovician (Katian–Hirnantian) Ghelli Formation are probably related to the augmentation of land-derived sediments either during the global sea-level fall linked to the Late Ordovician glaciation or adaptation of the primitive land plants in a wide range of climatic conditions. These miospore taxa were produced by the earliest primitive land plants, which probably grew close to the shoreline and were washed in from adjacent areas, producing a high volume of miospores. The associated marine palynomorphs consist of acritarchs (13 genera and 18 species), chitinozoans (9 genera and 10 species), prasinophycean algae, scolecodonts, and graptolite remains, which are not discussed in detail herein. The established chitinozoan biozones of this part of the Palaeozoic sequence are the Armoricochitina nigerica Biozone, the Ancyrochitina merga Biozone, the Tanuchitina elongata Biozone, and the Spinachitina oulebsiri Biozone, suggesting a Late Ordovician age (Katian–Hirnantian). These chitinozoan biozones are widely evidenced only in the peri-Gondwanan Domain, indicating that the study area was part of this palaeo-continent in the Late Ordovician.

During the end-Ordovician–early Silurian interval, two sequences of dark shales and cherts, the Wufeng and Kaochiapien formations, were deposited in Jiangsu and Anhui provinces on the Lower Yangtze Platform. Both sequences have great potential as petroleum source beds. Using previous biostratigraphic schemes for the area, combined with new material from outcrops and a borehole in the Nanjing Hills, this study recognized 11 graptolite biozones over four stages from the Dicellograptus complexus Biozone (Katian, Upper Ordovician) to the Coronograptus gregarius Biozone (early Aeronian, Silurian). Our comprehensive study of both the graptolite biostratigraphy and hydrocarbon source-bed features of a borehole in the Nanjing Hills showed that the Rhuddanian Parakidograptus acuminatus and Cystograptus vesiculosus biozones are the favorable intervals for shale gas occurrence.

The 186-m-thick Shiyanhe Formation exposed at the Sigang section, Neixiang area, Henan Province, central China has been investigated for conodonts. The collected 33 samples yielded 8858 conodont specimens. The conodonts are referred to 15 genera and 34 species, but four species cannot be positively identified and one taxon is kept in open nomenclature. The Oulodus ulrichi, the Oulodus robustus, the Aphelognathus grandis and the Aphelognathus divergens conodont biozones are introduced and the conodont fauna and biozones of the Shiyanhe Formation are referred to the Katian Stage (Stage slices Ka2–Ka4) of the Upper Ordovician. The presence of biostratigraphically important species of the genera Aphelognathus, Oulodus and Yaoxianognathus allows for the recognition of the previously defined local conodont biozones that were established from the studied section. Regionally, the Shiyanhe Formation fauna is relatively similar to the contemporaneous faunas from the Tarim terrane in western China and from the southwestern margin of the North China Platform. However, the faunal composition also shows a close affinity to the North American Midcontinent Province and correlation to North America is clear. The conodont fauna is dominated by the species of Aphelognathus, Belodina, Drepanoistodus, Oulodus, Panderodus, Phragmodus, “Plectodina” and Yaoxianognathus. The Aphelognathus–Oulodus biofacies, the “Plectodina” biofacies, the Panderodus biofacies, the Drepanoistodus biofacies and the Phragmodus biofacies have been established using multivariate statistical techniques on the conodont assemblage. As their turnovers were related to sea-level changes, the conodont biofacies are used to demonstrate the transgressive-regressive pattern in the studied section.

Investigation of 37 samples from continuously cored intervals of the upper part of the Quwarah Member of the Qasim Formation yielded well-preserved and diverse chitinozoan assemblages. Two biozones previously defined from the North Gondwanan Domain were recognized in the examined cores: the Tanuchitina elongata and Ancyrochitina merga. One new genus, Alhajrichitina, and five new species, Alhajrichitina adamantea, Hyalochitina incomposita, Rhabdochitina curvata, Tanuchitina contracta and Tanuchitina densimura, are described. The vertical distribution of these new taxa form the basis of the Tanuchitina elongata Partial Range Subzone, Hyalochitina incomposita Total Range Subzone, Tanuchitina contracta Partial Range Subzone, and Tanuchitina densimura-Belonechitina aff. robusta Concurrent Range Subzone. Two other assemblages, T. ontariensis and Angochitina cf. curvata are also recognized from the merga Biozone. These new subzones and assemblages improve regional and local stratigraphic correlations, and the recognition of the degree of the Hirnantian glacial erosion at the top of the Quwarah Member. An evolutionary lineage is proposed for the species assigned to Alhajrichitina nov. gen., originating with the Sandbian Lagenochitina dalbyensis, through the Katian Alhajrichitina adamantea and culminating with Rhuddanian species, Alhajrichitina nuayyimensis. Three minor diversity and abundance increases are recognized within the merga–elongata biozone interval. These events could represent minor pulses of sea level rise within a progressive, overall sea level drawdown. For this upper part of the core, a general trend of decreasing diversity is recognized and may indicate an upward shallowing. This trend is compatible with diversity trends from all paleocontinents. It could be speculated that fluctuations in sea level were caused by ice advance and retreat during the initiation of Hirnantian continental glaciation south of the study area.

In the Central Uplift of the Tarim Basin, northwestern China, the Katian (Upper Ordovician) limestones of the Lianglitag Formation extend from outcrops in the Bachu area to the subsurface in the Tazhong Oil Field (TZOF) area. Reefs and inner platform deposits are the dominant facies throughout the formation. The reef composition illustrates a palaeoecologic gradient from microbial-dominated buildups on the northwestern margin to metazoan-dominated reefs on the eastern and southern margins of the platform. Between these areas no outcrops are present. In the present study, data including litho- and biofacies logs and correlations from eight wells are presented, six of them of the region between Bachu and Tazhong, and two wells along the former platform margin from the TZOF. Calcimicrobial carbonates are common in core from the inner platform part. Benthic biota documented here resembles that of the microbial mounds and bioclastic limestones in the Bachu outcrop area, and thus is considered as the eastward extension of this realm. However, metazoan-dominated boundstones formed by corals, stromatoporoids, sponges together with calcareous algae are abundant along the southern platform margin, and are similar in composition to the reefs of TZOF in the easternmost part of the platform. The palaeoecologic differentiation between microbial- and metazoan-dominated reefs suggests a strong environmental gradient from a well-oxygenated windward eastern and southern side of the platform, which favoured the open ocean and which was dominated by metazoan reefs, and the inner platform as well as the northwestern, leeward margin of the platform with warmer, less-oxygenated water, which favoured the growth of microbial carbonates. Assuming the trade winds as cause for the contrasting facies on both sides of the platform a palaeo-position of Tarim south of the ITCZ seems probable because a position north of it would require a post-Ordovician clockwise rotation of Tarim of about 90° which is possible but less probable.

The final publication is available at Elsevier via https://doi.org/10.1016/j.chemgeo.2017.03.015 © 2017. This manuscript version is made available under the CC-BY-NC-ND 4.0 license

Well-preserved cryptospore and chitinozoan assemblages were recovered from the Tierekawati Formation (late Katian, Late Ordovician) of the Mannan-1 borehole, south Tarim basin (Tarim Block), China. The chitinozoan assemblage is low in abundance and diversity (two genera, five species), and its age is restricted to the late Katian (Late Ordovician). The cryptospore assemblage consists of the tetrads (three genera, five species) and dyads (three genera, four species), with a low abundance and diversity. It has similarities to the previous records from the coeval deposits around the world. Comparison of two coeval cryptospore assemblages from two boreholes more than 300 km apart within the Tarim Block shows the separate landmasses of the south and north Tarim Block were covered with much the same cryptophyte vegetation. The different elements in the vegetation might be caused by the local palaeogeography and palaeoenvironment.

The end-Ordovician (Hirnantian) crisis is the first globally distinct extinction during the Phanerozoic, but its causes are still not fully known. Here, we present an integrated geochemical and petrographic analysis to understand the sedimentary conditions taking place before, during and after the Late Ordovician ice age. New data from the Zbrza (Holy Cross Mountains) and Goldap (Baltic Depression) boreholes shows that, like in other worldwide sections, the total organic carbon (TOC) content is elevated in the upper Katian and uppermost Hirnantian to Rhudannian black shales, but depleted (below 1%) during most of the Hirnantian. Euxinic conditions occurred in the photic zone in both TOC-rich intervals. This is based on the maleimide distribution, occurrence of aryl isoprenoids and isorenieratane, as well as a dominance of tiny pyrite framboids. Euxinic conditions were interrupted by the Hirnantian regression caused by glaciation. Sedimentation on the deep shelf changed to aerobic probably due to intense thermohaline circulation. Euxinia in the water column occurred directly during the time associated with the second pulse of the mass extinction with a termination of the end-Ordovician glaciation and sea level rise just at the Ordovician/Silurian (O/S) boundary. In contrast, we suggest based on inorganic proxies that bottom water conditions were generally oxic to dysoxic due to upwelling in the Rheic Ocean. The only episode of seafloor anoxia in the Zbrza basin was found at the O/S boundary, where all inorganic indicators showed elevated values typical for anoxia (U/Th > 1.25; V/Cr > 4.25; V/(V + Ni): 0.54–0.82 and Mo > 10–25 ppm). Significant differences in hopanes to steranes ratio and in C 27 –C 29 sterane distribution between the Katian, Rhudannian and Hirnantian deposits indicate changes in marine microbial communities triggered by sharp climate change and Gondwana glaciation. The increase from biomarkers of cyanobacteria (2α-methylhopanes) after the O/S boundary implied enhanced microbial activity following the mass extinction event.

Marine cavities harbouring cryptic organisms have been ubiquitous throughout the Phanerozoic. However, our knowledge of early cryptic communities is as yet insufficient, and how metazoans began to utilize such habitats remains unknown. In this study, we document demosponge remains within intraskeletal cavities embedded in the micritic succession of a shallow carbonate platform in the Upper Ordovician (Katian) Xiazhen Formation of South China. Molluscs (gastropods, bivalves, and nautiloids) and corals (the solitary rugosan Tryplasma and colonial agetolitids) within the succession commonly contain patches of “spicular” demosponge remains (11%; n = 45/415), mainly occupying intraskeletal spaces with areas of 1–30 mm2 in thin-section. Sponge occurrence varies according to sedimentary facies: within lime mudstone facies, sponges commonly occur both inside and outside intraskeletal cavities, suggesting that sponges would have inhabited and become preserved within any available space in this environment. In contrast, when other sessile organisms co-occur in wackestone to packstone facies, there are fewer sponge occurrences both inside and outside cavities, possibly due to competition in open habitats and/or their poorer preservation in such environments. Overall, this result suggests that sponges would have exploited cryptic habitats by normal expansion of the open-surface biota. In addition, compared with coeval reef and hardground crypts, the Xiazhen intraskeletal cryptic biota is monotonous in composition, suggesting “decoupled” occupation of cryptic habitats in different environments.

Plectorthis is a commonly reported Late Ordovician brachiopod genus from Laurentia and several other tectonic plates. Examination of shells from the Cincinnati Arch type area shows that species previously assigned to the genus have a considerable range of variability, such as ribbing style, shell outline, and musculature. The type species, Orthis plicatella Hall, 1847 is characterized by generally simple costae, with double-rowed aditicules on each rib, and a cordate ventral muscle field. Some species previously attributed to Plectorthis have a subtriangular ventral muscle field and hence a closer affinity to the plaesiomyid genus Austinella . Orthis fissicosta is here demoted to a subspecies of Plectorthis plicatella based on its similar ribbing style to some specimens of the type species. In Laurentia, Plectorthis first appeared in the Darriwilian–Sandbian boundary interval, achieved a relatively high species diversity and wide paleogeographic distribution in pericratonic seas during the early Katian; the subequatorial species attained a notably larger shell than those in the higher paleotropics. The genus did not invade the intracratonic basins of Laurentia and became extinct by the late Katian.

Results of conodont-based δ18Ophos studies from two core sections in Estonia (Mehikoorma-421 and Valga-10) indicate that the pre-Hirnantian Late Ordovician was characterized by a general cooling trend: a rapid climate cooling in the early Sandbian and a less intense cooling in the late Sandbian through Katian. During this time interval, sea-surface temperatures probably decreased by up to 9o C. This fits with earlier ideas of a colder Late Ordovician climate before the Hirnantian. On the background of general cooling trend in the pre-Hirnantian Late Ordovician, tendencies in the temperature changes were quite variable. Several episodes of SST decrease and increase of different magnitudes and durations are evident from the δ18Ophos curves in the studied sections. In the interval sampled in detail, 7 cooling events are recognized and tentatively called (in stratigraphical order): Early Kukruse, Haljala, Keila, Early Nabala, Vormsi, Early Pirgu and Middle Pirgu CE-s. Duration of these events and amplitudes of changes in seawater temperatures increased from Sandbian to late Katian. All cooling events may have triggered the waxing of polar and subpolar Gondwana icecaps and are reflected in the sedimentary succession by major sea-level lowstands recognized also outside the study region. Results of our research do not support a simple, straightforward correlation between temperature trends inferred from δ18Ophos measurements and changes in the δ13C record. Comparison of δ18Ophos and δ13C curves reveal that these two variables behave quite independently: in some intervals their trends fit quite well, in others they might show completely the opposite. For this comparison we provide also a new, detailed δ13C curve from the Valga-10 core section.

The latest Katian (Late Ordovician) is marked by the third biodiversity climax of the Great Ordovician Biodiversification Event (GOBE) prior to the Late Ordovician mass extinction (LOME). In this study, the Chemical Index of Alteration (CIA) is used to determine the paleoenvironmental change recorded in the Arisu Member, the Siltstone Member, and the Sandstone Member of the Terekawat (= Tierekeawati) Formation (upper Katian) in the Tarim Basin, northwestern China. CIA values from these members are plotted in A–CN–K ternary diagrams respectively. Linear regression and 95% confidence interval estimation results indicate that these deposits were derived from the same parent rock, and the corrected CIA (CIAcorr.) values reveal significant paleo-climate changes during Late Ordovician. Sea-surface temperatures (SSTs) have been estimated by comparing 31 modern estuary systems. These data show that the CIAcorr. values dropped from 77.41 to 64.83, corresponding to an interpreted temperature drop from 20.5 to 10.2 °C in the Dicellograptus complexus graptolite Biozone of the upper Katian (Ka-4). CIAcorr. values varied within a range of 67.63–70.16, implying temperature fluctuations between 12.5 and 14.6 °C in the lower to middle Paraorthograptus pacificus Biozone. CIAcorr. values rose again from 69.09 to 76.05, corresponding to a temperature rise from 13.7 to 19.4 °C in the upper Paraorthograptus pacificus graptolite Biozone of the latest Katian. This is interpreted to be a cooling and warming cycle, corresponding to the mid-Boda cooling and the late-Boda warming events. This study suggests that the climate change during late Katian was more intense than previous thought, especially in subtropical zones of Paleo-Tethys. This cooling event enhanced the thermohaline ocean circulation and became one of the major factors causing the well-known late Katian faunal dispersal (i.e. the Boda event). Hirnantian glaciation would have further promoted global oceanic cooling, over-stressed the ecosystems, and triggered the LOME.

Pronounced excursions of carbon and sulfur isotopes (δ13C and δ34S) spanning the Ordovician–Silurian (O–S) transition have been recognized globally, yet the causes of these isotope events and their causal relationships to environmental changes, especially during Early Silurian time, remain the topics of debate. In this study, we present organic carbon and pyrite sulfur isotope (δ13Corg and δ34Spyr) records and elemental concentrations from a drill core spanning from the Upper Ordovician (Katian) to Lower Silurian (Aeronian) succession of the Yangtze Platform, China. The newly presented δ13Corg profile records previously recognized positive excursions, including the Hirnantian isotopic carbon excursion (HICE), the middle Rhuddanian excursion, and the early Aeronian positive carbon isotope excursion (EACIE). In addition, two negative δ13Corg excursions are recognized during the Katian to early Hirnantian and late Hirnantian to middle Rhuddanian stages. The δ34Spyr profile exhibits a great amount of variation (−17.8‰ to +19.6‰) but mimics the δ13Corg record. Coupled positive δ13Corg and δ34Spyr excursions during the middle Hirnantian and late Rhuddanian to Aeronian are associated with decreased total organic carbon (TOC) content and less reducing water column conditions, whereas the negative δ13Corg and δ34Spyr excursions during the Katian to early Hirnantian and late Hirnantian to middle Rhuddanian are associated with enhanced TOC values and the establishment of more strongly anoxic to euxinic conditions. The δ13C and δ34S excursions during the O–S transition, then, cannot be explained by changes in redox conditions or the burial of organic carbon and pyrite. The heavier and less variable middle Hirnantian and late Rhuddanian to Aeronian δ34Spyr values probably reflect low marine sulfate concentration. In contrast, negative Katian to early Hirnantian and late Hirnantian to middle Rhuddanian δ34Spyr excursions may reflect increased sulfate concentration. The two negative δ13Corg and δ34Spyr excursions associated with the Katian to early Hirnantian and late Hirnantian to middle Rhuddanian correspond with episodes of volcanism. We therefore propose that volcanism was the main driver of coupled negative δ13Corg and δ34Spyr excursions. As volcanism diminished during the middle Hirnantian and late Rhuddanian to Aeronian, both δ13Corg and δ34Spyr returned to more positive values. Our results indicate that volcanism played a crucial role in triggering carbon and sulfur isotope perturbations and environmental changes during the Late Ordovician and Early Silurian.

Oceanic upwelling is an important process in ocean cycling and has implications for climate change and ocean productivity. During the Late Ordovician to early Silurian (O/S) transition, many dramatic geologic events occurred, including the Hirnantian Glaciation, enhanced organic matter accumulation, and upwelling events. Upwelling is thought to be closely linked to contemporary geologic events; however, the internal relationships and mechanisms involved remain poorly understood due to a reliance on qualitative evidence and low-resolution data. To better determine the presence and development of upwelling, as well as its underlying mechanisms and potential implications for environmental changes during the O/S transition, we report new evidence and insights based on data for South China. Detailed petrographic and geochemical analyses of a well-sequenced drill core from the Lower Yangtze region are presented and compared with other extensively examined sections from the Upper Yangtze region. We show that the excessive biogenic silica content associated with certain geochemical fingerprints (i.e., Cd/Mo, Co × Mn, and CoEF × MnEF) offer compelling evidence for widespread upwelling in the Yangtze region during the O/S transition. This upwelling was strong during the late Katian to Hirnantian, significantly weaker during the early Rhuddanian, and was generally more intense in the relatively deep waters of the Yangtze region. The glacially-influenced temperature difference between the poles and equator, as well as longshore trade winds, may have been the drivers of this widespread upwelling. The upwelling event may have increased surface productivity, driving the accumulation of organic matter in the Wufeng Formation in South China. Moreover, the upwelling event can be regarded as a broad indicator of Late Ordovician glaciation and may be the geochemical basis for the Boda warm Event that occurred prior to Hirnantian cooling.

The Late Ordovician mass extinction (LOME) was the second most severe Phanerozoic biodiversity crisis. While environmental deterioration and oceanographic changes associated with the Hirnantian glaciation have been frequently invoked as potential extinction drivers, recent evidence for a large igneous province eruption at that time has challenged this prevailing view. As such, the triggering and killing mechanisms of the LOME remain debated. Here we report mercury (Hg) concentrations, isotopic compositions, Hg/total sulfur (Hg/TS), and Hg/total organic carbon (Hg/TOC) in Late Ordovician limestone/black shale alternations from two successions in South China and Laurentia that straddled the paleoequator. Our results, in both areas, show multiple Hg enrichments before and during the LOME, suggesting a global, or at least a widespread increase in environmental Hg loading. The initial Hg enrichments occur in the mid-upper Katian units and are followed by additional Hg anomalies in the lower Hirnantian strata that coincide temporally with the first pulse of the LOME. Extremely high levels of Hg, Hg/TS, and Hg/TOC, with maximum values of 737 ng g−1, 633 ng g−1 Hg/wt% TS, and 167 ng g−1 Hg/wt% TOC, respectively, represent ~3–13 × background values, indicating increased Hg input to the ocean. The absence of mass-independent fractionation of Hg isotopes in the Hg-enriched intervals suggests a volcanic source for the observed Hg anomalies. The temporal coincidence of Hg anomalies with the extinction horizon in both continents suggests that extensive and widespread volcanism may have had global climatic and ecological impact, and was a primary trigger for prolonged and synergetic deterioration of Late Ordovician environment such as climate changes, ocean acidification, and anoxia, causing the LOME.

Whether volcanic activity in South China (SC) was synchronous with global volcanism during the Ordovician-Silurian transition (OST) has long been an interesting topic. In recent years, an increasing number of volcanic ash beds (VABs) have been identified in outcrops and individual wells, thereby providing more evidence to explore this issue. Here, we used 12 outcrops and 3 wells to investigate the VABs distribution in SC and compared it with the distribution of VABs in other parts of the world. Detailed analysis reveals that the volcanism in SC was not only a part of the global volcanic activity but also had unique characteristics. In SC, the volcanic activity may have been stronger than that in other areas, because more VABs have been discovered. Additionally, the VABs in SC primarily formed during the Late Ordovician Katian and Hirnantian stages and the early Silurian Rhuddanian stage, while in other areas, they mainly formed during the Late Ordovician Sandbian and Katian stages. These characteristics may indicate that the volcanic activity in SC occurred slightly later than that in other areas. Furthermore, the interval with a dense VAB distribution corresponds to the organic-rich shale section, indicating that volcanic activity influenced the formation of the organic-rich shale to some degree by changing the paleoproductivity and paleoredox conditions. These results provide some insight into the relationship between volcanic activity in SC and global volcanism during the OST, and information on the impact of volcanic activity on the formation of organic-rich shale.

Previous studies, based on the qualitative morphological description on the Late Ordovician brachiopod fauna hypothesized that the earliest species of Hiscobeccus, which is one of the diagnostic taxa in North American epicontinental brachiopod fauna, evolved from Rhynchotrema, a well-known rhynchonellide brachiopod, which lived in pericratonic regions of Laurentia. A quantitative approach conducting multivariate analysis, which was based on biometric characters of rhynchonellide brachiopod specimens from the Late Ordovician (upper Sandbian–upper Katian) in North America, supported this hypothesis that the younger and larger species of Hiscobeccus evolved from older and smaller species of Rhynchotrema during the Late Ordovician. The current study proposes the first report of employing an artificial intelligence model based on neural networks to map a set of quantitative morphological measurements of the Rhynchotrema-Hiscobeccus lineage of North America to their locality and evolutionary trend. For this purpose, a total of 171 morphometric measurements of the Late Ordovician brachiopods from 11 localities of North America were divided into 114 training and validation samples and 57 testing sets. The input morphometric parameters of the studied brachiopods include shell length (L), shell width (W), shell thickness (T), sulcus depth (T1), sulcus maximum width (W1), sulcus floor width (W2), apical angle (AA), lamella-covered shell length (L1), lamella number (Ln). Artificial neural network tries to find a mathematical formulation between the mentioned morphometric parameters and their corresponding localities from North America. The results showed that the accuracy of the neural network approach in estimating the locality of the testing brachiopod samples is 81%. In the light of satisfactory results of neural networks, having a set of the morphometric data from the unseen Late Ordovician brachiopods, their localities can be estimated.

Redox variation during the Late Ordovician were an important driver of palaeoceanographic and ecologic changes that may have eventually facilitated biotic extinction in the end of the Ordovician. Previously, the Late Ordovician paleoredox studies have focused mostly on the last 1–2 million years prior to the end of the Ordovician; redox conditions during the Sandbian–Katian time (early–middle Late Ordovician) are poorly understood. In order to fully evaluate the effects of palaeoceanographic variations on biotic evolutionary trends through the entire Late Ordovician, it is important to fully understand redox variations following the Great Ordovician Biodiversification Event (GOBE) and prior to the end-Ordovician mass extinction. The present study reconstructs paleoredox conditions from the Sandbian–Katian successions of the Dawangou section, northwestern Tarim Basin, northwest China and the Puxihe section of the Middle Yangtze region, South China using pyrite framboidal and redox-sensitive element analyses. The distribution of volcanic microspherules, fossil fragment content and elemental analysis were also applied to reveal possible volcanisms and chemical weathering conditions, and to evoluate their effects on palaeoxygenation and biotic variations. The new results indicate three distinct periods of fluctuating paleoredox conditions during the Late Ordovician in the northwest Tarim and the Middle Yangtze regions, China. Overall, redox conditions varied from mainly oxic but punctuated by short-lived anoxic–dysoxic episodes to rapid fluctuations between reducing and oxidizing conditions, to persistent euxinic conditions. The varition of oxygen minimum zone (OMZ) that developed in the midwater column might be the main cause of anoxic events during the Sandbian–early Katian. Moreover, abundant volcanic microspheres, enhanced chemical weathering, decreasing fossil fragments of benthos, and positive europium anomaly from the study sections collectively indicate that intermittent volcanism during the early–middle Katian may have triggered anoxic-euxinic events during this interval. If integrating the newly obtained redox data with previously published data for the Katian to Hirnantian from the Middle Yangtze area, the long-term, stepwisely accelerated oxyen-poor conditions during the Late Ordovician may have facilitated biotic extinctions in the end of the Ordovician.

The earliest known endobiotic rugose corals are recorded in the Katian of Estonia. Multiple rugosans were partially embedded in colonies of the cystoporate bryozoan Ceramopora intercellata Bassler, 1911, leaving only their apertures free on the bryozoan growth surface. Bodophyllum sp. and Lambelasma sp. are rugosans that formed a symbiotic association with C. intercellata which may have been mutualistic. Rugosans presumably benefitted from growth within the stable substrate provided by the bryozoan, while bryozoans presumably benefitted by protection against some types of predators. Symbiosis between rugosans and the bryozoan Ceramopora intercellata was most likely facultative.