1. Thermal, chemical, optical properties and structure of Er3+-doped and Er3+/Yb3+-codoped P2O5–Al2O3–ZnO glasses
- Author
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Tsung-Shune Chin, C. C. Chang, K. L. Hsu, S.W. Yung, Y. S. Lai, Hsing I. Hsiang, and S. M. Hsu
- Subjects
Materials science ,Doping ,Absorption cross section ,Analytical chemistry ,Mineralogy ,Condensed Matter Physics ,Emission intensity ,Thermal expansion ,Electronic, Optical and Magnetic Materials ,Phosphate glass ,Ion ,Materials Chemistry ,Ceramics and Composites ,Glass transition ,Absorption (electromagnetic radiation) - Abstract
This study was explored in series of the optical, thermal, and structure properties based on 60P2O5–10Al2O3–30ZnO (PAZ) glasses system that doped with varied rare-earth (RE) elements Yb2O3/Er2O3. The glass transition temperature, softening temperature and chemical durability were increased with RE-doping concentrations increasing, whereas thermal expansion coefficient was decreased. In the optical properties, the absorption and emission intensities also increase with RE-doping concentrations increasing, When Er2O3 and Yb2O3 concentrations are over than 3 mol% in the Er3+-doped PAZ system and Yb3+-doped concentration is over than 3 mol% for Er3+/Yb3+-codoped PAZ system, the emission intensity significantly decreases presumably due to concentration quenching, formation of the ions clustering, and OH− groups in the glasses network. It is suggested that the maximum emission cross-section (σe) is 7.64 × 10− 21 cm2 at 1535 nm is observed for 3 mol% Er3+-doped PAZ glasses. Moreover, the maximum σe × full-width-at-half-maximum is 327.8 for 5 mol% Er3+-doped PAZ glasses.
- Published
- 2011