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46. Facile synthesis of a Ni3S2@C composite using cation exchange resin as an efficient catalyst to improve the kinetic properties of MgH2

Author

Xiantun Huang, Huiren Liang, Wenzheng Zhou, Zhiqiang Lan, Haizhen Liu, Jin Guo, Xiaobin Wen, Liang Zeng, Baobao Li, and Jun Tan

Subjects
010302 applied physics, Materials science, Hydrogen, Composite number, Enthalpy, Metals and Alloys, chemistry.chemical_element, 02 engineering and technology, 021001 nanoscience & nanotechnology, 01 natural sciences, Catalysis, Hydrogen storage, chemistry, Chemical engineering, Mechanics of Materials, 0103 physical sciences, Dehydrogenation, 0210 nano-technology, Ion-exchange resin, Carbon
Abstract

Carbon materials have excellent catalytic effects on the hydrogen storage performance of MgH2. Here, carbon-supported Ni3S2 (denoted as Ni3S2@C) was synthesized by a facile chemical route using ion exchange resin and nickel acetate tetrahydrate as raw materials and then introduced to improve the hydrogen storage properties of MgH2. The results indicated the addition of 10 wt.% Ni3S2@C prepared by macroporous ion exchange resin can effectively improve the hydrogenation/dehydrogenation kinetic properties of MgH2. At 100 °C, the dehydrogenated MgH2 Ni3S2@C-4 composite could absorb 5.68 wt.% H2. Additionally, the rehydrogenated MgH2 Ni3S2@C-4 sample could release 6.35 wt.% H2 at 275 °C. The dehydrogenation/hydrogenation enthalpy changes of MgH2 Ni3S2@C-4 were calculated to be 78.5 kJ mol−1/−74.7 kJ mol−1, i.e., 11.0 kJ mol−1/7.3 kJ mol−1 lower than those of MgH2. The improvement in the kinetic properties of MgH2 was ascribed to the multi-phase catalytic action of C, Mg2Ni, and MgS, which were formed by the reaction between Ni3S2 contained in the Ni3S2@C catalyst and Mg during the first hydrogen absorption–desorption process.

Published
2022

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