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1. Twisted 9, 10-phenanthrenequinones: Chromatographic enrichment of enantiomers and barriers to racemization

Author

Erwin Hartmann, Hans Buchner, Albrecht Mannschreck, and Doris Andert

Subjects
Circular dichroism, Investigation methods, Chromatography, Chemistry, Organic Chemistry, Drug Discovery, Organic chemistry, Enantiomer, Biochemistry, Racemization, Quinone
Abstract

The enantiomers (M) and (P) of helical 9, 10-phenanthrenequinones were enriched by liquid chromatography with enantiomeric purities of 0.31 to 0.95. Their barriers to racemization (Table 2) were compared with the ones of the corresponding hydrocarbons.

Published
1987
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