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Your search keyword '"Hamish McDonald"' showing total 2 results
Start Over Author "Hamish McDonald" Publisher elsevier bv
2 results on '"Hamish McDonald"'

1. A convenient intermediate for 4-demethoxyanthracyclinone synthesis

Author

Hamish McDonald, Paul D. Woodgate, Peter S. Rutledge, Richard C. Cambie, and David S. Larsen

Subjects
chemistry.chemical_compound, chemistry, Stereochemistry, Methyl acetate, Organic Chemistry, Drug Discovery, Acetal, Organic chemistry, Aklavinone, Biochemistry, High yielding
Abstract

Quinizarin is converted by high yielding steps into an acetoxyanthraquinone possessing acetal and methyl acetate substituents in the 2- and 3-positions. This compound is analogous to key intermediates in recent syntheses of aklavinone, 11-deoxydaunomycinone, and related compounds.

Published
1983
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2. Reductive claisen rearrangements of anthraquinone allyl ethers

Author

Hamish McDonald, David S. Larsen, Paul D. Woodgate, Peter S. Rutledge, Ian K. Boddy, Richard C. Cambie, J. Boniface, and PA Craw

Subjects
Sodium dithionite, chemistry.chemical_compound, Chemistry, Water effect, Organic Chemistry, Drug Discovery, Organic chemistry, Biochemistry, Anthraquinone, Carroll rearrangement
Abstract

Gentle heating of allyloxyanthraquinones with sodium dithionite in dimethylformanide - water effects a rapid and controlled rearrangement to give high yields of 2-allyanthraquinones.

Published
1982
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