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Start Over Author "Guo, Jinfei" Publisher elsevier bv
2 results on '"Guo, Jinfei"'

2. Synthesis, structural characterization and reactivity towards methanol of a bis(silyl)platinum(II) complex bearing a chelating depe ligand

Author

Yong-Hua Li, Shi Wang, Wenjin Zeng, Chao Huang, Guo Jinfei, Jia-Yi Zhu, Shuang-Shuang Sun, and Wei Huang

Subjects
Steric effects, Silylation, 010405 organic chemistry, Stereochemistry, Ligand, chemistry.chemical_element, 010402 general chemistry, 01 natural sciences, Medicinal chemistry, 0104 chemical sciences, Inorganic Chemistry, chemistry.chemical_compound, chemistry, Materials Chemistry, Reactivity (chemistry), Chelation, Methanol, Physical and Theoretical Chemistry, Platinum, Single crystal
Abstract

Treatment of 1,2-C6H4(SiH3)(SiH3) (1) with [Pt(depe)(PEt3)2] (depe = Et2PCH2CH2PEt2) in the ratio of 1:1 yields the complex [PtII{1,2-C6H4(SiH2)(SiH2)}(depe)] (2), which has unique reactivity towards sterically unhindered alcohol to form an unusual tetra-alkoxy substituted silyl platinum(II) compound (3). Only 2 examples of bis(silyl)platinum(II) complexes prepared from this chelating hydrosilane ligand have been registered in the Cambridge Structural Database. The structure of complex (3) was unambiguously determined by multinuclear NMR spectroscopic studies and single crystal X-ray analysis.

Published
2016

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