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The chemical characteristics of fine particulates in Metropolitan Manila, capital of the Philippines, were investigated. Week-long daily PM2.5 sampling observations were done in the months of May and October of 2018 in the Manila Bay area. May and October correspond to the boreal spring and fall monsoon transition periods, respectively. The sampling periods were selected to minimize the contribution of transboundary pollutants and to determine the influence of local mesoscale weather under similar synoptic flow conditions. Results show the daily average PM2.5 mass concentration for spring and fall to be 29.07 ± 4.69 and 50.06 ± 8.79 μg m − 3 , respectively. Most PM2.5 components were also found to be higher during fall. The difference in concentration between the two seasons is mainly due to the strong land/sea-breeze in spring induced by warmer land surface temperature. In spring, strong sea-breeze disperses PM2.5 inland, and the nighttime land-breeze serves as the outflow path of fine aerosols from Metropolitan Manila. In fall, the opposing flow of the weaker sea-breeze to the prevailing easterly produces stagnant air that leads to higher accumulated particulate concentration. Moreover, the suppressed outflow during fall season resulted in higher PM2.5 contribution of aged secondary aerosol components. Overall, the largest contributors to Metropolitan Manila PM2.5 mass concentration are the primary and secondary aerosols from local vehicular emissions, followed by soil dust and seasalt.

This study inter-compared the concentration and chemical characteristics of PM2.5 at two harbors in East Asia, and identified the potential sources of PM2.5 and their contribution. Two sites located at the Kaohsiung (Taiwan) and Manila (the Philippines) Harbors were selected for simultaneous sampling of PM2.5 in four seasons. The sampling of 24-h PM2.5 was conducted for continuous seven days in each season. Water-soluble ions, metallic elements, carbonaceous content, anhydrosugars, and organic acids in PM2.5 were analyzed to characterize their chemical fingerprints. Receptor modeling and trajectory simulation were further applied to resolve the source apportionment of PM2.5. The results indicated that the Kaohsiung Harbor was highly influenced by long-range transport (LRT) of polluted air masses from Northeast Asia, while the Manila Harbor was mainly influenced by local emissions. Secondary inorganic aerosols were the most abundant ions in PM2.5. Crustal elements dominated the metallic content of PM2.5, but trace elements were mainly originated from anthropogenic sources. Higher concentrations of organic carbon (OC) than elemental carbon (EC) was found in PM2.5, with secondary OC (SOC) dominant to the former. Levoglucosan in PM2.5 at the Manila Harbor were superior to those at the Kaohsiung Harbor due to biomass burning surrounding the Manila Harbor. Additionally, high mass ratios of malonic and succinic acids (M/S) in PM2.5 indicated the formation of SOAs. Overall, the ambient air quality of Manila Harbor was more polluted than Kaohsiung Harbor. The Kaohsiung Harbor was more severely affected by LRT of polluted air masses from Northeast Asia, while those toward the Manila Harbor came from the oceans. The major sources resolved by CMB and PMF models at the Kaohsiung Harbor were secondary aerosols, ironworks, incinerators, oceanic spray, and ship emissions, while those at the Manila Harbor were secondary aerosols, soil dust, biomass burning, ship emissions, and oceanic spray.

Two elevated fine particulate mass concentration events were observed in a span of a week in northern Philippines on March of 2017. Results from chemical characterization, lidar observation, and model simulations of particulate matter show the high aerosol concentration events to be caused by long range transport (LRT) of anthropogenic pollutants from northern East Asia at the surface and biomass burning emission from Indochina aloft. In this study, we investigated the transport path of these LRT aerosols and estimated their direct radiative forcing. A strong Siberian high and a confluent flow induced by a continental high over the main Asian continent and a cyclonic circulation over the south of Japan produced a strong northerly wind that carried pollutants from northern East Asia to northern Philippines. At the same time, strong westerlies 2–4 km aloft carried biomass burning emissions from Indochina, which also had an impact on ground concentration. Mass extinction efficiency of LRT aerosols was estimated to be in the range of 2.06–6.44 m2g-1 with a mean value of 4.32 ± 1.32 m2g−1. In addition, we calculated the direct radiative forcing effect under clear sky condition and found that the transported aerosols had a mean net negative forcing (cooling) effect of −50.80 ± 12.38 Wm−2 and −11.98 ± 3.96 Wm−2 on surface and at the top of the atmosphere, respectively. Such pollutant transport during wintertime cold surges had been shown to reduce local surface pollutants in northern China. Consequently, its impacts shift to downwind regions as far as the Philippines. As winter cold surge frequency increases due to the warming arctic, more LRT events may be expected as a result of climate change.

The influence of humidity is considered on the concentration of the suspended particulate matter (SPM) measured with a β -ray counter. The humidity condition inside a small observatory where the counter is located is, in general, different from the ambient condition outside the observatory. From the measured values, the ambient SPM concentration is derived considering the hygroscopic effect of common aerosol species of sea salt (SS), (NH 4 ) 2 SO 4 , NH 4 NO 3 and NaNO 3 . In a case study conducted during September 2005, temperature and humidity were measured both inside and outside the observatory. The average value of the relative humidity is 48% for inside and 78% for outside, resulting in approximately 53% larger SPM mass concentration after the correction. Accordingly, the value of mass extinction efficiency, which is given by the ratio between the optically measured extinction coefficient and the mass concentration, becomes lower after the correction.

Seasonal variations of tropospheric aerosol properties in Chiba, Japan, are investigated by means of optical monitoring (1999–2005), ground sampling (1998–2004), and wind data. The observation site at Chiba University is located in the urban Chiba area, about 30 km southeast of Tokyo. The aerosol optical thickness (AOT) and Angstrom exponent are derived from the data taken with a sun photometer. The value of AOT at the wavelength of 500 nm exhibits a seasonal variation, showing small values (

Continuous data of the atmosphere monitored using a portable automated lidar are correlated with the concentration of ground-measured suspended particulate matter (SPM). When the boundarylay er is well mixed, a high correlation is found between the lidar and the ground SPM data, making it possible to calculate the mass extinction efficiencyof the aerosols in the atmosphere. It is found that within the ground layer, the value of mean mass extinction efficiencychanges in a range of 4–12 m 2 g −1 , with smaller and larger values occurring for size distributions dominated bycoarse and fine particles, respectively .