1. Pyrite from coal mining: High-energy milling and analysis of the electrical and optical properties
- Author
-
Michael Peterson, Camila Machado de Oliveira, Fabiano Raupp-Pereira, Thuani Gesser Müller, Elis Machado de Oliveira, Rafael Alves André, and Elen Machado de Oliveira
- Subjects
Materials science ,business.industry ,Mechanical Engineering ,Metallurgy ,Coal mining ,Nanoparticle ,02 engineering and technology ,engineering.material ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Tailings ,0104 chemical sciences ,Mechanics of Materials ,engineering ,General Materials Science ,Charge carrier ,Direct and indirect band gaps ,Crystallite ,Pyrite ,0210 nano-technology ,business ,Absorption (electromagnetic radiation) - Abstract
Pyrite is part of the tailings from coal mining and presents a great valorization potential technological, economic and environmental in the production of nanoparticles. In this work, pyrite from coal mining was subjected to high-energy milling and the particle size reduction, electrical and optical properties were evaluated. With the milling parameters used, the apparent size of the crystallites was reduced from 34.7 nm to 23.8 nm, resulting in highly unstable particles and charge carriers with low mobility. Due to this instability, submicron particles were observed, in the range of 300–500 nm, with a hydrodynamic diameter of 1257 ± 36 nm. The processed pyrite showed good visible light absorption and an indirect band gap of 1.51 eV.
- Published
- 2019