1. Enhanced thermometry sensitivity in upconversion nanoparticles via near-field manipulation.
- Author
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Xu, Yao, Wu, Chuangxin, Wang, Pujin, Zhan, Shiping, Zeng, Jiujie, Wu, Xiaofeng, and Liu, Yunxin
- Subjects
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PHOTON upconversion , *THERMOMETRY , *THERMAL equilibrium , *NANOPARTICLES , *COMPOSITE structures , *PHOTONIC crystals - Abstract
Recently, nanoscale thermometry has attracted extensive attention. Here, we present an innovative approach to enhance the sensitivity of upconversion nanoparticles for thermometry through near-field manipulation. This method involves a composite structure consisting of photonic crystals and upconversion nanoparticles, with the near-field of the nanoparticles manipulated by tuning the absorption of the photonic crystals. The fluorescence intensity ratio (540nm/520 nm) of 4H 11/2 and4S 3/2 states of upconversion nanoparticles doped with Er3+ ions is sensitive to temperature change and employed as a temperature indicator that satisfies Boltzmann thermal equilibrium. The composite structure exhibited a relative thermometry sensitivity of 21.9 × 10−3 K−1 at 298 K, representing a significant improvement over pure core-shell upconversion nanoparticles with a 63.43% increase in relative sensitivity and a 675% increase in absolute sensitivity. This finding demonstrates the potential of our approach for advancing nanoscale thermometry. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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