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Discharge of acid mine drainage (AMD) along with heavy metals mobilization is a critical environmental concern. An urgent need is to manage or treat AMD in the minefield effectively. To this end, based on a hydrogeological investigation, the d -T (deuterium excess parameter-Tritium content) technique was adopted to trace the recharge, runoff, and discharge of AMD in the abandoned Dashu pyrite mine in China. The results reveal that AMD in the minefield originates from local precipitation and shallow groundwater and exhibits apparent seasonal runoff variations. The AMD is associated with shallow groundwater from the top of the Quaternary platform on the axis of the Dashu anticline, and protons could originate from the pyrite oxidation. Therefore, an engineering practice to purify the AMD is combined with (1) water diversion to stop AMD formation and blockage of the AMD outlets. (2) Acceleration of Fe(II) oxidation through aeration promotes the precipitation of Fe-oxide and hydroxide. (3) Neutralization of AMD using Karst water from the Maokou Formation (P 2 m). This study provides a new research idea and tracing method for improving hydrogeological surveys and effectively handling environmental problems related to AMD of abandoned mines. • Deuterium excess parameter and tritium traces the recharge, runoff, and discharge of AMD. • Karst river water is utilized to purify AMD from abandoned mines. • Engineering simulations provided a scientific basis for the treatment of AMD. [ABSTRACT FROM AUTHOR]

The Three Gorges Reservoir (TGR) is the largest reservoir in China. Cadmium (Cd) is a primary pollutant in the TGR, and its speciation and bioavailability have attracted extensive attention since TGR submergence. In this study, Chelex-100 DGT (diffusive gradient in thin films) and the sequential extraction method were used to investigate the bioavailable Cd in sediments obtained from a typical tributary (Meixi) and mainstream (Yangtze) in the TGR. The total Cd concentrations in sediments of the four stations were also determined. In comparison to the concentrations of labile Cd measured by DGT (C DGT -Cd) in four profiles, CJ and MX-upstream/downstream were at potential risk for Cd release from surface sediments using the apparent diffusion flux across the interface numerical model. The order of C DGT -Cd in surface sediments was as follows: CJ > MX-downstream > MX-upstream > MX-midstream. Additionally, a positive correlation was demonstrated between C DGT -Cd and Cd in the exchangeable fraction (F1) in the surface sediments, indicating that Cd in the exchangeable fraction was readily captured by DGT. A negative correlation was observed between C DGT -Cd and C DGT -Fe, C DGT -Mn in the sediment-water-interface (SWI), suggesting that Fe/Mn oxides did not control the release of labile-Cd from sediments. Furthermore, a positive correlation existed between the C DGT -Cd in the surface sediments and Cd in the oxidizable fraction (F3), illustrating that Cd sorbed or bound with organic matter or sulfide was labile and released into the water phase from the surface sediments. A dark area was found in the AgI gel, which further demonstrated that Cd simultaneously was released with sulfide in this area. [ABSTRACT FROM AUTHOR]

The Three Gorges Reservoir (TGR) is one of the world's largest man-made hydropower projects, which has posed great challenges to the aquatic environment of the Yangtze River since the impoundment of water. As a non-essential toxic metalloid, information on the bioavailability of Antimony (Sb) in TGR sediments is lacking. Four sediment cores were collected from a tributary and the mainstream in the TGR to investigate the distribution and remobilization of Sb using the diffusive gradients in thin films (DGT) technique. The results showed that the concentrations of Sb obtained by DGT (C DGT -Sb) at all of the sampling stations were low (below 0.30 μg/L), compared to the relatively high Sb concentrations in the sediments. The lateral and vertical distributions of C DGT -Sb revealed different tendencies in overlying water and sediments at all of the sampling sites in the TGR, which may be attributed to anthropogenic impacts, the heterogeneity of sediments and the unevenness of the sediment-water interface (SWI) during the deployment of DGT probes. In addition, C DGT -Sb in the surface sediments were lower than those in the overlying water, and concentration gradients were found near the SWI, demonstrating that Sb has the potential to diffuse from the overlying water into the sediment. In the sediment cores, different peaks were discovered in the DGT probes and the remobilization of Sb simultaneously appeared in the vicinity of −10 cm. Correlation analysis showed that C DGT -Sb had no or negative correlation with C DGT -Fe and C DGT -Mn in all of the DGT probes, suggesting that the release of Sb was unassociated with Fe and Mn in the sediments in the study area. [ABSTRACT FROM AUTHOR]

Owing to the growing public awareness on the safety and aesthetics in water sources, more attention has been given to the adverse effects of volatile organic compounds (VOCs) on aquatic organisms and human beings. In this study, 77 target VOCs (including 54 common VOCs, 13 carbonyl compounds, and 10 taste and odor compounds) were detected in typical drinking water sources from 5 major river basins (the Yangtze, the Huaihe, the Yellow, the Haihe and the Liaohe River basins) and their occurrences were characterized. The ecological, human health, and olfactory assessments were performed to assess the major hazards in source water. The investigation showed that there existed potential ecological risks (1.30 × 10 ≤ RQ total s ≤ 8.99 × 10) but little human health risks (6.84 × 10 −7 ≤ RQ total s ≤ 4.24 × 10 −4 ) by VOCs, while that odor problems occurred extensively. The priority contaminants in drinking water sources of China were also listed based on the present assessment criteria. [ABSTRACT FROM AUTHOR]

Abstract: Due to the continuous urbanization and industrialization in many countries of the world, heavy metals are continuously emitted into the terrestrial environment and pose a great threat on human health. A detailed study was conducted to determine the concentrations of six heavy metals (Cr, Ni, Cu, Zn, Cd and Pb) in road dusts in urban parks of Beijing, and assessed the health risk of these metals for local people. The dust samples were collected from 13 different urban parks in Beijing, China. The health risk was assessed using Hazard Quotient (HQ) and Health Index (HI). The results show that the average concentrations of Cr, Ni, Cu, Zn, Cd, Pb in the dust samples are 69.33, 25.97, 72.13, 219.20 0.64 and 201.82mg/kg, respectively. The concentrations of Cu, Zn, Cd and Pb were much higher than those in the background value of Chinese soil. The assessment of health risk indicated that there were mainly three exposure pathways for people: ingestion, dermal contact and inhalation. The main exposure pathway of heavy metals to both children and adults is ingestion. The values of HQ and HI are lower than the safe level (=1), indicating no health risk exists in present condition. Meanwhile, the HI value for children is higher than that for adults, indicating that children have higher potential health risk than adults in Beijing parks. [Copyright &y& Elsevier]

Abstract: This study was undertaken to investigate the current contamination status of polyhalogenated aromatic hydrocarbons (PHAHs) in sediments from 14 principal rivers of the Hai River basin. The concentrations of 22 polybrominated biphenyl (PBB) congeners, 27 polybrominated diphenyl ether (PBDE) congeners, and 27 polychlorinated biphenyl (PCB) congeners in sediments were measured using GC–MS/MS technique. The highest PBB levels were detected in sediments from River Daqing: PBB3, 10, 4, 15, 26, 31, and 49 were observed in the sediments. The highest concentrations of PBDEs were in River Tuhe (G.M.=2.10ngg−1 dw), and PBDE15 was the most predominant congener in the sediments from all of the rivers of this study, except for River Tuhe, which accounted for >13.5% of the total PBDEs in sediments. PBDE209 was detected in sediments from the Beijingpaiwu, Nanyun, Majia and Tuhe rivers, with observed values ranging from 0.06 to 0.13ngg−1 dw. PCBs had the highest concentrations in sediment samples collected from River Luan and River Daqing, with levels of 18.13 and 25.62ngg−1 dw, respectively. The most predominant PCB congener in these samples was PCB138, which accounted for about 24% of the sum of the seven indicator PCB congeners (PCB28, 52, 101, 118, 138, 153, and 180) measured in the two rivers. The measured levels of PHAHs were compared with recent results, reported in the literature, and the respective sediment quality guidelines recommended by USEPA. The levels of PHAHs in the present study were generally lower than respective threshold-effect levels, or were comparable to those reported in relatively uncontaminated freshwaters from other regions. This suggests that, in these rivers, toxic biological effects on aquatic biota—due to PHAH contamination of sediments—can be expected to be negligible. Thus, in terms of PHAHs, the sediments can be regarded as relatively uncontaminated. [Copyright &y& Elsevier]

This study was conducted to estimate the total daily dietary intakes (TDIs) of three PHAHs subfamilies for residents living around the large e-waste disassembly sites in the Zhejiang province of China. A total of 191 food samples (including seven food groups and drinking water) were obtained from the disassembly sites and the control site in April, 2007. The levels of three PHAHs were measured by GC-MS. The estimated TDIs of PBBs (385.5 ng day−1), PBDEs (195.9 ng day−1), and PCBs (12,372.9 ng day−1) in the disassembly sites were approximately 2–3 times higher than those in the control site, which suggested that these PHAHs from e-waste might have entered into the food chain. Rice appeared to be the food group showing the highest contribution to the individual dietary intakes of these PHAHs. The estimated TDIs were also compared with those results reported recently in the literature and their respective reference doses by WHO (or Health Canada). By and large, although the estimated TDIs for the PHAHs under study were lower than their respective reference doses, they were obviously higher than those observed in other places listed in the literature, thus suggesting that residents living around the disassembly sites have been exposed to higher levels of PHAHs than those places, and might thus be at greater health risk. [Copyright &y& Elsevier]

As the most widely used method for evaluating heavy metals (HMs) in soil or sediment, the enrichment factor (EF) is prone to bias and even yields misleading assessment results for HM pollution due to data uncertainties, lack of local background values and a failure to assess the comprehensive pollution of multiple HMs. Here, we developed an improved EF model integrating stochastic mathematical methods and geochemical baselines (GBs). First, GBs were obtained using the relative cumulative frequency distribution method. The probability that each HM belongs to each enrichment degree was then quantified based on the probability density function deduced from the maximum entropy method. Furthermore, we defined a synthetic index to reveal the probability that multiple HMs belongs to comprehensive enrichment degree considering the weight of each HM. Finally, the enrichment category for each HM and multiple HMs were determined following the first-order moment principle. The improved EF model was successfully applied to evaluate and predict the HM pollution in sediments collected from Poyang Lake, the largest freshwater lake in China. Slight enrichment (1.88) of multiple HMs was found in sediments from Poyang Lake, characterized by a pronounced probability (0.35) to deteriorate to the "moderate enrichment" category. Among the different HMs, Cd requires more attention considering its dominant contribution (0.51) to the comprehensive pollution and high probability (0.65) for deterioration. Otherwise, assessment results employing the improved EF model agree with the spatial patterns of HM concentrations based on spatial autocorrelation analysis and source apportionment using Pb isotopic signatures and principal component analysis. Compared with the conventional EF method, the assessment results of the improved EF model were more accurate, comprehensive and reliable. In conclusion, the improved EF model has a better capability of evaluating and predicting HM enrichment in sediments and can be helpful for optimizing control measures for HM pollution. Unlabelled Image • We proposed an improved EF model using stochastic methods and geochemical baselines. • The improved EF model has a better capability in predicting the HM pollution. • Slight enrichment of Cd and multiple HMs was observed in sediments from Poyang Lake. • Cd in Poyang Lake requires more attention considering its deteriorative probability. [ABSTRACT FROM AUTHOR]

Highlights: [•] Sorption of PAEs in young and old leachates on AC, CNTs, and biochars were compared. [•] Carbonaceous sorbents had higher sorption of PAEs in YL than those in OL. [•] Young DOM slightly increased the sorption of DEP and DBP, but old DOC was contrary. [•] CNTs had remarkable lower sorption of PAEs in old leachates relative to AC. [Copyright &y& Elsevier]

Abstract: This study was conducted to explore the burdens of PBBs, PBDEs, and PCBs among cancer patients living in the e-waste disassembly sites. The contents of 23 PBB congeners, 12 PBDE congeners, and 27 PCB congeners in kidney, liver, and lung samples were measured by GC–MS. The results showed that low-brominated PBBs and PBB153 were the predominant congeners. PBDE47 were the most predominant PBDE congeners. PBDE209 were detected in >70% of the samples, with geometric means ranging from 64.2 to 113.9 ng g−1 lipid. Among the three subfamilies of PHAHs, PCB concentrations were the highest. The detected levels of PHAHs were in the same order of magnitude in the three tissues, which indicated that any of the three tissues could be the suitable indicator for assessing body burdens of PHAHs. PBB contents (181–192 ng g−1 lipid) were obviously higher than those reported in the general USA population (3–8 ng g−1 lipid). PBDE levels (174.1–182.3 ng g−1 lipid) were comparable to those reported in the USA population, but significantly higher than those of the European population. PCBs levels were comparable to those of the European population. The high cancer incidence in the disassembly sites may be related to higher burdens of PBBs, PBDEs, and PCBs in tissues. [Copyright &y& Elsevier]

With the implementation of large-scale water diversion projects, the reduction of river flow in water diversion areas may impact the ecological environment of the river. In this study, we used integrated hydrodynamic, habitat, and risk modeling methods to produce an ecological risk time series based on the consequences of departures from the optimum environmental flow range of a river, quantifying the extent to which flow regulation affects fish habitats. Taking the water diversion project in central Yunnan as an example, we used this method to produce a risk time series of fish habitats. This time series shows that the ecological risk increases when the river flow deviates from the optimal range of environmental flow. The degree of risk is different in different periods: in wet years, the risk is negligible; in normal years, the risk is between acceptable and critical, and in dry years, the risk is above critical. The research results can provide a basis for the optimal allocation of water resources to meet environmental flow requirements. • Large drops in river flow in diversion areas may impact the ecological environment. • Our model captured risk dynamics of a river system following water diversion. • Our model generated a time series of risks rather than a single point risk. • Eco-environmental risk increases with river flow deviating from the optimal range. • This study offers a basis to allocate water to meet eco-environmental requirements. [ABSTRACT FROM AUTHOR]

Abstract Pentachlorophenol (PCP) and its byproduct hexachlorobenze (HCB) are two co-existing persistent environmental chemicals, but their combined toxicity remains unclear. In this study, adult zebrafish were exposed to 5 (low dose) and 25 μg·L−1 (high dose) of PCP, HCB or their combination for 21 days, and the impact on endocrine and reproduction was investigated. Results showed that combined exposure to 25 μg·L−1 PCP and 25 μg· L−1 HCB significantly increased the plasma estradiol (E2) and testosterone (T) levels, altered the expressions of genes along the hypothalamic-pituitary-gonadal-liver (HPGL) axis, inhibited gonadal development, and eventually lead to decreased egg production of F0 zebrafish as well as inhibited development of F1 eggs/larvae. Compared to the combined exposure of high doses, significantly lower levels of plasma E2 and T were observed for either the high PCP or high HCB alone exposure, indicating a synergistic effect of the two chemicals on endocrine disruption after combination. Furthermore, the high PCP alone exposure inhibited the gonadal development in both the males and females, while the HCB alone exposure did not. Comparison of exposure effects indicated a greater decrease of mature gametes levels and egg production in the high combined group when compared to the high HCB alone group, but no significant difference was observed between the high combined group and the high PCP alone group. Taken together, the results suggested that combined exposure to PCP and HCB may synergistically affect endocrine of zebrafish, and result in reproduction impairments, with PCP being the primary contributor. Highlights • Combined exposure to PCP and HCB resulted in reproductive impairments in zebrafish. • Combined exposure to PCP and HCB may synergistically affect endocrine of zebrafish. • Decreased GSI value and inhibited gonadal development in females might be associated with the decrease of egg production. • Reproductive impairments in the high combined group may be more attributable to the PCP toxicity. [ABSTRACT FROM AUTHOR]

Lead (Pb) contamination was recognized in China early in the 1920s. However, the response of Pb contamination in sediments to China's rapid economic and social development remains uncertain to date. We conducted a literature review of over 1000 articles from 1990 to 2016 and the first national-scale survey of Pb contamination in China. A literature review showed that available research in China focused on the economically highly developed river basins, including the Pearl River Basin (PRB), Yellow River Basin (YRB), and Yangtze River Basin (YtRB), whereas those in the less developed southeastern, southwestern, and northwestern river basins received limited attention. The YtRB and YRB had higher Pb contamination levels than other basins, corresponding with the rapid economic development in those regions. However, the less economically developed river basins in the southeastern and northwestern regions of China were also contaminated by Pb. Analysis of 146 studies in the PRB, YRB, and YtRB revealed that Pb contamination in PRB sediments showed a tendency to improve over time, whereas that from the YtRB exhibited a tendency to worsen. For the YRB, there was a slight increase from 1990 to 2006 and a decreasing trend from 2007 to 2014. The overall temporal trend in Pb levels in PRB and YRB sediments corresponded with that of the Pb discharged in wastewater in the surrounding cities, indicating that industrial wastewater discharge was possibly one of the main anthropogenic sources of Pb in those sediments. For the YtRB, the increasing trend in Pb concentrations was related to the considerably high atmospheric Pb emissions in the surrounding cities and its geographical characteristics. These findings suggested that China should develop systematic and consistent approaches for monitoring Pb contents in sediments and adopt a regional economic development policy focusing on pollution prevention. [ABSTRACT FROM AUTHOR]

A national-scale investigation of total nitrogen (TN), total phosphorus (TP), total organic carbon (TOC), and pH in sediments was performed. The sediment samples investigated in this study were collected from 10 major basins in China (Songhua River Basin (SRB), Liao River Basin (LRB), Hai River Basin (HRB), Yellow River Basin (YRB), Huai River Basin (HuRB), Yangtze River Basin (YtRB), Southeastern River Basin (SeRB), Pearl River Basin (PRB), Southwestern River Basin (SwRB), and Northwestern River Basin (NwRB)). And then, a pollution assessment was performed by comparing the data with established sediment quality guidelines (SQGs) and organic nitrogen index values. Results demonstrated that the mean TN content in the sediments of the 10 basins was 1.070 g/kg, while the mean TP content was 0.733 g/kg. The TN contents displayed significantly positive correlations with the TP contents in the sediments of SRB, LRB, YtRB, SeRB, PRB, and NwRB. Moreover, the concentrations of TN in the sediments of nine basins (SRB, LRB, HRB, YRB, HuRB, YtRB, SeRB, PRB, and NwRB) and TP concentrations of four basins (LRB, YtRB, SeRB, and PRB) were possibly related to the TOC contents, and the distributions of TN concentrations in eight basins (SRB, LRB, HRB, YRB, YtRB, SeRB, PRB, and NwRB) as well as the TP concentrations in LRB might be affected by the pH of sediments. By comparing the data in our study with those obtained in other periods (1990–2013), we found that the TN contamination situation in HuRB and the TP contamination situation in PRB have potentially worsened over time, which deserves more attention. According to the results of SQGs and organic nitrogen index assessment, among the 10 basins, SeRB was the worst watershed polluted by N and HRB was the worst watershed polluted by P. [ABSTRACT FROM AUTHOR]

To investigate the pollution status and potential pollution risk of mercury (Hg) in China, surface sediment samples were collected from eight hundred and eighty-one sites, including ten major basins (Songhua River Basin (SRB), Liao River Basin (LRB), Hai River Basin (HRB), Yellow River Basin (YRB), Huai River Basin (HuRB), Yangtze River Basin (YtRB), Pearl River Basin (PRB), Southeastern River Basin (SeRB), Southwestern River Basin (SwRB) and Northwestern River Basin (NwRB)). Results showed that Hg concentrations in sediments of ten basins in China ranged from 0.001 to 8.800 mg/kg, with average ± S.D. value of 0.274 ± 0.675 mg/kg, which was obviously higher than Chinese soil background value (0.038 mg/kg) and Chinese sediment background value (0.040 mg/kg). The mean Hg concentration of ten basins decreased in the order of HRB > YtRB > SRB > PRB > HuRB > SwRB > YRB > SeRB > LRB > NwRB. Moreover, it was found that the Hg concentrations in the sediments of LRB, YtRB, PRB, SeRB and SwRB were partly driven by their total organic carbon (TOC) contents, while the effect of pH on the distribution of Hg was not obvious. The Hg concentration data were also compared with those got in other periods (1994–2015) to obtain the general variation tendency of Hg level. It was recorded that Hg concentrations in HRB have remained on high levels for a long history, while Hg contamination situation in YRB after 2004 has potentially turned to be better. The results of pollution assessment by sediment quality assessment guidelines (SQGs), contamination factor (CF), geoaccumulation index ( I geo ) and potential ecological risk ( E i ) suggested that YRB and HRB were the most seriously polluted river basins among the ten basins. It is urgent of constructing SQGs in China to scientifically evaluate the Hg pollution in the future. [ABSTRACT FROM AUTHOR]

To investigate the impact of water impoundment on the metal contamination in sediments cores from the three tributaries of Three Gorges Reservoir (TGR), the concentrations, distribution, bioavailability, and potential risk of eight trace metals between summer and winter were analyzed using sequential analysis. The mean contents of all studied metals were higher than the geochemical background value, and were higher in summer than in winter. The results of the partitioning study indicated that Cr and Ni prevailed in the residual fraction, while a small proportion was found in the easily soluble fractions. Cu and Zn were distributed mainly in the residual and reducible fraction, while Cd and Pb were predominantly associated with non-residual fractions. These observations suggested that the most easily mobilized metals in the study area were Cd and Pb. The mean enrichment factors (EF) of Cu, Zn, Cd and Hg were higher than 1.5, revealing the potential anthropogenic inputs, whilst the EF of other metals remained within the range of natural variability. The positive correlation between non-residual Cu, Zn and Cd and their EF values further indicated that anthropogenic inputs were the potentially major contributor for the enrichment of Cu, Zn and Cd in TGR sediments. The results evaluated by both potential ecological risk index and modified risk assessment code (mRAC) of all sampling sites demonstrated the relatively high potential risk of sediment contamination effect in TGR. [ABSTRACT FROM AUTHOR]

Abstract: Impoundment of the Three Gorges Reservoir has created an artificial riparian zone with a vertical height of 30m and a total area of 349km2, which has been subjected to seasonal inundation and exposure due to regular reservoir impoundment and the occurrence of natural floods. The significant alteration of hydrologic regime has caused numerous environmental changes. The present study investigated the magnitude and spatial pattern of sedimentation and metal enrichment in a typical section of the riparian zone, composed of bench terraces with previous agricultural land uses, and explored their links to the changed hydrologic regime. In particular, we measured the total sediment depths and collected surface riparian sediments and down-profile sectioned riparian soils (at 5cm intervals) for trace metal determination. Our analysis showed that the annual average sedimentation rates varied from 0.5 to 10cm·yr−1 and they decreased significantly with increasing elevation. This lateral distribution was principally attributed to seasonal variations in water levels and suspended sediment concentrations. Enriched concentrations of trace metals were found both in the riparian sediments and soils, but they were generally higher in the riparian sediments than in riparian soils and followed a similar lateral decreasing trend. Metal contamination assessment showed that the riparian sediments were slightly contaminated by Ni, Zn, and Pb, moderately contaminated by Cu, and moderately to strongly contaminated by Cd; while riparian soils were slightly contaminated by As, and moderately contaminated by Cd. Trace metal enrichment in the riparian sediments may be attributed to external input of contaminated sediments produced from upstream anthropogenic sources and chemical adsorption from dissolved fractions during pure sediment mobilization and after sink for a prolonged flooding period due to reservoir impoundment. [Copyright &y& Elsevier]

Abstract: In the present study, goethite and goethite doped with boron (B-goethite) were employed to detect the presence or absence of semiconductor photocatalytic reaction mechanism in the reaction systems. B-goethite was prepared by sol–gel method in presence of boron acid in order to improve its photocatalystic efficiency under the ultraviolet and visible light irradiation. The optical properties of goethite and B-goethite were characterized by ultraviolet and visible absorption spectra and the result indicated that B-goethite has slight red shift in the band gap transition beside their stronger light absorption compared with pristine goethite. Degradation of aniline was investigated in presence of goethite and B-goethite in aqueous solution. It was found that the B-goethite photocatalyst exhibited enhanced ultraviolet and visible light photocatalytic activity in degradation of aniline compared with the pristine goethite. The photocatalytic degradation mechanism of B-goethite was discussed. [Copyright &y& Elsevier]

Abstract: Persistent organochlorine pesticides pollutants (OCPs) have been reported to occur at relatively high concentrations in some Chinese waters. In order to map the distribution of organochlorine pesticides in the surface water throughout China, samples were collected from over 600 sites in seven major river basins and three main internal rivers drainage areas during 2003 and 2004. The surface water samples were analyzed for the representative organochlorine pesticides contaminants including lindane (γ-HCH), p,p′-DDT and heptachlor epoxide. In general, the most frequently detected compound was lindane, being detected in 83.9% of samples (mean=31.3 ng/l; range <0.17–860 ng/l), and the highest concentration was present in the Yellow River basin. p,p′-DDT was detected in 63.1% of the samples collected (mean=14.6 ng/l; range <0.14–368 ng/l) with the highest concentration present in the Huaihe River basin. Heptachlor epoxide was detected in only 9.3% of water samples (range <0.11–10 ng/l). Measured concentrations for the three compounds were low and rarely exceed the environment quality standard for surface water of China. Lindane was more frequently detected at much higher concentrations in the rivers of northern China compared with those of southern China. The sites with higher concentration of lindane and p,p′-DDT mainly occurred in the Yellow River and Huaihe River basins, so the results of this investigation indicate that the organochlorine pesticide contamination of Yellow River and Huaihe River basins should be of particular concern relative to the other basins. When compared with other regions of the world, it appears that the Chinese surface water is moderately polluted by lindane and p,p′-DDT. [Copyright &y& Elsevier]

Abstract: The chlorophenol pollutants (CPs) have been reported to occur at relatively high concentrations in some Chinese waters. To map the distribution of CPs in the surface water throughout China, samples were collected from over 600 sites in the seven major watersheds and three drainage areas. The samples were analyzed for the representative CPs including 2,4-dichlorophenol, 2,4,6-trichlorophenol, and pentachlorophenol. In general, it was observed that 2,4-dichlorophenol and 2,4,6-trichlorophenol were more frequently detected at higher concentrations in the rivers of North China compared with those of South China. High concentration sites of 2,4-dichlorophenol and 2,4,6-trichlorophenol mainly occurred in the Yellow River, Huaihe River, and Haihe River watersheds, while pentachlorophenol contamination mainly occurred in the Yangtze River watershed. The pentachlorophenol was the most ubiquitous CPs being detected in 85.4% of samples (median=50.0ngl−1; range <1.1–594.0ngl−1), 2,4-dichlorophenol was detected in 51.3% (median=5.0ngl−1; range <1.1–19960.0ngl−1) and the 2,4,6-trichlorophenol was detected in 54.4% of water samples (median=2.0ngl−1, range <1.4–28650.0ngl−1). The results of this investigation indicated that 2,4-dichlorophenol and 2,4,6-trichlorophenol contaminations of Yellow River, Huaihe River, and Haihe River watersheds were of particular concern, while the pentachlorophenol contamination mainly occurred in the Yangtze River watershed. These results showed that CPs contamination in the surface water of China was similar to other places of the world. [Copyright &y& Elsevier]