1. A new double-layered kagome antiferromagnet ScFe6Ge4.
- Author
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Kassem, Mohamed Abdelkareem, Shiotani, Taiki, Ohta, Hiroto, Tabata, Yoshikazu, Waki, Takeshi, and Nakamura, Hiroyuki
- Subjects
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ANTIFERROMAGNETIC materials , *NUCLEAR magnetic resonance , *STRUCTURAL stability , *SPACE groups , *HYPERFINE structure , *IRON clusters , *HIGH temperatures - Abstract
ScFe 6 Ge 4 with the LiFe 6 Ge 4 -type structure (space group R 3 ¯ m), which has a double-layered kagome lattice (18 h site) of Fe crystallographically equivalent to that of a well-known topological ferromagnet Fe 3 Sn 2 , is newly found to be antiferromagnetic (AFM) with a high Néel temperature of T N ≈ 650 K, in contrast to the ferromagnetic (FM) ground state previously proposed in a literature. 45Sc nuclear magnetic resonance experiment revealed the absence of a hyperfine field at the Sc site, providing microscopic evidence for the AFM state and indicating AFM coupling between the bilayer kagome blocks. The stability of the AFM structure under the assumption of FM intra-bilayer coupling is verified by DFT calculations. • LiFe 6 Ge 4 -type ScFe 6 Ge 4 is a double-layered kagome antiferromagnet. • The Néel temperature is as high as 650 K. • In-bilayer ferromagnetic and inter-bilayer antiferromagnetic couplings were proposed. • The stability of the antiferromagnetic structure was verified by DFT calculations. • ScFe 6 Ge 6 is an antiferromagnetic alternative to the topological magnet Fe 3 Sn 2. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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