Cho, Myeongki, Jeon, Gyeong G., Sang, Mingyu, Kim, Tae Soo, Suh, Jungmin, Shin, So Jeong, Choi, Min Jun, Kim, Hyun Woo, Kim, Kyubeen, Lee, Ju Young, Noh, Jeong Yeon, Kim, Jong H., Kim, Jincheol, Park, Nochang, and Yu, Ki Jun
Recently, perovskite solar cells (PSCs) have been attracting attention as the most promising alternative to conventional photovoltaics, mainly due to their high power conversion efficiency (PCE) of 25.7%. However, prior to commercialization, problems with their long-term stability caused by moisture should be solved. Accordingly, encapsulation is a crucial strategy for enhancing the long-term stability of PSCs, meaning a well-established strategy that includes an excellent barrier that protects them from the external environment while minimizing any damage during encapsulation is required. In this study, a room temperature thin-film encapsulation (RT-TFE) strategy is applied by transferring a defect-free thermally grown silicon dioxide nanomembrane (t-SiO 2 NM), which is a well-known superior water molecule barrier, onto the PSCs. The average PCE of the devices decreased by only 0.012% with a standard deviation of 0.4249 during the entire encapsulation process, which was achieved by minimizing any thermal degradation of the photovoltaic components, including the perovskite and hole transport layers. This t-SiO 2 NM successfully protected the PSC from external water molecules in an underwater condition for 31 days at room temperature, which is the longest reported survival time of encapsulated PSCs. As a result, the RT-TFE PSC maintained more than 98% of the initial efficiency. • Demonstrated room temperature thin film encapsulation using thermally grown SiO 2. • Demonstrated encapsulation of perovskite solar cells without thermal decomposition. • The thermally grown silicon dioxide nanomembrane is superior moisture barrier. • The encapsulated perovskite solar cell was stable for 31 days underwater. [ABSTRACT FROM AUTHOR]