31 results on '"Richter, Frank M."'
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2. Isotopic mass fractionation laws for magnesium and their effects on 26Al–26Mg systematics in solar system materials.
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Davis, Andrew M., Richter, Frank M., Mendybaev, Ruslan A., Janney, Philip E., Wadhwa, Meenakshi, and McKeegan, Kevin D.
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ALUMINUM isotopes , *MAGNESIUM isotopes , *SOLAR system , *NUCLEOSYNTHESIS , *HIGH temperature metallurgy - Abstract
Magnesium isotope ratios are known to vary in solar system objects due to the effects of 26 Al decay to 26 Mg and mass-dependent fractionation, but anomalies of nucleosynthetic origin must also be considered. In order to infer the amount of enhancement of 26 Mg/ 24 Mg due to 26 Al decay or to resolve small nucleogenetic anomalies, the exact relationship between 26 Mg/ 24 Mg and 25 Mg/ 24 Mg ratios due to mass-dependent fractionation, the mass-fractionation “law”, must be accurately known so that the 25 Mg/ 24 Mg ratio can be used to correct the 26 Mg/ 24 Mg ratio for mass fractionation. Mass-dependent fractionation in mass spectrometers is reasonably well characterized, but not necessarily fully understood. It follows a simple power fractionation law, sometimes referred to as the “exponential law”. In contrast, mass fractionation in nature, in particular that due to high temperature evaporation that likely caused the relatively large effects observed in calcium-, aluminum-rich inclusions (CAIs), is reasonably well understood, but mass-fractionation laws for magnesium have not been explored in detail. The magnesium isotopic compositions of CAI-like evaporation residues produced in a vacuum furnace indicate that the slope on a log 25 Mg/ 24 Mg vs. log 26 Mg/ 24 Mg plot is ∼0.5128, and different from those predicted by any of the commonly used mass-fractionation laws. Evaporation experiments on forsterite-rich bulk compositions give exactly the same slope, indicating that the measured mass-fractionation law for evaporation of magnesium is applicable to a wide range of bulk compositions. We discuss mass-fractionation laws and the implications of the measured fractionation behavior of magnesium isotopes for 26 Al– 26 Mg chronology. [ABSTRACT FROM AUTHOR]
- Published
- 2015
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3. Isotope fractionation of Li and K in silicate liquids by Soret diffusion.
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Richter, Frank M., Bruce Watson, E., Chaussidon, Marc, Mendybaev, Ruslan, Christensen, John N., and Qiu, Lin
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LITHIUM isotopes , *LABORATORY techniques , *POTASSIUM isotopes , *THERMOPHORESIS , *SILICATES , *PRESSURE - Abstract
Abstract: Laboratory experiments were used to determine the thermal (Soret) isotopic fractionation of lithium and potassium in a basalt melt, which adds elements with ionic charge +1 to the list of elements for which thermal isotopic fractionations in silicate liquids have been previously reported (i.e., Ca, Mg, Fe, Si, O, Sr, Hf, and U). The new experiments were run at a moderate pressure of about 1.5GPa in a piston cylinder apparatus in order to avoid gas bubbles once the sample was melted. The samples were displaced slightly below the hot spot of the piston cylinder assembly graphite furnace so that there would be a temperature difference of about 125°C across the samples while molten. The thermal isotopic fractionation factor Ω (per mil fractionation per 100°C per one atomic mass unit difference) was found to be 6.0 for lithium isotopes and 1.1 for potassium isotopes. The isotopic fractionation in both cases resulted in the heavy isotopes becoming enriched at the cold end. The expanded data set of thermal isotopic fractionation in silicate liquids is used to evaluate the degree to which recently proposed parameterizations are able to reproduce the experimental data. [Copyright &y& Elsevier]
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- 2014
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4. Experimental evaporation of Mg- and Si-rich melts: Implications for the origin and evolution of FUN CAIs.
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Mendybaev, Ruslan A., Richter, Frank M., Georg, R. Bastian, Janney, Philip E., Spicuzza, Michael J., Davis, Andrew M., and Valley, John W.
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METAL inclusions , *MELTING , *ISOTOPE geology , *EVAPORATION (Meteorology) , *CHEMICAL kinetics , *LOW temperatures - Abstract
FUN (Fractionation and Unidentified Nuclear) calcium-, aluminum-rich inclusions (CAIs) have large mass-dependent fractionations of silicon, magnesium, and oxygen isotopes (up to δ29Si ∼15‰ and δ25Mg ∼40‰), and mass-independent isotopic anomalies in many elements. To test the proposition that the mass-fractionation effects of all three isotopic systems in FUN CAIs were the result of evaporation of at least partially molten precursors, we conducted a series of experiments in which two magnesium- and silicon-rich melts (FUN1 with 53.4wt% MgO and 41.3% SiO2, and FUN2 with 32.7% MgO and 38.7% SiO2, and Al2O3 and CaO in solar proportions) were evaporated into vacuum at 1900°C for various lengths of time. The chemical and isotopic compositions of the evaporation residues were measured and compared to two of the most highly mass-fractionated FUN CAIs, Vigarano 1623-5 and Allende C1. The isotopic composition of the evaporation residues was also used to determine the kinetic isotopic fractionation factors α 25,24 =0.98372±0.00041 for 25Mg/24Mg and α 17,16 =0.9883±0.0006 for 17O/16O for residues containing >15wt% MgO, and α 25,24 =0.98567±0.00046 and α 17,16 ∼0.994 for residues containing <15wt% MgO. The 29Si/28Si fractionation factor α 29,28 =0.9899±0.0004 was found to fit the data from the entire set of residues. Simple linear correlations were found for δ29Si, δ25Mg, and δ17O as a function of the fraction of magnesium or silicon remaining in the residues. The fact that the isotopic fractionations of magnesium, silicon and oxygen of C1 are in the same proportions as in the experimental evaporation residues suggests that the evaporation played a major role in the chemical evolution of this FUN inclusion. In the case of Vigarano 1623-5, the magnesium and oxygen isotopic fractionations are consistent with the experimental data, but fractionation of silicon isotopes relative to that of magnesium in 1623-5 is about a third less than in the experimental residues. Assuming that Allende C1 and Vigarano 1623-5 are evaporation residues that were produced in much the same way as our experimental residues (i.e., evaporation of completely molten droplets), the chemical compositions of their precursors were calculated using bulk chemical and isotopic compositions of C1 and 1623-5 together with the experimentally determined kinetic fractionation factors α 25,24 and α 29,28. It was found that the present chemical and isotopic compositions of C1 can be explained by evaporation of a precursor with a bulk composition close to that of a condensate from a solar composition gas. In the case of Vigarano 1623-5, however, the calculated precursor is significantly enriched in magnesium and depleted in silicon compared to plausible condensates from a solar composition gas. Among the possible reasons for such misfit could be uncertainties in bulk chemical and isotopic compositions measured in Vigarano 1623-5, or evaporation at lower temperatures from partially rather than completely molten precursors which could have different evaporation kinetics and isotopic fractionation factors. [ABSTRACT FROM AUTHOR]
- Published
- 2013
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5. Magnesium isotope fractionation by chemical diffusion in natural settings and in laboratory analogues
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Chopra, Rahul, Richter, Frank M., Bruce Watson, E., and Scullard, Christian R.
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MAGNESIUM isotopes , *DIFFUSION , *SILICATES , *FUSION (Phase transformation) , *IGNEOUS rocks , *CHEMICAL processes , *MASS transfer - Abstract
Abstract: Laboratory experiments are used to document isotopic fractionation of magnesium by chemical diffusion in a silicate melt and the results compared to the magnesium isotopic composition across contacts between igneous rocks of different composition in natural settings. The natural samples are from transects from felsic to mafic rocks at Vinal Cove in the Vinalhaven Intrusive Complex, Maine and from the Aztec Wash pluton in Nevada. Two laboratory diffusion couples made by juxtaposing melts made from powders of the felsic and mafic compositions sampled at Vinal Cove were annealed at about 1500°C for 22.5 and 10h, respectively. The transport of magnesium in the diffusion couples resulted in easily measured magnesium isotopic fractionations at the interface (δ 26Mg∼1.5‰). These isotopic fractionations provide a distinctive isotopic “fingerprint” that we use to determine whether chemical gradients in natural settings where melts of different composition were juxtaposed were due to chemical diffusion. The magnesium isotopic fractionation along one profile at Vinal Cove is exactly what one would expect based on the fractionations found in the laboratory experiments. This is an important result in that it shows that the isotope fractionation by chemical diffusion found in highly controlled laboratory experiments can be found in a natural setting. This correspondence implies that chemical diffusion was the dominant process responsible for the transport of magnesium across this particular contact at Vinal Cove. A second Vinal Cove profile has a very similar gradient in magnesium concentration but with significantly less magnesium isotopic fractionation than expected. This suggests that mass transport at this location was only partly by diffusion and that some other mass transport mechanism such as mechanical mixing must have also played a role. The magnesium isotopic composition of samples from Aztec Wash shows no resolvable isotopic fractionation across the contact between the mafic and felsic rocks. The different degrees of magnesium isotopic fractionation associated with otherwise similar composition gradients in natural settings show that kinetic isotope fractionations provide a key discriminator for establishing whether or not molecular diffusion was the process responsible for an observed elemental gradient. In the one case of a contact at Vinal Cove where we are confident that the magnesium elemental and isotopic gradients were produced by diffusion, we deduced a cooling rate of about 1.5°C per day. [Copyright &y& Elsevier]
- Published
- 2012
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6. Isotopic mass dependence of metal cation diffusion coefficients in liquid water
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Bourg, Ian C., Richter, Frank M., Christensen, John N., and Sposito, Garrison
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ATOMIC mass , *METAL ions , *DIFFUSION , *WATER , *ISOTOPE geology , *HYDRODYNAMICS , *CHEMICAL kinetics , *MOLECULAR dynamics , *SIMULATION methods & models - Abstract
Abstract: Isotope distributions in natural systems can be highly sensitive to the mass (m) dependence of solute diffusion coefficients (D) in liquid water. Isotope geochemistry studies routinely have assumed that this mass dependence either is negligible (as predicted by hydrodynamic theories) or follows a kinetic-theory-like inverse square-root relationship (D ∝ m −0.5). However, our recent experimental results and molecular dynamics (MD) simulations showed that the mass dependence of D is intermediate between hydrodynamic and kinetic theory predictions (D ∝ m − β with 0⩽ β <0.2 for Li+, Cl−, Mg2+, and the noble gases). In this paper, we present new MD simulations and experimental results for Na+, K+, Cs+, and Ca2+ that confirm the generality of the inverse power-law relation D ∝ m − β . Our new findings allow us to develop a general description of the influence of solute valence and radius on the mass dependence of D for monatomic solutes in liquid water. This mass dependence decreases with solute radius and with the magnitude of solute valence. Molecular-scale analysis of our MD simulation results reveals that these trends derive from the exponent β being smallest for those solutes whose motions are most strongly coupled to solvent hydrodynamic modes. [Copyright &y& Elsevier]
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- 2010
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7. Isotopic fractionation of the major elements of molten basalt by chemical and thermal diffusion
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Richter, Frank M., Watson, E. Bruce, Mendybaev, Ruslan, Dauphas, Nicolas, Georg, Bastian, Watkins, James, and Valley, John
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IRON isotopes , *THERMAL diffusivity , *ATOMIC mass , *SEPARATION (Technology) , *ANALYTICAL chemistry , *BASALT , *RHYOLITE , *THERMAL analysis - Abstract
Abstract: Samples produced in piston cylinder experiments were used to document the thermal isotopic fractionation of all the major elements of basalt except for aluminum and the fractionation of iron isotopes by chemical diffusion between a natural basalt and rhyolite. The thermal isotopic fractionations are summarized in terms of a parameter Ωi defined as the fractionation in per mil per 100°C per atomic mass units difference between the isotopes. For molten basalt we report Ω Ca =1.6, Ω Fe =1.1, Ω Si =0.6, Ω O =1.5. In an earlier paper we reported Ω Mg =3.6. These fractionations represent a steady state balance between thermal diffusion and chemical diffusion with the mass dependence of the thermal diffusion coefficient being significantly larger than the mass dependence of the chemical diffusion coefficients for isotopes of the same element. The iron isotopic measurements of the basalt–rhyolite diffusion couple showed significant fractionation that are parameterized in terms of a parameter β Fe =0.03 when the ratio of the diffusion coefficients D 54 and D 56 of 54Fe and 56Fe is expressed in terms of the atomic mass as D 54/D 56 = . This value of β Fe is smaller than what we had measured earlier for lithium, magnesium and calcium (i.e., β Li =0.215, β Ca =0.05, β Mg =0.05) but still significant when one takes into account the high precision with which iron isotopic compositions can be measured (i.e., ±0.03‰) and that iron isotope fractionations at magmatic temperatures from other causes are extremely small. In a closing section we discuss technological and geological applications of isotopic fractionations driven by either or both chemical and thermal gradients. [Copyright &y& Elsevier]
- Published
- 2009
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8. Magnesium isotope fractionation in silicate melts by chemical and thermal diffusion
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Richter, Frank M., Watson, E. Bruce, Mendybaev, Ruslan A., Teng, Fang-Zhen, and Janney, Philip E.
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DIFFUSION , *MAGNESIUM , *IGNEOUS rocks , *ISOTOPES - Abstract
Abstract: Two types of laboratory experiments were used to quantify magnesium isotopic fractionations associated with chemical and thermal (Soret) diffusion in silicate liquids. Chemical diffusion couples juxtaposing a molten natural basalt (SUNY MORB) and a molten natural rhyolite (Lake County Obsidian) were run in a piston cylinder apparatus and used to determine the isotopic fractionation of magnesium as it diffused from molten basalt to molten rhyolite. The thermal diffusion experiments were also run in a piston cylinder apparatus but with a sample made entirely of molten SUNY MORB displaced from the hotspot of the assembly furnace so that the sample would have a temperature difference of about 100–200°C from one end to the other. The chemical diffusion experiments showed fractionations of 26Mg/24Mg by as much as 7‰, which resulted in an estimate for the mass dependence of the self-diffusion coefficients of the magnesium isotopes corresponding to with β =0.05. The thermal diffusion experiments showed that a temperature difference of about 100°C resulted in the MgO, CaO, and FeO components of the basalt becoming slightly enriched by about 1wt% in the colder end while SiO2 was enriched by several wt% in the hotter end. The temperature gradient also fractionated the magnesium isotopes. A temperature difference of about 150°C produced an 8‰ enrichment of 26Mg/24Mg at the colder end relative to the hotter end. The magnesium isotopic fractionation as a function of temperature in molten basalt corresponds to 3.6×10−2‰/°C/amu. [Copyright &y& Elsevier]
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- 2008
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9. Elemental and isotopic fractionation of Type B CAI-like liquids by evaporation
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Richter, Frank M., Janney, Philip E., Mendybaev, Ruslan A., Davis, Andrew M., and Wadhwa, Meenakshi
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SILICON , *EVAPORATION (Chemistry) , *MOISTURE , *MAGNESIUM - Abstract
Abstract: Vacuum evaporation experiments with Type B CAI-like starting compositions were carried out at temperatures of 1600, 1700, 1800, and 1900°C to determine the evaporation kinetics and evaporation coefficients of silicon and magnesium as a function of temperature as well as the kinetic isotope fractionation factor for magnesium. The vacuum evaporation kinetics of silicon and magnesium are well characterized by a relation of the form J = J oe−E/RT with J o =4.17×107 molcm−2 s−1, E =576±36kJmol−1 for magnesium, J o =3.81×106 molcm−2 s−1, E =551±63kJmol−1 for silicon. These rates only apply to evaporation into vacuum whereas the actual Type B CAIs were almost certainly surrounded by a finite pressure of a hydrogen-dominated gas. A more general formulation for the evaporation kinetics of silicon and magnesium from a Type B CAI-like liquid that applies equally to vacuum and conditions of finite hydrogen pressure involves combining our determinations of the evaporation coefficients for these elements as a function of temperature (γ = γ 0e−E/RT with γ 0 =25.3, E =92±37kJmol−1 for γ Si; γ 0 =143, E =121±53kJmol−1 for γ Mg) with a thermodynamic model for the saturation vapor pressures of Mg and SiO over the condensed phase. High-precision determinations of the magnesium isotopic composition of the evaporation residues from samples of different size and different evaporation temperature were made using a multicollector inductively coupled plasma mass spectrometer. The kinetic isotopic fractionation factors derived from this data set show that there is a distinct temperature effect, such that the isotopic fractionation for a given amount of magnesium evaporated is smaller at lower temperature. We did not find any significant change in the isotope fractionation factor related to sample size, which we interpret to mean that recondensation and finite chemical diffusion in the melt did not affect the isotopic fractionations. Extrapolating the magnesium kinetic isotope fractionations factors from the temperature range of our experiments to temperatures corresponding to partially molten Type B CAI compositions (1250–1400°C) results in a value of α Mg ≈0.991, which is significantly different from the commonly used value of . [Copyright &y& Elsevier]
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- 2007
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10. Crystallization of melilite from CMAS-liquids and the formation of the melilite mantle of Type B1 CAIs: Experimental simulations
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Mendybaev, Ruslan A., Richter, Frank M., and Davis, Andrew M.
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MELILITE , *CRYSTALLIZATION , *MAGNESIUM , *SILICON - Abstract
Abstract: Type B CAIs are subdivided into B1s, with well-developed melilite mantles, and B2s, with randomly distributed melilite. Despite intensive study, the origin of the characteristic melilite mantle of the B1s remains unclear. Recently, we proposed that formation of the melilite mantle is caused by depletion of the droplet surface in volatile magnesium and silicon due to higher evaporation rates of volatile species compared to their slow diffusion rates in the melt, thus making possible crystallization of melilite at the edge of the CAI first, followed by its crystallization in the central parts at lower temperatures. Here, we present the results of an experimental study that aimed to reproduce the texture observed in natural Type B CAIs. First, we experimentally determined crystallization temperatures of melilite for three melt compositions, which, combined with literature data, allowed us to find a simple relationship between the melt composition, crystallization temperature, and composition of first crystallizing melilite. Second, we conducted a series of evaporation and cooling experiments exposing CAI-like melts to gas mixtures with different oxygen fugacities . Cooling of the molten droplets in gases with resulted in crystallization of randomly distributed melilite, while under more reducing conditions, melilite mantles have been formed. Chemical profiles through samples quenched right before melilite started to crystallize showed no chemical gradients in samples exposed to relatively oxidizing gases , while the near-surface parts of the samples exposed to very reducing gases were depleted in volatile MgO and SiO2, and enriched in refractory Al2O3. Using these experimental results and the fact that the evaporation rate of magnesium and silicon from CAI-like melts is proportional to , we estimate that Type B1 CAIs could be formed by evaporation of a partially molten precursor in a gas of solar composition with . Type B2 CAIs could form by slower evaporation of the same precursors in the same gas with . [Copyright &y& Elsevier]
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- 2006
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11. Kinetic isotopic fractionation during diffusion of ionic species in water
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Richter, Frank M., Mendybaev, Ruslan A., Christensen, John N., Hutcheon, Ian D., Williams, Ross W., Sturchio, Neil C., and Beloso, Abelardo D.
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LITHIUM , *POTASSIUM , *IONS , *DIFFUSION , *SEPARATION (Technology) - Abstract
Abstract: Experiments specifically designed to measure the ratio of the diffusivities of ions dissolved in water were used to determine . The measured ratio of the diffusion coefficients for Li and K in water (DLi/DK =0.6) is in good agreement with published data, providing evidence that the experimental design being used resolves the relative mobility of ions with adequate precision to also be used for determining the fractionation of isotopes by diffusion in water. In the case of Li, we found measurable isotopic fractionation associated with the diffusion of dissolved LiCl . This difference in the diffusion coefficient of 7Li compared to 6Li is significantly less than that reported in an earlier study, a difference we attribute to the fact that in the earlier study Li diffused through a membrane separating the water reservoirs. Our experiments involving Mg diffusing in water found no measurable isotopic fractionation . Cl isotopes were fractionated during diffusion in water whether or not the co-diffuser (Li or Mg) was isotopically fractionated. The isotopic fractionation associated with the diffusion of ions in water is much smaller than values we found previously for the isotopic fractionation of Li and Ca isotopes by diffusion in molten silicate liquids. A major distinction between water and silicate liquids is that water surrounds dissolved ions with hydration shells, which very likely play an important but still poorly understood role in limiting the isotopic fractionation associated with diffusion. [Copyright &y& Elsevier]
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- 2006
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12. Timescales determining the degree of kinetic isotope fractionation by evaporation and condensation
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Richter, Frank M.
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EVAPORATION (Chemistry) , *CONDENSATION , *SOLAR system , *HIGH temperatures - Abstract
Abstract: A first order characteristic of the relative abundance of the elements in solar system materials ranging in size from inclusions in primitive meteorites to planetary sized objects such as the Earth and the Moon is that they are very much like that of the Sun for the more refractory elements but systematically depleted to varying degrees in the more volatile elements. This is taken as evidence that evaporation and and/or condensation were important processes in determining the distinctive chemical properties of solar system materials. In some instances there is also isotopic evidence suggesting evaporation in that certain materials are found enriched in the heavy isotopes of their more volatile elements. Here model calculations are used to explore how the relative rates of various key processes determine the relationship between elemental and isotopic fractionation during partial evaporation and partial condensation. The natural measure of time for the systems considered here is the evaporation or condensation timescale defined as the time it would take under the prevailing conditions for evaporation or condensation to completely transfer the element of interest between the two phases of the system. The other timescales considered involve the rate of change of temperature, the rate at which gas is removed from further interaction with the condensed phase, and the rates of diffusion in the condensed and gas phases. The results show that a key determinant of whether or not elemental fractionations have associated isotopic effects is the ratio of the partial pressure of a volatile element (Pi) to its saturation vapor pressure (Pi,sat) over the condensed phase. Systems in which the rate of temperature change or of gas removal are slow compared to the evaporation or condensation timescale will be in the limit Pi ∼ Pi,sat and thus will have little or no isotopic fractionation because at the high temperatures considered here there is negligible equilibrium fractionation of isotopes. If on the other hand the temperature changes are relatively fast, then Pi ≠ Pi,sat and there will be both elemental and isotopic fractionation during partial evaporation or partial condensation. Rapid removal of evolved gas results in Pi ≪ Pi,sat which will produce isotopically heavy evaporation residues. Diffusion-limited regimes, where transports within a phase are not sufficiently fast to maintain chemical and or isotopic homogeneity, will typically produce less isotopic fractionation than had the phases remained well mixed. The model results are used to suggest a likely explanation for the heavy silicon and magnesium isotopic composition of Type B CAIs (as due to rapid partial melting and subsequent cooling at rates of a few °C per hour), for the uniformity of the potassium isotopic composition of chondrules despite large differences in potassium depletions (as due to volatilization of potassium by reheating in regions of large but variable chondrules per unit volume), and that the remarkable uniformity of the potassium isotopic composition of solar system materials is not a measure of the relative importance of evaporation and condensation but rather due to the solar nebula having evolved sufficiently slowly that materials did not significantly depart from chemical equilibrium. [Copyright &y& Elsevier]
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- 2004
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13. Isotope fractionation by chemical diffusion between molten basalt and rhyolite
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Richter, Frank M., Davis, Andrew M., DePaolo, Donald J., and Watson, E. Bruce
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RHYOLITE , *BASALT , *DIFFUSION , *FIELD-flow fractionation - Abstract
Experimental diffusion couples were used to study chemical diffusion between molten rhyolite and basalt with special emphasis on the associated fractionation of calcium and lithium isotopes. Diffusion couples were made by juxtaposing firmly packed powders of a natural basalt (SUNY MORB) and a natural rhyolite (Lake County Obsidian) and then annealing them in a piston cylinder apparatus for times ranging from 0.1 to 15.7 h, temperatures of 1350–1450°C, and pressures of 1.2–1.3 GPa. Profiles of the major elements and many trace elements were measured on the recovered quenched glasses. The diffusivities of all elements except lithium were found to be remarkably similar, while the diffusivity of lithium was two to three orders of magnitude larger than that of any of the other elements measured. Chemical diffusion of calcium from molten basalt into rhyolite was driven by a concentration ratio of ∼18 and produced a fractionation of 44Ca from 40Ca of about 6 ‰. Because of the relatively low concentration of lithium in the natural starting materials a small amount of spodumene (LiAlSi2O6) was added to the basalt in order to increase the concentration difference between basalt and rhyolite, which was expected to increase the magnitude of diffusive isotopic fractionation of lithium. The concentration ratio between Li-doped basalt and natural rhyolite was ∼15 and the resulting diffusion of lithium into the rhyolite fractionated 7Li from 6Li by about 40‰. We anticipate that several other major rock-forming elements such as magnesium, iron and potassium will also exhibit similarly larger isotopic fractionation whenever they diffuse between natural melts with sufficiently large differences in the abundance of these elements. [Copyright &y& Elsevier]
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- 2003
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14. Elemental and isotopic fractionation of Type B calcium-, aluminum-rich inclusions: experiments, theoretical considerations, and constraints on their thermal evolution
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Richter, Frank M., Davis, Andrew M., Ebel, Denton S., and Hashimoto, Akihiko
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EVAPORATION (Meteorology) , *SILICON , *MAGNESIUM - Abstract
Experiments exposing Type B calcium-, aluminum-rich inclusion (CAI)-like melts at high temperatures to high vacuum or reducing hydrogen-rich gas mixtures were used to determine the rates and consequences of elemental and isotopic fractionation by evaporation. Silicon and magnesium were found to evaporate much faster than calcium and aluminum, and the resulting residual liquid trajectories in composition space are reproduced via a thermodynamic model for the saturation vapor pressure of the evaporating species. Isotopic fractionations associated with evaporation were measured for magnesium. The resulting relationship between fraction of magnesium lost and enrichment of the residue in the heavy isotopes of magnesium follows a Rayleigh fractionation curve with a fractionation factor that is close to, but not exactly, the theoretically expected value. The rate of evaporation is found to be a strong function of temperature, oxygen fugacity, and melt composition, which can be understood and modeled in terms of the dependence of the saturation vapor pressures on these variables. The relationship between evaporation rate, which we measure, and calculated saturation vapor involves empirical evaporation coefficients that we find to be significantly less than one (∼0.1). Analytical and numerical models are used to characterize how diffusion in both the melt and in the surrounding gas affects evaporation rates and the degree of chemical and isotopic fractionation. The experimental data and theoretical considerations are combined to give a parameterization of the rates and consequences of evaporation of Type B CAI-like liquids, which is then used to translate the measured isotopic fractionation of Type B CAIs into constraints on their thermal history. Cooling rates of the order of 10°C per hour are indicated. [Copyright &y& Elsevier]
- Published
- 2002
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15. Erratum to F.M. Richter, P.E. Janney, R.A. Mendybaev, A.M. Davis and M. Wadhwa (2007) “Elemental and isotopic fractionation of Type B CAI-like liquids by evaporation”, Geochimica et Cosmochimica Acta 71, 5544–5564
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Richter, Frank M.
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- 2008
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16. Citation for presentation of the 2008 Houtermans Award to Nicolas Dauphas
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Richter, Frank M.
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- 2009
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17. On the origin of compressional intraplate stresses in South America
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Mendiguren, Jorge A. and Richter, Frank M.
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- 1978
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18. A relation between the driving force and geoid anomaly associated with mid-ocean ridges
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Parsons, Barry and Richter, Frank M.
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- 1980
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19. The rate and consequences of Sr diagenesis in deep-sea carbonates
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Richter, Frank M. and Liang, Yan
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- 1993
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20. Oxygen isotope exchange in a two-layer model of oceanic crust
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Schrag, Daniel P., DePaolo, Donald J., and Richter, Frank M.
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- 1992
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21. Sr isotope evolution of seawater: the role of tectonics
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Richter, Frank M., Rowley, David B., and DePaolo, Donald J.
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- 1992
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22. Fluid flow in deep-sea carbonates: estimates based on porewater Sr
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Richter, Frank M.
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- 1993
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23. Simple models for the geochemical response of the ocean to climatic and tectonic forcing
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Richter, Frank M. and Turekian, Karl K.
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- 1993
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24. Tibetan tectonics from 40Ar/ 39Ar analysis of a single K-feldspar sample
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Richter, Frank M., Lovera, Oscar M., Mark Harrison, T., and Copeland, Peter
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- 1991
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25. Models for the coupled Sr-sulfate budget in deep-sea carbonates
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Richter, Frank M.
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- 1996
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26. Simple models for trace element fractionation during melt segregation
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Richter, Frank M.
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- 1986
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27. Diagenesis and Sr isotopic evolution of seawater using data from DSDP 590B and 575
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Richter, Frank M. and DePaolo, Donald J.
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- 1988
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28. Experiments quantifying elemental and isotopic fractionations during evaporation of CAI-like melts in low-pressure hydrogen and in vacuum: Constraints on thermal processing of CAIs in the protoplanetary disk.
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Mendybaev, Ruslan A., Kamibayashi, Michiru, Teng, Fang-Zhen, Savage, Paul S., Georg, R. Bastian, Richter, Frank M., and Tachibana, Shogo
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SILICON isotopes , *ISOTOPIC fractionation , *PROTOPLANETARY disks , *VACUUM , *COMPUTER assisted instruction , *MAGNESIUM isotopes , *HYDROGEN - Abstract
It is widely believed that the precursors of coarse-grained CAIs in chondrites are solar nebula condensates that were later reheated and melted to a high degree. Such melting under low-pressure conditions is expected to result in evaporation of moderately volatile magnesium and silicon and their mass-dependent isotopic fractionation. The evaporation of silicate melts has been extensively studied in vacuum laboratory experiments and a large experimental database on chemical and isotopic fractionations now exists. Nevertheless, it remains unclear if vacuum evaporation of CAI-like melts adequately describes the evaporation in the hydrogen-rich gas of the solar nebula. Here we report the results of a detailed experimental study on evaporation of a such melt at 1600 °C in both vacuum and low-pressure hydrogen gas, using 1.5- and 2.5-mm diameter samples. The experiments show that although at 2 × 10−4 bar H 2 magnesium and silicon evaporate ∼2.8 times faster than at 2 × 10−5 bar H 2 and ∼45 times faster than in vacuum, their relative evaporation rates and isotopic fractionation factors remain the same. This means that the chemical and isotopic evolutions of all evaporation residues plot along a single evaporation trajectory regardless of experimental conditions (vacuum or low-P H2) and sample size. The independence of chemical and isotopic evaporation trajectories on P H2 of the surrounding gas imply that the existing extensive experimental database on vacuum evaporation of CAI-like materials can be safely used to model the evaporation under solar nebula conditions, taking into account the dependence of evaporation kinetics on P H2. The experimental data suggest that it would take less than 25 min at 1600 °C to evaporate 15–50% of magnesium and 5–20% of silicon from a 2.5-mm diameter sample in a solar nebula with P H2 ∼2 × 10−4 bar and to enrich the residual melt in heavy magnesium and silicon isotopes up to δ25Mg ∼5–10‰ and δ29Si ∼2–4‰. The expected chemical and isotopic features are compatible to those typically observed in coarse-grained Type A and B CAIs. Evaporation for ∼1 h will produce δ25Mg ∼30–35‰ and δ29Si ∼10–15‰, close to the values in highly fractionated Type F and FUN CAIs. These very short timescales suggest melting and evaporation of CAI precursors in very short dynamic heating events. The experimental results reported here provide a stringent test of proposed astrophysical models for the origin and evolution of CAIs. [ABSTRACT FROM AUTHOR]
- Published
- 2021
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29. Thermal and chemical evolution in the early Solar System as recorded by FUN CAIs: Part II – Laboratory evaporation of potential CMS-1 precursor material.
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Mendybaev, Ruslan A., Williams, Curtis D., Spicuzza, Michael J., Richter, Frank M., Valley, John W., Fedkin, Alexei V., and Wadhwa, Meenakshi
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MOLECULAR evolution , *FORSTERITE , *OXYGEN isotopes , *EVAPORATION (Chemistry) , *MAGNESIUM - Abstract
We present the results of laboratory experiments in which a forsterite-rich melt estimated to be a potential precursor of Allende CMS-1 FUN CAI was evaporated into vacuum for different lengths of time at 1900 °C. The evaporation of this melt resulted in residues that define trajectories in chemical as well as magnesium, silicon and oxygen isotopic composition space and come very close to the measured properties of CMS-1. The isotopic composition of the evaporation residues was also used to determine the kinetic isotopic fractionation factors [ α 2,1 (vapor-melt) defined as the ratio of isotopes 2 and 1 of a given element in the evaporating gas divided by their ratio in the evaporating source] for evaporation of magnesium ( α 25,24 for 25 Mg/ 24 Mg), silicon ( α 29,28 for 29 Si/ 28 Si) and oxygen ( α 18,16 for 18 O/ 16 O) from the forsterite-rich melt at 1900 °C. The values of α 25,24 = 0.98383 ± 0.00033 and α 29,28 = 0.99010 ± 0.00038 are essentially independent of change in the melt composition as evaporation proceeds. In contrast, α 18,16 changes from 0.9815 ± 0.0016 to ∼0.9911 when the residual melt composition changes from forsteritic to melilitic. Using the determined values of α 25,24 and α 29,28 and present-day bulk chemical composition of the CMS-1, the composition of the precursor of the inclusion was estimated to be close to the clinopyroxene + spinel + forsterite assemblage condensed from a solar composition gas. The correspondence between the chemical composition and isotopic fractionation of experimental evaporation residues and the present-day bulk chemical and isotopic compositions of CMS-1 is evidence that evaporation played a major role in the chemical evolution of CMS-1. [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
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30. Internal 26Al–26Mg isotope systematics of a Type B CAI: Remelting of refractory precursor solids
- Author
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Kita, Noriko T., Ushikubo, Takayuki, Knight, Kim B., Mendybaev, Ruslan A., Davis, Andrew M., Richter, Frank M., and Fournelle, John H.
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ALUMINUM isotopes , *MAGNESIUM isotopes , *REGRESSION analysis , *CRYSTALLIZATION , *ANORTHITE , *FUSION (Phase transformation) , *SPINEL , *CRYSTAL grain boundaries , *SOLAR system - Abstract
Abstract: High precision SIMS 26Al–26Mg isotope analyses were performed for a pristine Type B1 CAI Leoville 3535-1 on multiple mineral phases that include aluminum-rich zoned melilite mantle (Åk20–Åk60), magnesium-rich melilite (Åk70), fassaite, spinel and anorthite in the core. The data yield a well-defined internal isochron with an inferred initial 26Al/27Al ratio of (5.002±0.065)×10−5, which is lower than those of bulk CAIs and pristine fine-grained CAIs. Assuming homogeneous distribution of 26Al in the early solar system, Leoville 3535-1 formed ∼50ka after the time corresponding to the bulk CAI isochron. One anorthite analysis near the grain boundary adjacent to melilite shows sub-μm-scale heterogeneous magnesium distribution, though the 26Al–26Mg data plot on the isochron regression. Thus, the internal 26Al–26Mg system of the CAI remained closed since the last melting event that crystallized anorthite. High precision magnesium isotope analyses of magnesium-rich minerals (fassaite, magnesium-rich melilite, and spinel) show a small amount of scatter from the regression line (∼0.1‰) beyond analytical uncertainties. Most spinel and some fassaite data are systematically displaced below and above the regression line, respectively. It is likely that spinel remained unmelted at the time of the last melting event, while fassaite and anorthite crystallized from a partial melt. The regression line made by fassaite and anorthite data shows an initial 26Al/27Al ratio indistinguishable from that using all data. Mass dependent fractionation of magnesium isotopes in spinel is the same as those in melilite and fassaite (δ25Mg∼5‰), indicating that magnesium isotope fractionation, presumably from evaporative magnesium loss, predated the last melting event. Thus a majority of the CAI appears to have escaped magnesium isotope exchange with nebular gas during the last melting event, except for the outer rim of the melilite mantle that shows slightly lower δ25Mg values. The 26Al–26Mg systematics of this Leoville Type B CAI suggest it experienced a final melting event at ∼50ka after the initial Al–Mg fractionation event. This may correspond to melting during the active protostar stage (known as “Class I”), during which sporadic high temperature heating events repeatedly affected refractory solids in the solar nebula. [Copyright &y& Elsevier]
- Published
- 2012
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31. Silicon isotopic fractionation of CAI-like vacuum evaporation residues
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Knight, Kim B., Kita, Noriko T., Mendybaev, Ruslan A., Richter, Frank M., Davis, Andrew M., and Valley, John W.
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SILICON isotopes , *SEPARATION (Technology) , *ALUMINUM , *METAL inclusions , *CALCIUM , *MAGNESIUM isotopes , *BULK solids , *HIGH temperatures , *SOLAR system - Abstract
Abstract: Calcium-, aluminum-rich inclusions (CAIs) are often enriched in the heavy isotopes of magnesium and silicon relative to bulk solar system materials. It is likely that these isotopic enrichments resulted from evaporative mass loss of magnesium and silicon from early solar system condensates while they were molten during one or more high-temperature reheating events. Quantitative interpretation of these enrichments requires laboratory determinations of the evaporation kinetics and associated isotopic fractionation effects for these elements. The experimental data for the kinetics of evaporation of magnesium and silicon and the evaporative isotopic fractionation of magnesium is reasonably complete for Type B CAI liquids (Richter F. M., Davis A. M., Ebel D. S., and Hashimoto A. (2002) Elemental and isotopic fractionation of Type B CAIs: experiments, theoretical considerations, and constraints on their thermal evolution. Geochim. Cosmochim. Acta 66, 521–540; Richter F. M., Janney P. E., Mendybaev R. A., Davis A. M., and Wadhwa M. (2007a) Elemental and isotopic fractionation of Type B CAI-like liquids by evaporation. Geochim. Cosmochim. Acta 71, 5544–5564.). However, the isotopic fractionation factor for silicon evaporating from such liquids has not been as extensively studied. Here we report new ion microprobe silicon isotopic measurements of residual glass from partial evaporation of Type B CAI liquids into vacuum. The silicon isotopic fractionation is reported as a kinetic fractionation factor, α Si, corresponding to the ratio of the silicon isotopic composition of the evaporation flux to that of the residual silicate liquid. For CAI-like melts, we find that α Si =0.98985±0.00044 (2σ) for 29Si/28Si with no resolvable variation with temperature over the temperature range of the experiments, 1600–1900°C. This value is different from what has been reported for evaporation of liquid Mg2SiO4 (Davis A. M., Hashimoto A., Clayton R. N., and Mayeda T. K. (1990) Isotope mass fractionation during evaporation of Mg2SiO4. Nature 347, 655–658.) and of a melt with CI chondritic proportions of the major elements (Wang J., Davis A. M., Clayton R. N., Mayeda T. K., and Hashimoto A. (2001) Chemical and isotopic fractionation during the evaporation of the FeO–MgO–SiO2–CaO–Al2O3–TiO2–REE melt system. Geochim. Cosmochim. Acta 65, 479–494.). There appears to be some compositional control on α Si, whereas no compositional effects have been reported for α Mg. We use the values of α Si and α Mg, to calculate the chemical compositions of the unevaporated precursors of a number of isotopically fractionated CAIs from CV chondrites whose chemical compositions and magnesium and silicon isotopic compositions have been previously measured. [Copyright &y& Elsevier]
- Published
- 2009
- Full Text
- View/download PDF
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