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Rhodope placozophagus nov. spec. from the western Gulf of Mexico that actively preys on placozoans is described. This white-translucent rhodopemorph was discovered on glass slides introduced in marine aquariums as part of an assemblage of small organisms including the vorticellids, ciliates, acoela, heliozoans and high populations of placozoans, which correlate with an abundance of this worm-like mollusk. When R. placozophagus comes into contact with placozoans, it immediately everts the anterior portion of the buccal bulb and sucks large portions of the disc-shape organism. The new species is likely to be a specialized predator since it was never observed chasing other microorganisms and especially because it can be reared for several generations while feeding exclusively on placozoans. It is known that the lipid granules called shiny spheres, located in the dorsal epithelium of Trichoplax , contain venoms and toxins that serve as an anti-predator defense. These properties can therefore be transmitted, at least transitorily, to a predator. Apart from one report of Riedl (1959) of Rhodope veranii preying on Trichoplax , no other predator-prey association has been described for placozoans. [ABSTRACT FROM AUTHOR]

The Chalkidiki block is a major domain in the North Aegean that, contrary to other domains in the region, largely escaped thermal perturbations during Tertiary extension. As a result, the Chalkidiki block is an ideal candidate to glean information related to the timing of Mesozoic thermal events using appropriate geochronological techniques. We have undertaken a laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) study (U-Th-Pb on monazites and U-Pb on zircons) coupled with 40 Ar/ 39 Ar dating on nine samples from various structural levels within the thrust system of the Chalkidiki block. The eastern, and structurally lower part of the system revealed a complete isotopic reset of Carboniferous – Early Triassic monazites coeval with partial monazite destruction, REE-mobilisation and formation of apatite-allanite-epidote coronas at ~ 132 Ma, a reaction that is commonly observed in amphibolite-facies rocks. These coronas formed after crystallisation of garnet (i.e., at T > 580 °C) and, in all probability, either close to the peak-temperature conditions (~ 620 °C) on a prograde path or during retrogression between the peak-temperature and the low-temperature boundary of the amphibolite facies. Cooling of these rocks and arrival at mid-crustal levels occurred at 95–100 Ma. By contrast, the western, and structurally uppermost part of the system went through the same event by 120–125 Ma. Further structural considerations with respect to medium-temperature geochronology data imply that syn-metamorphic thrusting must have ceased by early Late Cretaceous. We emphasize that, with the sole exception of the Chalkidiki block, no pre-45 Ma medium-temperature geochronology data are preserved in other North Aegean domains, a feature that is clearly related to the extension-induced thermal perturbation of the region during the Tertiary. [ABSTRACT FROM AUTHOR]

Detrital heavy mineral and bulk rock geochemistry and a review of sandstone petrographic data have been used to investigate the post-collisional effusive magmatism that followed the closure of the Vardar Ocean and the generation of volcanic sediments in a complex and compositionally variable volcanic region. Available petrographic data gives evidence of contributions from three key source areas corresponding to the three main tectonic units: the structurally lower Gneiss–Migmatite Complex (Byala Reka-Kechros and Kesebir-Kardamos domes) and the upper Variegated (Kimi) Complex, both fringed by the low-to-medium-grade Mesozoic rocks of the Circum-Rhodope Belt. Besides the deposition of siliciclastic material, volcanic contributions from both, intermediate and acid products represent an important source of sediment in the area. Despite dominant intermediate to acid volcanic products, volcanic lithic fragments in sandstones (microlithic, lathwork and brown vitric textures) indicate main inputs from intermediate and basic-intermediate products generating questions on the interpretation of volcanic detritus in reconstruction of provenance. Detrital amphibole and pyroxene chemistry is used to characterise the supply of volcanic material as well as the dispersal mechanisms and understand the role played by each of the volcanic centers present in the area in the infill of the north-western Thrace basin. Amphibole chemistry reveals high compositional heterogeneity according to both compositional variability of the numerous volcanic centres active at the time of deposition and presence of metamorphic amphibole. 4 Al and Al T apfu values indicate that most of the amphiboles from the NERZ are not of volcanic origin and their presence can only be attributed to the numerous amphibolite facies metamorphic rocks abundantly documented in the area. Detrital amphibole compositions from the ZKVS indicate major contributions from the Iran Tepe and Zvedzel volcanoes. Analysed detrital clinopyroxenes from the NERZ are mostly diopside–augite, with no hedenbergite or Fe–augite detected. The 4 Al/ 6 Al ratio is comparable with compositions of volcanic pyroxenes from the Momchilgrad–Arda (ZKVS) region and products from the pre-caldera phase of the Borovitza. [ABSTRACT FROM AUTHOR]

In this study, we report the first discovery of microdiamond inclusions in kyanite–garnet schists from the Central Rhodope Mountains in Bulgaria. These inclusions occur in garnets from metapelites that are part of a meta-igneous and meta-sedimentary mélange hosted by Variscan (Hercynian) orthogneiss. Ultra-high-pressure (UHP) conditions are further supported by the presence of exsolved needles of quartz and rutile in the garnet and by geothermobarometry estimates that suggest peak metamorphic temperatures of 750–800 °C and pressures in excess of 4 GPa. The discovery of UHP conditions in the Central Rhodopes of Bulgaria compliments the well-documented evidence for such conditions in the southernmost (Greek) part of the Rhodope Massif. Dating of garnets from these UHP metapelites (Chepelare Shear Zone) using Sm–Nd geochronology indicates a Late Cretaceous age (70.5–92.7 Ma) for the UHP metamorphic event. This is significantly younger than previously reported ages and suggests that the UHP conditions are associated with the Late Mesozoic subduction of the Vardar Ocean northward beneath the Moesian platform (Europe). The present-day structure of the RM is the result of a series of subduction–exhumation events that span the Cenozoic, alongside subsequent post-orogenic extension and metamorphic core complex formation. [ABSTRACT FROM AUTHOR]

In the Chalkidiki Peninsula of northern Greece a thrust complex made of a basement (Vertiskos Unit), a cover (Circum–Rhodope belt) and arc/back-arc units (Chortiatis Magmatic Suite and eastern Vardar Ophiolites) is exposed in the Chalkidiki Peninsula of northern Greece. The complex forms the western part of the Rhodope Metamorphic Province and lies on the hanging-wall of the Kerdylion Detachment, the structure responsible for the exhumation of the Southern Rhodope Core Complex and the most prominent and visible ductile structure related to the Tertiary Aegean extension. The Chalkidiki thrust complex arguably preserves a complete record of Cretaceous deformation and related fabrics. In this contribution we describe the geometry of foliation, stretching lineation and shear sense(s) on a regional scale. The regional foliation strikes NW–SE and displays different patterns in the three studied units: (i) dominantly dipping at low angle in the Vertiskos Unit, (ii) affected by upright folding in the Circum–Rhodope belt and (iii) systematically steeply dipping to the NE in the Chortiatis Magmatic Suite. Stretching lineation trend dominantly SW–NE in the three mentioned units. On the basis of new mapping, neglecting local perturbations and deformation related to Tertiary extension, we infer the regional kinematics of Cretaceous syn-metamorphic thrusting and subsequent exhumation of the metamorphic units. Thrusting took place toward the SW (in present-day coordination) and the related fabrics are recorded throughout the metamorphic pile. On the contrary, exhumation-related fabrics are related to shear toward the NE and are preferentially recorded in the uppermost part of the metamorphic pile suggesting that extension was more localised and of less finite intensity compared to thrusting. [ABSTRACT FROM AUTHOR]

In the Thrace region of NE Greece, the crystallization and post-solidification cooling below 600 °C of the intrusive suite of the Circum-Rhodope Belt arc-related Evros ophiolite span from 176.4 ± 0.93 to 163.5 ± 3.85 Ma. In the underlying Rhodope high-grade metamorphic basement, (ultra-) high-pressure metamafic rocks are cross-cut by orthogneisses with granitoid protoliths and crystallization ages between 160 ± 0.69 and 154 ± 1.5 Ma. This new U–Pb LA–ICP-MS zircon geochronological data provides evidence that the timing of the evolution of the Evros ophiolite coincides, within analytical error, with granitoid magmatism in the underlying high-grade basement. One of the dated metagranitoid rocks cross-cuts amphibolitized eclogite, indicating that the high-pressure conditions have a maximum age of 160 Ma postdating one of the proposed ages of ultra-high pressure conditions in the Rhodope Massif. The currently earliest recognised Rhodope high/ultra-high pressure metamorphic event is therefore related to the subduction setting which formed the Evros ophiolite. Based on these new temporal constraints and the regional tectonic–geochronologic framework, we discuss and update the geodynamic context connected to the Jurassic subduction–collisional setting at the Rhodope continental margin of Eurasia. [ABSTRACT FROM AUTHOR]

We present textural, chemical and U-Th-Pb-age data on monazites from garnet--kyanite (Grt-Ky) metapelites, from the Chepelare Shear Zone (Bulgaria) and the Nestos Shear Zone (Greece), in the Central Rhodope. Samples from both locations have experienced two stages of high temperature metamorphism during Alpine times. The first event involved mid-Mesozoic granulite facies dehydration melting. The second event involved mid-Cenozoic lower-grade fluid-assisted partial melting. The latter is well expressed in adjacent felsic rocks but had limited impact on the Grt-Ky metapelites. Most samples display evidence for strong ductile shearing in the presence of fluids. Monazite is present in the highly foliated matrix and as inclusions in garnet and kyanite. Unlike the inclusions, matrix monazites display features of fluid-assisted dissolution--recrystallization. Y-poor domains with U-Th-Pb ages of between ca. 115 and 165 Ma represent the largest part of the grains. Y-rich domains with mid-Cenozoic ages occur as rims, or as small satellite grains surrounding the Mesozoic grains. The Cenozoic monazite domains crystallized at the expense of the Mesozoic ones and simultaneously incorporated Y provided by the fluid-assisted resorption of garnet. An age of ca. 36 Ma is obtained for the samples of both shear zones, interpreted as dating the main episode of monazite growth during the Cenozoic. Similar ages exist for the crystallization of leucosomes and pegmatites in the adjacent migmatitic gneisses, indicating that the fluids responsible for the precipitation of the Cenozoic monazites were probably released during the crystallization of nearby anatectic melts. Together with associated rutile and biotite, many newly grown monazites show a preferred orientation paralleling the matrix foliation. This supports the hypothesis of dynamic dissolution--precipitation as an efficient mean to promote renewed monazite crystallization during ductile deformation of the host rock at ca. 36 Ma. [ABSTRACT FROM AUTHOR]

The Rhodope Domain in NE Greece is comprised of different tectonometamorphic complexes involved in the Alpine collisional history between the Eurasian and African plates. The Kechros Complex represents the lowermost tectonic unit in East Rhodope, and contains a metamorphic suite of Na–Al-rich leucocratic rocks (i.e., alkali feldspar granites, alkali syenites and syenites) within the Virsini antigorite serpentinite. Based on the calculated P–T pseudosection and superimposed isopleths for a meta-syenite, we have determined a peak pressure and temperature of 1.55±0.03GPa and 550±25°C, suggesting HP metamorphism for leucocratic rocks enclosed in the Virsini serpentinized peridotites. The retrograde conditions suggest a prolonged exhumation history, with equilibration conditions first at P 1.1±0.03GPa and T 580±20°C and then at P 0.55±0.04GPa and T 430±30°C. The P–T conditions suggest an early rapid uplift event followed by a late-stage exhumation period, characterized by rapid cooling at relatively isobaric conditions. Similar metamorphic signatures are also recorded in continental rocks of the Kechros complex (i.e., orthogneisses, metapelites), suggesting that crustal and mantle rocks underwent a common Alpine tectonometamorphic evolution. The exact ages of HP metamorphism in the Kechros Complex are not well constrained, however, a Rb–Sr age of 37Ma from a neighboring orthogneiss records a stage of exhumation that may be contemporaneous with the Eocene HP metamorphism (49–55Ma; i.e., recorded in the Nestos Shear Zone of Central Rhodope). We interpret this to be the result of the eventual closure of the Axios/Vardar Ocean and subsequent subduction of the Apulian continental crust (a promontory of the Africa continent) under the southern margin of the European continent in the late Cretaceous and early Tertiary. [ABSTRACT FROM AUTHOR]

Abstract: In the central Rhodope mountains of Greece a carbonate-bearing metaperidotite lens ∼200×500m in size crops out as part of the high- to ultrahigh-pressure metamorphic Upper Sidironero Complex ∼500m SE of the Gorgona Village, north of Xanthi town. It is composed primarily of coarse grained (3–20mm in size) olivine and orthopyroxene, medium grained clinohumite and medium to fine grained tremolite, chlorite, dolomite, magnesite, talc, antigorite and various spinel phases. Whole-rock chemistry, mineral textures and compositions, and phase diagram calculations show that the metaperidotite was subjected to a prograde HP metamorphism, isofacial with the surrounding migmatitic gneisses, metapelites and amphibolites. The prograde character of metamorphism is demonstrated by inclusions of talc, antigorite, chlorite, dolomite, magnesite and Ti-clinohumite in ferrit-chromite, olivine, and orthopyroxene, as well as of olivine in orthopyroxene, and by the typical change in composition of zoned spinel minerals from ferrit-chromite in the core to chromian spinel at the rim. The prograde path is characterized by successive growth of amphibole, Ti-clinohumite, olivine and orthopyroxene, followed by the breakdown of Ti-clinohumite to olivine+Mg-ilmenite and of chlorite to olivine+spinel, probably during exhumation. The construction of a partial petrogenetic P–T grid in the system CaO–MgO–Al2O3–SiO2–CO2–H2O (CMASCH) for Ca-poor ultramafic bulk compositions has proven highly useful for the reconstruction of the metamorphic evolution and a P–T path, indicating that the use of univariant reactions in mixed volatile systems is highly warranted. The P–T path is clearly constrained to pressures below 1.5–1.7GPa by the absence of clinopyroxene. These pressures are slightly lower than those recorded in the closely associated Jurassic eclogites and much lower than those recorded in the diamond-bearing gneisses 5km to the south in the same tectonic unit. The carbonate-bearing metaperidotite from Gorgona probably represents a fragment of the hydrated mantle wedge. This is indicated by the REE compositions which differ from those of ophiolitic peridotites and resemble those of spinel or garnet peridotites of sub-continental origin. The ultramafic slice was incorporated tectonically into the subduction channel, most likely by tectonic erosion in the Early Jurassic, but did not experience ultrahigh-pressure metamorphism like the nearby metapelites that exhumed along the same subduction channel. [Copyright &y& Elsevier]

Abstract: The Rhodope Metamorphic Province in Bulgaria and Northern Greece has been affected by significant extensional tectonics since the Middle to Late Eocene. An important fault system active in the Eocene and Early Oligocene includes the Ribnovo Fault on the eastern side of the Mesta Basin in Bulgaria and the Vertiskos–Kerdilion Fault in Greece. Together with several minor normal fault relicts identified during this study, these represent an originally west-southwest-dipping, low-angle (at least at the end of faulting) normal fault with greenschist-facies mylonites in the footwall and cataclasites along the fault plane, the Mesta–Kerdilion Detachment, exposed over ca. 150km along strike and about 50km parallel to the slip direction. During the intrusion of several plutons in the Pirin Mountains at ca. 32Ma, the footwall of the fault was uplifted to form a large anticline parallel to fault strike, and the fault was offset by a system of antithetic, northeast-dipping normal faults along the northeastern flank of this anticline (Dobrotino and Breznitsa faults). The Mesta–Kerdilion Detachment was later, in the Miocene, again crosscut and offset by the southwest-dipping Strimon Valley Detachment which accommodated important, core complex-like exhumation to the South, strongly diminishing and finally ceasing towards north. This rotational activity of the Strimon Valley Detachment represents the onset of the extension that led to opening of the Aegean Basin. The Mesta–Kerdilion Detachment can be viewed as a precursor of this, but with slightly different kinematics (i.e. not involving significant vertical-axis rotation) and separated in time from the following events by a phase of relative tectonic quiescence in the Late Oligocene. [Copyright &y& Elsevier]

Abstract: Single and multiphase inclusions in garnet porphyroblasts from the diamond-bearing pelitic gneisses were studied by means of combined Raman Spectroscopy and Electron Scanning Microscopy (SEM/EDX). They are either randomly distributed or with preferred orientation within the garnet host and their dimensions vary from less than 5 up to 60μm. In the single-phase inclusions quartz, rutile, kyanite and graphite dominate. Biotite, zircon, apatite, monazite and allanite are also common. Two types of multiphase inclusions were recognized, hydrous silicate (Type I) and silicate–carbonate (Type II) ones. The carbon-bearing multiphase inclusions predominantly consist of Mg-siderite+graphite+CO2 +muscovite+quartz formed by a high density carboniferous fluid rich in Fe, Mg, Si and less Ca, Mn, Al and K trapped in the growing garnet in a prograde stage of metamorphism at high-pressure (HP) conditions. The carbon-free multiphase inclusions predominantly consist of biotite+quartz+rutile±kyanite+muscovite formed through decompression-dehydration/melting reactions of pre-existing phengite. Single and multiphase inclusions are characterized by polygonal to negative crystal shape formed by dissolution-reprecipitation mechanism between the garnet host and the inclusions during the long lasting cooling period (>100Ma) of the Kimi Complex. [Copyright &y& Elsevier]

Abstract: The monazite Th–Pb chronometer is widely used in a variety of geological contexts but may be affected by interaction with fluids. In the central part of the Rhodope Massif (Greece, Bulgaria), synfolial pegmatite veins were emplaced within two major synmetamorphic shear zones. In the Chepelare shear zone (CZS), which displays no evidence of post-metamorphic fluid flow, consistent monazite Th–Pb ages of ∼36 Ma are interpreted as dating vein emplacement. Higher in the metamorphic pile, zircon and monazite give U–Th–Pb ages of ∼42 Ma for vein emplacement. In the Nestos Shear Zone (NSZ) pegmatites show evidence of post-emplacement interaction with fluids during greenschist facies ductile deformation. Evidence for this includes the precipitation of calcite in microscale tension gashes within feldspar porphyroclasts, and the oxygen isotope disequilibrium between quartz and feldspar. Aqueous carbonic fluids deriving from carbonate lithologies in the footwall of the NSZ are identifiable in the pegmatites by the high δ 18O value of quartz (up to 21.8‰) and the presence of calcium in calcite veinlets. In these samples, some of the monazite grains show large intragrain scattering of Th–Pb age spanning up to ∼12 Ma, with intergrain scattering reaching ∼16 Ma (from ∼39 to ∼55 Ma). Within individual grains, age domains correlate with chemical heterogeneities, and some show a characteristic Ca-excess. These chemical and isotopic alterations are interpreted to be caused by interaction with fluids derived from carbonate lithologies. Complementary U–Pb data on zircons from the NSZ pegmatites yield mostly Mesozoic ages related to an older metamorphic cycle, and an age of ∼48 Ma for one grain with typical magmatic zoning. The Th–Pb ages of 49.3±1.6 to 54.9±1.7 Ma probably relate to the emplacement of the pegmatites. The spread of younger Th–Pb ages (from 38.6±1.1 to 46.2±1.6 Ma) probably reflects the period of fluid circulation during progressive cooling to greenschist facies conditions, or variable perturbations of the monazite isotope system during fluid-assisted greenschist facies deformation. This is consistent with 39Ar–40Ar mica ages of ∼32 to 34 Ma, interpreted as a tighter constraint for the timing of the greenschist facies metamorphism. This study illustrates the capacity of monazite to record distinct events in a single rock and highlights the need for identifying the potential involvement of fluids in order to interpret monazite ages. [Copyright &y& Elsevier]

Abstract: The region located between the Carpathian–Balkan and Aegean arcs, the Moesian Platform and Bulgarian Rhodope, is generally assumed to have been stably attached to the East European craton during the Cenozoic evolution of these arcs. The kinematic evolution of this region is, however, poorly constrained by paleomagnetic analysis. In this paper we provide new paleomagnetic data (800 volcanic and sedimentary samples from 12 localities) showing no significant post-Eocene rotation of the Moesian platform and Rhodope with respect to Eurasia, therefore confirming the stability of this region. We compare this result to a provided review of paleomagnetic data from the South Carpathians (Tisza block) and the Aegean region. The Tisza block underwent 68.4±16.7° of middle Miocene (∼15–10 Ma) clockwise rotation with respect to the Moesian Platform, in line with previous rotation estimates based on structural geology. The stability of the Moesian platform during middle Miocene eastward emplacement of the Tisza block into the Carpathian back-arc supports dextral shear along the Southern Carpathians recorded by 13–6 Ma clockwise strike-slip related rotations in foreland deposits. The new reference direction for the Moesian platform and Rhodope allows accurate quantification of the rotation difference with the west Aegean domain at 38.0±7.2° occurring between 15 and 8 Ma. To accommodate this rotation, we propose that the pivot point of the west-Aegean rotation was located approximately in the middle of the rotating domain rather than at the northern tip as previously proposed. This new scenario predicts less extension southeast of the pivot point, in good agreement with estimates from Aegean structural geology. Northwest of the pivot point, the model requires contraction or extrusion that can be accommodated by the coeval motion of the Tisza Block around the northwestern edge of the Moesian platform. [Copyright &y& Elsevier]

Abstract: Zircons from an eclogite and a diamond-bearing metapelite near the Kimi village (north-eastern Rhodope Metamorphic Complex, Greece) have been investigated by Micro Raman Spectroscopy, SEM, SHRIMP and LA-ICPMS to define their inclusion mineralogy, ages and trace element contents. In addition, the host rocks metamorphic evolution was reconstructed and linked to the zircon growth domains. The eclogite contains relicts of a high pressure stage (ca. 700 °C and >17.5 kbar) characterised by matrix omphacite with Jd40–35. This assemblage was overprinted by a lower pressure, higher temperature metamorphic event (ca. 820 °C and 15.5–17.5 kbar), as indicated by the presence of clinopyroxene (Jd35–20) and plagioclase. Biotite and pargasitic amphibole represent a later stage, probably related to an influx of fluids. Zircons separated from the eclogite contain magmatic relicts indicating Permian crystallization of a quartz-bearing gabbroic protolith. Inclusions diagnostic of the high temperature, post-eclogitic overprint are found in metamorphic zircon domain Z2 which ages spread over a long period (160–95 Ma). Based on zircon textures, zoning and chemistry, we suggest that the high-temperature peak occurred at or before ca. 160 Ma and the zircons were disturbed by a later event possibly at around 115 Ma. Small metamorphic zircon overgrowths with a different composition yield an age of 79±3 Ma, which is related to a distinct amphibolite-facies metamorphic event. The metapelitic host rock consists of a mesosome with garnet, mica and kyanite, and a quartz- and plagioclase-bearing leucosome, which formed at granulite-facies conditions. Based on previously reported micro-diamond inclusions in garnet, the mesosome is assumed to have experienced UHP conditions. Nevertheless, (U)HP mineral inclusions were not found in the zircons separated from the diamond-bearing metapelite. Inclusions of melt, kyanite and high-Ti biotite in a first metamorphic zircon domain suggest that zircon formation occurred during pervasive granulite-facies metamorphism. An age of 171±1 Ma measured on this zircon domain constrains the high-temperature metamorphic event. A second, inclusion-free metamorphic domain yielded an age of 160±1 Ma that is related to decompression and melt crystallization. The similar age data obtained from the samples indicate that both rock types recorded a high-T metamorphic overprint at granulite-facies conditions at ca. 170–160 Ma. This age implies that any high pressure or even ultra-high pressure metamorphism in the Kimi Complex occurred before that time. Our findings define new constraints for the geodynamic evolution for the Alpine orogenic cycle within the northernmost Greek part of the Rhodope Metamorphic Complex. It is proposed that the rocks of the Kimi Complex belong to a suture zone squeezed between two continental blocks and result from a Paleo-ocean basin, which should be located further north of the Jurassic Vardar Ocean. [Copyright &y& Elsevier]

Summary: The Aggitis karst system developed in the marbles of the Rhodope massif. The conditions of the development of its karst drainage network are determined from the geological and geomorphologic settings by means of a microstructural analysis, following Eraso’s method. This analysis shows that the karst conduit network intensely developed in the western part of the mountain Falakro where the majority of the open fractures oriented in the same direction as the hydraulic gradient, while the two directions are perpendicular in its eastern part drained by the spring of Drama. The behaviour of the system was analysed by means of hydrodynamic and water geochemical techniques. Despite the extension of the cave system and of the favourable development conditions of conduits, the functioning appears complex, with a significant storage, and a slow infiltration as well as an easy drainage. On the contrary the Drama karst system, characterised by a low variability in its hydrological and geochemical characteristics does not show any karst functioning. In the Aggitis karst system the initial groundwater flow conditions in combination with the aperture planes of which the directions are in agreement with the hydraulic gradient, favoured the rapid development of a drainage network system. The recharge from a large surface catchment area on non-karstic rocks, through swallow holes in a wide polje contributed to increase the groundwater flow through the karst part of the system, facilitating the development of the conduits. [Copyright &y& Elsevier]

Abstract: Orthogneisses of late-Hercynian protolith age crop out in the Central Rhodope high-grade metamorphic complex, which is part of the Alpine orogen in south-eastern Europe. They compose a tectonic unit bordered by late-Alpine extensional shear zones. These rocks reflect Eocene amphibolite facies migmatization (<750 °C/0.9–0.5 GPa). The low-temperature melting favored zircon inheritance and disturbed mainly the LILE protolith compositions. Despite the intense Alpine metamorphic overprint, the major elements, HFSE and REE reflect the initial composition of the Hercynian protolith. A geochemical data set summarizing 200 whole rock analyses testifies to a calc-alkaline magma differentiation producing a compositional range of tonalite and/or granodiorite to granite and leucocratic granite. Geochemical compositions combined with published isotope and age data suggest dominant I-type protoliths and mixed magma sources including crustal and mantle material, and distinguish between older granitoids of volcanic-arc affinity and probably younger ones of late or post-collision origin. [Copyright &y& Elsevier]

U–Pb ion microprobe (SHRIMP) dating of zircon domains assisted by cathodoluminescence imaging was carried out on (1) a garnet-rich mafic rock and (2) a cross-cutting pegmatoid from the area of Kimi, East Rhodope. Quartz exsolution lamellae in cpx of the garnet-rich mafic rock point to a precursor supersilicic cpx implying pressures >2.5 GPa. This indicates UHP conditions for the studied geotectonic unit and is in line with the (rare) presence of radial cracks around quartz inclusions in garnet, which suggest the former presence of coesite. Bleb-shaped cpx inclusions in garnet may be interpreted as primary inclusions during garnet growth. However, based on their shape and general orientation, the possibility that they represent exsolutions from a precursor majoritic garnet, in an advanced state of recrystallization (coalescing initial needles) remains open and needs further investigation. If the latter is proven true, it implies minimum pressures of 4 GPa.The oscillatory zoned domains of the zircon crystals from the garnet-rich mafic rock yield a weighted mean age at 117.4±1.9 Ma (Early Cretaceous) for the magmatic crystallization of the protolith. The zircon domains characterized by clearly fainted oscillatory zoning and/or U-rich embayments of the same zircon crystals are interpreted as metamorphic domains. They yield a weighted mean age of metamorphism at 73.5±3.4 Ma (Late Cretaceous). Different degrees of Pb loss resulted in discordant ages scattering between the magmatic and metamorphic age. The euhedral oscillatory zoned zircons of the cross-cutting pegmatoid yield a weighted mean age of 61.9±1.9 Ma for the time of emplacement and crystallization of retrograde metamorphic fluids into the middle-upper crust. Two scenarios are considered as possible for the interpretation of the SHRIMP-results and the petrological observations: (1) the protolith was an ultra high pressure melt (probably a grt±cpx cumulate) crystallizing in the mantle at Early Cretaceous times, partly exhumed into the lithosphere by mantle upwelling, and then transferred to a subduction zone and metamorphosed under eclogite-facies conditions in the Late Cretaceous; (2) the protolith was a cumulate within a gabbroic melt crystallizing at high crustal levels in the Early Cretaceous and subsequently metamorphosed under UHP conditions in the Late Cretaceous. Retrograde stages of metamorphism (ca. 500 °C, 0.5 GPa) occurred at 61.9±1.9 Ma.The petrological findings, which provide evidence for UHP conditions for these rocks of the Kimi Unit, combined with the SHRIMP-results, reveal different conditions of rock formation at different times for the Rhodope zone. The existence of a subduction zone in the Late Cretaceous shows that the Rhodope was not metamorphosed as a single geotectonic element but consists of different terranes subducted and exhumed at different times. [Copyright &y& Elsevier]