1. Three-dimensional imaging of carbon clusters in thermally stable nickel silicides by carbon pre-implantation.
- Author
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Park, Iksoo, Seol, Jae Bok, Yoon, Gilsang, and Lee, Jeong-Soo
- Subjects
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FULLERENES , *THREE-dimensional imaging , *ATOM-probe tomography , *RAPID thermal processing , *NICKEL (Coin) - Abstract
• Carbon pre-implantation improves the thermal stability of NiSi. • Carbon clusters are formed the vicinity of NiSi/Si interface. • NiSi agglomeration suppressed by carbon clusters formed at the NiSi/Si interface. • Ni diffusion is inhibited by carbon clusters at the interface of NiSi/Si. • The effect of carbon pre-implantation could be analyzed using atom probe at near-atomic scale. We have investigated effects of carbon pre-implantation (C-implantation) on electrical and morphological properties of nickel silicide (NiSi). C-implanted NiSi showed an improved thermal stability on the electrical characteristics in terms of sheet resistance (R sh) and contact resistivity (ρ c) after rapid thermal annealing (RTA) up to 700 °C. The process temperature window was extended by ~100 °C when the C-implantation with a dose of 1 × 1015 cm−2 was introduced. From transmission electron microscopy (TEM) images, the suppression of NiSi agglomeration was confirmed in the C-implanted NiSi. In order to further understand the role of carbon, atom probe tomography (APT) was performed. The three-dimensional (3D) distribution and composition of elements by APT unveiled the formation of carbon clusters with a diameter ranging from 2 to 10 nm near the NiSi/Si interface. The carbon clusters with a peak concentration of 6.0 at. % at the NiSi/Si interface can effectively suppress NiSi agglomeration and Ni diffusion, resulting in improving thermal stability of the NiSi. [ABSTRACT FROM AUTHOR]
- Published
- 2021
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