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Start Over Author "Hofer, Manuel" Publisher elsevier b.v.
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3. Cross-coupling of arene–gold(III) complexes.

Author

Hofer, Manuel and Nevado, Cristina

Subjects
*COUPLING reactions (Chemistry), *AROMATIC compounds, *GOLD compounds, *ANISOLE, *NUCLEOPHILIC reactions, *LIGANDS (Chemistry)
Abstract

Abstract: The reactivity of electron-deficient arene–gold(III) complexes toward nucleophilic aromatic and heteroaromatic counterparts has been studied. 1-Methylindole proved to be the best reaction partner while trimethoxybenzenes did not react. The ancillary ligand on gold also influenced the reactivity in the order PPh3>P t Bu3>IPr. An oxidative cross-coupling starting from the corresponding gold(I) complexes in presence of hypervalent iodide oxidants was also studied. [Copyright &y& Elsevier]

Published
2013
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