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Abstract: Deposition of trace gases, such as sulfur dioxide (SO2), can affect plant and soil chemistry in different ecosystems. Measurements over a complex ecosystem, like a forest clearing, are necessary to determine more accurate deposition rates that can be used to improve parameterizations and models. The flux-gradient technique was used to determine SO2 fluxes over grass in a clearing at Duke Forest, North Carolina, USA on 25 June – 2 July 2008. The mean flux was −0.037 ± 0.024 μg m−2 s−1. Dew on the canopy enhanced the uptake of SO2, which increased deposition rates. Deposition velocities (Vd ) fluctuated greatly with a mean of 1.00 ± 0.48 cm s−1. The large variation in Vd was not fully captured by estimates determined from a multilayer model (MLM) and a big-leaf model (BLM). Mean deposition velocities derived from the MLM and BLM were 1.25 ± 0.21 cm s−1 and 0.63 ± 0.12 cm s−1, respectively. The model estimations of Vd in this study were probably affected by uncertainties associated with canopy resistance, particularly with stomatal and non-stomatal processes. [Copyright &y& Elsevier]

Abstract: Atmospheric ammonia has been shown to degrade regional air quality and affect environmental health. In-situ measurements of ammonia are needed to determine how ambient concentrations vary in different ecosystems and the extent to which emission sources contribute to those levels. The objective of this study was to measure and compare ammonia concentrations in two Tennessee Valley (USA) ecosystems: a forested rural area and a metropolitan site adjacent to a main transportation route. Integrated samples of atmospheric ammonia were collected with annular denuder systems for ~4weeks during the summer of 2009 in both ecosystems. Ancillary measurements of meteorological variables, such as wind direction and precipitation, were also conducted to determine any relationships with ammonia concentration. Measurements in the two ecosystems revealed ammonia concentrations that were mostly representative of background levels. Arithmetic means were 1.57±0.68μgm−3 at the metropolitan site and 1.60±0.77μgm−3 in the forest. The geometric mean concentrations for both sites were ~1.46μgm−3. Wind direction, and to a lesser extent air temperature and precipitation, did influence measured concentrations. At the metropolitan site, ammonia concentrations were slightly higher in winds emanating from the direction of the interstate highway. Meteorological variables, such as wind direction, and physical factors, such as topography, can affect measurement of ambient ammonia concentrations, especially in ecosystems distant from strong emission sources. The 12-h integrated sampling method used in this study was unable to measure frequent changes in ambient ammonia concentrations and illustrates the need for measurements with higher temporal resolution, at least ~1–2h, in a variety of diverse ecosystems to determine the behavior of atmospheric ammonia and its environmental effects. [Copyright &y& Elsevier]

Abstract: We analyzed net CO2 exchange data from 13 flux tower sites with 27 site-years of measurements over maize and wheat fields across midcontinent North America. A numerically robust “light-soil temperature-VPD”-based method was used to partition the data into photosynthetic assimilation and ecosystem respiration components. Year-round ecosystem-scale ecophysiological parameters of apparent quantum yield, photosynthetic capacity, convexity of the light response, respiration rate parameters, ecological light-use efficiency, and the curvature of the VPD-response of photosynthesis for maize and wheat crops were numerically identified and interpolated/extrapolated. This allowed us to gap-fill CO2 exchange components and calculate annual totals and budgets. VPD-limitation of photosynthesis was systematically observed in grain crops of the region (occurring from 20 to 120 days during the growing season, depending on site and year), determined by the VPD regime and the numerical value of the curvature parameter of the photosynthesis-VPD-response, σ VPD. In 78% of the 27 site-years of observations, annual gross photosynthesis in these crops significantly exceeded ecosystem respiration, resulting in a net ecosystem production of up to 2100g CO2 m−2 year−1. The measurement-based photosynthesis, respiration, and net ecosystem production data, as well as the estimates of the ecophysiological parameters, provide an empirical basis for parameterization and validation of mechanistic models of grain crop production in this economically and ecologically important region of North America. [Copyright &y& Elsevier]