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Abstract: To better understand the role of aqueous alteration on the CI1 parent body, we have analyzed the texture, composition and mineral associations of iron nickel sulfides in four of the five known CI1 chondrites. The most commonly-occurring sulfide present in the CI1 chondrites is the iron-deficient Fe,Ni sulfide pyrrhotite ([Fe,Ni]1−xS), that has a composition close to that of stoichiometric troilite (FeS). Three of the CI1s (Alais, Ivuna and Tonk) also contain pentlandite ([Fe,Ni]9S8), although pentlandite is a rare phase in Ivuna. Cubanite (CuFe2S3) was found in both Alais and Ivuna in this study, although it has also been reported in Orgueil (MacDougall and Kerridge, 1977). The pyrrhotite grains in all four chondrites form hexagonal, rectangular or irregular shapes, and show no evidence of Ni or Co zoning. The pyrrhotite grains in Orgueil and Ivuna are, in general, smaller, and show more “corrosions,” or “embayments,” than those in Alais or Tonk. We suggest that the precursor sulfide present in the CI1 chondrites was troilite which, during brecciation and oxidation on the parent body at a temperature of 100°C or less, converted the troilite to magnetite and pyrrhotite with pentlandite inclusions. Subsequently, continued alteration on the parent body removed pentlandite—partially from Alais, Tonk and Ivuna, completely from Orgueil—leaving behind pyrrhotite with spaces (“corrosions”) where the pentlandite had been. Ni derived from the pentlandite was incorporated into ferrihydrite, onto the surface of which the Ni,Na sulfate Ni-bloedite formed. Based on the size and abundant “corrosions” within pyrrhotite grains, combined with observations from other authors, we conclude that Orgueil and Ivuna have undergone a greater degree of alteration than Alais and Tonk. Further work is needed to assess the conditions under which pentlandite would be dissolved preferentially to pyrrhotite, as the study of terrestrial literature indicates that the latter mineral is preferentially removed. [Copyright &y& Elsevier]

We present a paleomagnetic study of seven CM carbonaceous chondrites. CM chondrites are believed to be some of the most chemically primitive materials available in our solar system and may sample the continuum of transitional objects between asteroids and comets formed in the outer solar system. As such, CM chondrites can help us to understand primordial aspects of the history of the early solar system including protoplanetary disk and planetesimal magnetism. The ferromagnetic assemblage of CM chondrites is composed of a mixture of primary metallic iron, pyrrhotite, and magnetite. The remanent properties are usually dominated by secondary pyrrhotite. Paleomagnetic analyses using thermal and alternating field demagnetization identified a stable origin-trending component of magnetization in the seven studied CM chondrites. In each meteorite, this component is homogeneous in direction at least at the cm scale and is therefore post-accretional. We interpret this stable component as a pre-terrestrial chemical remanent magnetization acquired during crystallization of magnetite and pyrrhotite during parent body aqueous alteration in a field of at least a few μ T ( 2 ± 1.5 μ T ) . Considering the timescale and intensities of primordial magnetic fields, both internally generated fields from a putative dynamo and external fields, generated in the protoplanetary disk, may have been recorded by CM chondrites. It is presently difficult to discriminate between the two hypotheses. Regardless, CM chondrites likely contain the oldest paleomagnetic record yet identified. [ABSTRACT FROM AUTHOR]

Abstract: CR chondrites are considered as one of the most primitive classes of meteorites. Most of them experienced a mild aqueous alteration and show no evidence of significant effect of thermal metamorphism. We present here a search for low degree metamorphic effects in CR chondrites. We studied 15 CR chondrites using different metamorphic indicators: (1) structure and Ni content of metal grains; (2) hydration state of matrix; (3) structure and composition of organic matter. The different metamorphic indicators show that two of the analyzed CR chondrites, GRA 06100 and GRO 03116, experienced thermal metamorphism. Indeed, all of the metal grains in GRA 06100 and half of the metal grains in GRO 03116 show Ni-rich phases; the matrix of GRA 06100 is almost completely dehydrated, and the matrix of GRO 03116 is partially dehydrated; Raman spectra of organic matter in these two meteorites are clearly different from those obtained for organic matter in the other CR chondrites, which resemble Raman spectra of organic matter in unmetamorphosed, CM2 meteorites; IR spectra of insoluble organic matter extracted from GRA 06100 and GRO 03116 show lower carbonyl abundance and higher CH2/CH3 ratio with respect to organic matter of unmetamorphosed chondrites. The other CR chondrites analyzed here lack these characteristics and only show a few metal grains with Ni-rich inclusions. Our results also show that the metamorphic effects observed in GRA 06100 and GRO 03116 are different from those observed in type 3 chondrites, which experienced long-duration metamorphism of radiogenic origin. We infer that thermal processing in these two CRs extended over a short duration and was triggered by impacts. [Copyright &y& Elsevier]

Abstract: We recovered micrometeorites from surface snow layers near the French-Italian station CONCORDIA. The unique weather and isolation conditions of Dome C allowed us to recover micrometeorites that are much better preserved than those extracted from blue ice fields. We have identified a new population of friable fine-grained micrometeorites; the absence of such particles in previous collections can be explained by their destruction by mechanical processes. In contrast to previous collections of micrometeorites, the particles from CONCORDIA Collection are characterized by a high content of Fe-sulfides and an undepleted CI elemental abundance pattern of their fine-grained matrix. These features suggest that micrometeorites from Dome C snow have endured much lower alteration from terrestrial weathering, unlike the micrometeorites recovered from near the margin of the Antarctic ice sheet (Adélie Land). The CONCORDIA particles have well constrained terrestrial ages and, given the low Dome C precipitation rate, the central regions of Antarctica provide a unique opportunity to search for particles from historical meteor showers. [Copyright &y& Elsevier]

• Discovery of a ∼650 km2 impact glass strewnfield in the Central Depression of the Atacama Desert. • cm-sized splash-form glassy objects, called atacamaites, formed by impact at 7.8 ± 0.26 Ma. • Dacitic composition with the addition of a variable iron meteorite contamination, 5 wt.% on average. • Small size, heterogeneity, oxidation state, contamination level distinguish them from tektites. • Impactor was an iron meteoroid, very likely from the IIAB group. Glassy ejecta are associated to a limited number of impact craters, and yet hold key information about hypervelocity impact processes. Here we report on the discovery of a ∼650 km2 impact glass strewnfield in the Central Depression of the Atacama Desert. These cm-sized splash-form objects, that we refer to as atacamaites, are essentially composed of a dacitic glass formed by high-temperature melting of local magmatic rocks, with the addition of a variable iron meteorite contamination, 5 wt.% on average. The most likely nature for the impactor is the IIAB iron group. The fission-track plateau method, on two samples, yielded a mean formation age of 7.83 ± 0.26 Ma. No associated impact crater has been discovered so far, suggesting it may be a relatively small, km-sized crater. The glassy nature, aerodynamic shapes, elevated formation temperature, and low water content are reminiscent of tektites. However, their small size, heterogeneity, oxidation state, significant contamination by the impactor, and likely more proximal provenance distinguish them from tektites. Atacamaites have no equivalent among the few known terrestrial ejected impact glasses, and increase the intriguing diversity of such products that we propose to name "tektoids". [ABSTRACT FROM AUTHOR]

• Snow from central Antarctica offers unique advantages for cosmic dust collection. • Flux measurements with accurate control on the exposure parameter were performed. • The micrometeorites size distributions are measured down to 30 μm. • New constraints on the annual accretion of interplanetary dust by Earth inferred. • Melted/un-melted particles proportion indicates the origin of cosmic dust at 1 AU. The annual flux of extraterrestrial material on Earth is largely dominated by sub-millimetre particles. The mass distribution and absolute value of this cosmic dust flux at the Earth's surface is however still uncertain due to the difficulty in monitoring both the collection efficiency and the exposure parameter (i.e. the area-time product in m2.yr). In this paper, we present results from micrometeorite collections originating from the vicinity of the CONCORDIA Station located at Dome C (Antarctica), where we performed several independent melts of large volumes of ultra-clean snow. The regular precipitation rate and the exceptional cleanliness of the snow from central Antarctica allow a unique control on both the exposure parameter and the collection efficiency. A total of 1280 unmelted micrometeorites (uMMs) and 808 cosmic spherules (CSs) with diameters ranging from 30 to 350 μm were identified. Within that size range, we measured mass fluxes of 3.0 μg.m−2.yr−1 for uMMs and 5.6 μg.m−2.yr−1 for CSs. Extrapolated to the global flux of particles in the 12-700 μm diameter range, the mass flux of dust at Earth's surface is 5 , 200 ± 1200 1500 tons.yr−1 (1 , 600 ± 500 and 3 , 600 ± 700 1000 tons.yr−1 of uMMs and CSs, respectively). We indicate the statistical uncertainties expected for collections with exposure parameters in the range of 0.1 up to 105 m2.yr. In addition, we estimated the flux of altered and unaltered carbon carried by heated and un-heated particles at Earth's surface. The mass distributions of CSs and uMMs larger than 100 μm are fairly well reproduced by the CABMOD-ZoDy model that includes melting and evaporation during atmospheric entry of the interplanetary dust flux. These numerical simulations suggest that most of the uMMs and CSs originate from Jupiter family comets and a minor part from the main asteroid belt. The total dust mass input before atmospheric entry is estimated at 15,000 tons.yr−1. The existing discrepancy between the flux data and the model for uMMs below 100 μm suggests that small fragile uMMs may evade present day collections, and/or that the amount of small interplanetary particles at 1 AU may be smaller than expected. [ABSTRACT FROM AUTHOR]