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Abstract: Two micrometer emission of Ho3+-doped new fluorophosphate glass sensitized by Yb3+ upon excitation of a conventional 980nm laser diode is reported. Based on the measured absorption spectra, the Judd–Ofelt parameters and radiative properties were calculated and discussed. For Yb3+/Ho3+ codoped fluorophosphate glass, the predicted spontaneous transition probability and emission cross-section of Ho3+:5I7→5I8 reaches 73.54s−1 and 4.66×10−21 cm2 , respectively, are much higher than other reported glasses. Larger product of emission cross-section (σem ) and radiative lifetime (τrad ) in the prepared glass shows the prepared glass is expected to be better laser material. In addition, the σem and maximum gain coefficient of Ho3+ in Yb3+/Ho3+ codoped fluorophosphate glass is 12.02% and 12.12% larger than those of Ho3+ singly-doped sample, respectively. The results suggest Yb3+/Ho3+ fluorophosphate glass is a good candidate for efficient 2μm laser. [ABSTRACT FROM AUTHOR]

Highlights: [•] LMA PCF was prepared by sol–gel method and stack-capillary-draw technique. [•] The spectra properties of Yb3+, Al3+ co-doped silica glass were discussed. [•] The laser experiment and laser behaviors were illustrated. [ABSTRACT FROM AUTHOR]

Abstract: Tm3+ and Ho3+ co-doped TeO2–ZnO–Bi2O3 (TZB) glasses were prepared by the conventional melt-quenching method. Two micrometre emission properties of the TZB glasses exited by 808nm Laser Diode (LD) were analyzed and discussed. The Judd–Ofelt parameters, spontaneous radiative transition probabilities and radiative lifetime of Ho3+ were calculated based on the absorption spectra by using Judd–Ofelt theory. The absorption spectra and fluorescence spectra were measured. The predicted spontaneous radiative transition rate of 5I7 → 5I8 of Ho3+ is as high as 466.8 s−1. The result of fluorescence spectra indicates that the maximum emission intensity of Ho3+ 2.0μm and of Tm3+ 1.47μm emission can be achieved at the concentration of 1mol% Tm2O3 and 1mol% Ho2O3 in TZB glasses. The maximum absorption and emission cross-section of Ho3+ near 2.0μm are 0.87×10−20 cm2 at 1951nm and 1.07×10−20 cm2 at 2047nm, respectively. [Copyright &y& Elsevier]

Abstract: The lead-free boron silicon bismuthate glasses were investigated in terms of their physical, optical and structural properties. The physical properties of these glasses have been explored by compositional variation of X-ray diffraction (XRD), differential thermal analysis (DTA) and density. The optical properties of theses glasses have been investigated by UV–Vis and mid-infrared transmittance spectra, and refractive index. The structure of these glasses has been characterized by infrared (IR) absorption and Raman spectra. [Copyright &y& Elsevier]