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• We found no differences in bulk soil C stocks across treatments. • More C found in mineral-associated organic matter with more intensive management. • Results suggest management intensification could increase soil C persistence. Early thinning of loblolly pine plantations can potentially deliver sustainable feedstocks for biofuel/bioenergy. However, the management intensification for increased productivity and the removal of additional biomass from these plantations could reduce carbon (C) inputs belowground and therefore reduce overall ecosystem C storage. Increased fertilization could also affect C stocks, and their relative distribution between soil organic matter (SOM) fractions. We analyzed soil C stocks as a function of soil type and different pine plantation management systems across the Western Gulf region of the United States. Additionally, we analyzed SOM fractions with inherently different stabilization mechanisms and potential C persistence. We found no significant differences in bulk soil C stocks across management intensities or soil types. The early thinning treatment had no effect on the C distribution across each soil organic matter fraction. However, proportionally more C was found in mineral-associated organic matter and less in particulate organic matter in the more intensive management regime treatment, possibly due to higher below ground nutrient inputs and enhanced microbial activity. Our results suggest that management intensification to support biofuel production from loblolly pine plantations will not affect soil C stocks, but may increase their persistence. This study demonstrates that, from a soil C perspective, early thinning of intensively managed loblolly pine plantations has potential as a sustainable biofuel feedstock. [ABSTRACT FROM AUTHOR]

The Quest Carbon Capture and Storage (CCS) project in Alberta, Canada, is a fully integrated project, as it involves the capture, transport, injection, storage of CO 2 , and a measurement, monitoring and verification (MMV) program. The MMV program has two key objectives: a) to ensure containment and b) to ensure conformance. Prior to the start of CO 2 injection at the end of August 2015, a number of projects were undertaken to gather data from various domains, namely the atmosphere, biosphere, hydrosphere and geosphere, to provide input to the Quest MMV program. The focus of this paper is on monitoring activities undertaken in relation to the atmosphere and biosphere domains. Activities undertaken across the Quest sequestration lease area (SLA) included an eddy covariance system, soil gas probes, soil flux chambers, and walk-over surveys. In conclusion, understanding the spatial and temporal variability of CO 2 levels prior to start of CO 2 injection represents an important activity of a CCS MMV program. It provides technical input to the development of such a program, but also provides knowledge for communication to and awareness of project stakeholders (e.g. landowners) regarding CO 2 levels within the atmosphere and biosphere across a SLA. [ABSTRACT FROM AUTHOR]

In Brazil, sugarcane expansion for ethanol production has been predominantly on areas previously used as pasture. Losses of C and N induced by land use change raise controversies about the environmental suitability of biofuel production. Therefore, we conducted a field study within the largest sugarcane-producing region of Brazil to evaluate the effects of the primary land use change (LUC) sequence in sugarcane expansion areas (i.e., native vegetation to pasture to sugarcane), on C and N dynamics in the top 1 m soil layer. The LUC sequences caused substantial but varying changes in soil C and N stocks in areas undergoing expansion of sugarcane in south-central Brazil. The increase of C stocks in areas converted from pasture to sugarcane cultivation was 1.97 Mg ha −1 yr −1 , in contrast to conversion of native vegetation to pasture, which decreased soil C stocks by 1.01 Mg ha −1 yr −1 for 0–1.0 m soil layer. The use of 13 C measurements to partition soil C sources showed that the greater C stocks in sugarcane areas compared to pasture was due to retention of the native-C stocks and increased accrual of modern-C comparing to pasture. Finally, the inclusion of deeper soil layers, at least down to 1.0 m depth, is essential to assess the impacts of LUC on C balances in agricultural areas. [ABSTRACT FROM AUTHOR]

Abstract: Plant-derived carbon compounds enter soils in a number of forms; two of the most abundant being leaf litter and rhizodeposition. Our knowledge concerning the predominant controls on the cycling of leaf litter far outweighs that for rhizodeposition even though the constituents of rhizodeposits includes a cocktail of low molecular weight organic compounds which represent a rapidly cycling source of carbon, readily available to soil microbes. We determined the mineralization dynamics of a major rhizodeposit, glucose, and its relationship to land-use, microbial community and edaphic characteristics across a landscape in the southeastern United States. The landscape consists of cultivated, pasture, pine plantation, and hardwood forest sites (n = 3). Mineralization dynamics were resolved in both winter and summer using an in situ 13C-glucose pulse-chase approach. Mineralization rates of the labeled glucose decline exponentially across the 72 h measurement periods. This pattern and absolute mineralization rates are consistent across seasons. An information-theoretic approach reveals that land-use is a moderately strong predictor of cumulative glucose mineralization. Measures assessing the size, activity, and/or composition of the microbial community were poor predictors of glucose mineralization. The strongest predictor of glucose mineralization was soil-extractable phosphorus. It was positively related to glucose mineralization across seasons and explained 60% and 48% of variation in cumulative glucose mineralization in the summer and winter, respectively. We discuss potential mechanisms underlying the relationship between soil phosphorus and glucose mineralization. Our results suggest that specific soil characteristics often related to land-use and/or land-management decisions may be strong predictors of glucose mineralization rates across a landscape. We emphasize the need for future research into the role of soil phosphorus availability and land-use history in determining soil organic carbon dynamics. [Copyright &y& Elsevier]

Abstract Biofuels are fundamental for meeting societal energy needs within the next few decades, but the sustainability of large-scale land use conversions to supply feedstock crops remains unclear. Quantitative data documenting how biofuel crop expansion will affect ecosystem services (ES) is needed to develop sustainable energy policies. Using pairwise comparisons of published and novel environmental, social and economic indicators, we quantitatively assessed the provision of critical ES related to key aspects of the sustainability of pasture-to-sugarcane transitions in Brazil. We found that with the exception of maintaining biodiversity, conversion of pasturelands to sugarcane fields enhanced many ES. Based on the Sustainability index, aimed to capture changes on key sustainability aspects by considering multiple ES and properly integrating them, we concluded that pasture to sugarcane transitions would increase the sustainability by 78% in south-central Brazil. Our results provide science-based empirical evidence that the expansion of sugarcane into degraded pasturelands is a suitable strategy to enhance Brazil's biomass feedstock supplies for producing bioenergy. Moreover, facing the complex and multidimensional concept of sustainability, our study also illustrates the importance of considering holistically land use change effects rather than individual ESs when establishing sustainable land management practices and bioenergy policies. Graphical abstract Except for Maintenance of biodiversity, the expansion of sugarcane over pasturelands improve many ecosystem services in areas of biofuels expansion. As result, this LUC would increase the sustainability by 78% in south-central Brazil. SOC: soil organic C. FRT: Soil fertility index. H?: Shannon?s diversity index. CYC: C cycling index. STR: Soil structural quality index. SEC: Socioeconomic index. fx1 Highlights • In Brazil, most of the recent sugarcane expansion has been placed over extensive pastures. • Pasture (PA) to sugarcane (SG) transitions affects key ecosystem services (ES). • Except for Maintenance of biodiversity, this land use change improve the ESs evaluated. • As result, PA-SG transitions would increase the sustainability by 78% in south-central Brazil. • Our index provides a sensitive and science-based approach for sustainability assessments. [ABSTRACT FROM AUTHOR]

Land use changes (LUC) from pasture to sugarcane ( Saccharum spp.) crop are expected to add 6.4 Mha of new sugarcane land by 2021 in the Brazilian Cerrado and Atlantic Forest biomes. We assessed the effects of these LUC on the abundance and community structure of animals that inhabit soils belowground through a field survey using chronosequences of land uses comprising native vegetation, pasture, and sugarcane along a 1000-km-long transect across these two major tropical biomes in Brazil. Macrofauna community composition differed among land uses. While most groups were associated with samples taken in native vegetation, high abundance of termites and earthworms appeared associated with pasture soils. Linear mixed effects analysis showed that LUC affected total abundance ( X 2 (1) = 6.79, p = 0.03) and taxa richness ( X 2 (1) = 6.08, p = 0.04) of soil macrofauna. Abundance increased from 411 ± 70 individuals m − 2 in native vegetation to 1111 ± 202 individuals m − 2 in pasture, but decreased sharply to 106 ± 24 individuals m − 2 in sugarcane soils. Diversity decreased 24% from native vegetation to pasture, and 39% from pasture to sugarcane. Thus, a reduction of ~ 90% in soil macrofauna abundance, besides a loss of ~ 40% in the diversity of macrofauna groups, can be expected when sugarcane crops replace pasture in Brazilian tropical soils. In general, higher abundances of major macrofauna groups (ants, coleopterans, earthworms, and termites) were associated with higher acidity and low contents of macronutrients and organic matter in soil. This study draws attention for a significant biodiversity loss belowground due to tropical LUC in sugarcane expansion areas. Given that many groups of soil macrofauna are recognized as key mediators of ecosystem processes such as soil aggregation, nutrients cycling and soil carbon storage, our results warrant further efforts to understand the impacts of altering belowground biodiversity and composition on soil functioning and agriculture performance across LUC in the tropics. [ABSTRACT FROM AUTHOR]

Land use change (LUC) in Brazil for sugarcane ethanol production has raised concerns about its potential environmental impacts. Soil quality is a key indicator to infer about the environmental sustainability of Brazilian ethanol production. Our objective was to quantify the effects of the most common LUC sequence associated with sugarcane expansion ( i.e ., native vegetation to pasture to sugarcane) on chemical attributes in tropical soils. Soil sampling was carried out in three study sites located in central-southern Brazil, primary sugarcane region of production and expansion of the world. Overall, long-term conversions from natural ecosystems to extensive pasturelands decreases available P, S, Ca, Mg and B contents. In addition, the LUC leads to soil acidification and decreases of CEC pH7 , indicating that pasturelands have poor soil chemical quality. The LUC from pasture to sugarcane increases soil nutrient levels and reduces the soil acidity due to inputs of lime and fertilizers. Despite that, increments of available P and base saturation are necessary to achieve ideal soil chemical conditions to sugarcane growth. Overall, our findings suggest that sugarcane expansion in Brazil replacing pasturelands will promotes improvements on soil chemical quality. Nevertheless, sugarcane expansion can be associated with management strategies to increase soil organic matter and improve the soil fertility, reducing the environmental and economic costs associated with ethanol production in Brazil. [ABSTRACT FROM AUTHOR]

Historical data of land use change (LUC) indicated that the sugarcane expansion has mainly displaced pasture areas in Central–Southern Brazil, globally the largest producer, and that those pastures were prior established over native forests in the Cerrado biome. We sampled 3 chronosequences of land use comprising native vegetation (NV), pasture (PA), and sugarcane crop (SC) in the sugarcane expansion region to assess the effects of LUC on soil carbon, nitrogen, and labile phosphorus pools. Thirty years after conversion of NV to PA, we found significant losses of original soil organic matter (SOM) from NV, while insufficient new organic matter was introduced from tropical grasses into soil to offset the losses, reflecting in a net C emission of 0.4 Mg ha − 1 yr − 1 . These findings added to decreases in 15 N signal indicated that labile portions of SOM are preserved under PA. Afterwards, in the firsts five years after LUC from PA to SC, sparse variations were found in SOM levels. After more than 20 years of sugarcane crop, however, there were losses of 40 and 35% of C and N stocks, respectively, resulting in a rate of C emission of 1.3 Mg ha − 1 yr − 1 totally caused by the respiration of SOM from C4-cycle plants. In addition, conversion of pastures to sugarcane mostly increased 15 N signal, indicating an accumulation of more recalcitrant SOM under sugarcane. The microbe- and plant-available P showed site-specific responses to LUC as a function of different P-input managements, with the biological pool mostly accounting for more than 50% of the labile P in both anthropic land uses. With the projections of 6.4 Mha of land required by 2021 for sugarcane expansion in Brazil to achieve ethanol's demand, this explanatory approach to the responses of SOM to LUC will contribute for an accurate assessment of the CO 2 balance of sugarcane ethanol. [ABSTRACT FROM AUTHOR]

Abstract: It is clear that the density and porosity of biochar will impact its mobility in the environment, its interaction with the soil hydrologic cycle, and its suitability as an ecological niche for soil microorganisms. However, the wide range of biochar pore sizes complicates biochar porosity characterization, making it challenging to find methods appropriate to connect the fundamental physical properties of density and porosity to environmental outcomes. Here, we report the use of two fast, simple density measurement techniques to characterize biochar density and porosity. We measured biochar skeletal density by helium pycnometry and envelope density by displacement of a dry granular suspension. We found that biochar skeletal density ranged from 1.34 g cm−3 to 1.96 g cm−3, and increased with pyrolysis temperature. Biochar envelope density ranged from 0.25 g cm−3 to 0.60 g cm−3, and was higher for wood biochars than grass biochars—a difference we attribute to plant cell structures preserved during pyrolysis. We compared the pore volumes measured by pycnometry with those measured by nitrogen gas sorption and mercury porosimetry. We show that biochar pore volumes measured by pycnometry are comparable to the values obtained by mercury porosimetry, the current benchmark method. We also show that the majority of biochar pore volume is in macropores, and thus, is not measured by gas sorption analysis. These fast, simple techniques can now be used to study the relationship between biochar's physical properties and its environmental behaviors. [Copyright &y& Elsevier]

Lignocellulosic bioenergy crops are a potential option for climate mitigation and for meeting the targets of the Paris Agreement in Europe. The PopFor process-based model has been developed based on the earlier MiscanFor model and parameterised for poplar using data from a literature review in combination with experimental data on high performing clones Max 1, 3, 4 for extensively and intensively managed sites in Germany. PopFor needs comparatively few input data to provide accurate estimates of biomass yield. The parameters found allowed a good match to measured values. The best fit for bud emergence is 81 °days (base 5), with leaf emergence at 463 °days (base 5) and the temperature at which photosynthesis slows is 28 °C. Maximum radiation use efficiency was set to 2.9 gMJ−1. The air temperature threshold that kills crop was set at −37 °C with the number of days below this threshold that kills the crop set at 90 days. 30 days below wiltpoint was set as a threshold that kills the crop from drought. It was found that plant available water was the key explanatory variable in predicting yield and access to groundwater explained 97% of the yield variation between the sites. The results show that the model estimates the yield of poplar after the establishment phase with a mean difference of 0.27 DM t ha−1 y−1 (r2 0.99, n29, F = 4.18, p < 0.05 with RMSE = 19.68%). PopFor was shown to be an effective model for predicting yields under different soil conditions. Image 1 • New poplar model for predicting yield estimates on a local or larger scale. • PopFor needs only soil and weather data, no diameter or stem measurements. • PopFor accurately modelled yield for 2nd rotation and intensively managed 1st rotation poplar coppice. • PopFor parameters are widely applicable. • PopFor is a suitable tool for defining the most suitable areas for poplar bioenergy. [ABSTRACT FROM AUTHOR]