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The Zinvinjian polymetallic deposit occurs as veins controlled by a NW–SE trending–structure within the Cretaceous metamorphosed limestone and dolomite, schist, and metavolcanic rocks, northwest of Iran. The retrograde greenschist facies metamorphism was accompanied by large–scale transpressional faulting, crack–seal veins, infiltration of large volumes of hydrous fluid with high X CO 2 , and is largely overlapped by the main hydrothermal events. The metamorphism has resulted in two stages of mineralization in the Zinvinjian deposit. These are early–stage polymetallic sulfides–quartz and late–stage pyrite–quartz veins. The early–stage veins filled fractures and are undeformed, suggesting a tensional shear setting. The late–stage veins are also mainly open–space fissure–fillings that cut or replace earlier veins. Three types of fluid inclusions (FIs), including aqueous (type–I), mixed carbonic–aqueous (type–II), and carbonic (type–III), were identified in ore–related quartz veins. The early–stage quartz contained all three types of primary FIs homogenized at temperatures of range 197–300 °C and salinities of 2.5–15.2 wt% NaCl equivalent. In contrast, the late–stage quartz veins contained only type–I FIs with homogenization temperatures ranging between 192 and 210 °C, and salinities of 0.2–2.7 wt% NaCl equivalent. This indicates that the metallogenic system evolved from a carbonic–rich, metamorphic fluid to a carbonic–poor, one through input of meteoric fluids. All three types of FIs in the early–stage minerals displayed evidence of vein formation during an episode of fluid immiscibility. Quartz δ 18 O (+ 15.3 to + 19.0‰) and sulfide δ 34 S (− 9.4 to + 11.6‰) indicate isotopic equilibrium with host metasediments (rock buffering) and a metasedimentary source of sulfur during early–stage. It is believed that ore mineralization is the result of a decrease in base–metal solubility during an episode of the fluid immiscibility. This study suggests that mineralization at the Zinvinjian deposit is metamorphogenic in style, probably related to a deep–seated orogenic system. [ABSTRACT FROM AUTHOR]

The Iju Cu porphyry is located in the NW part of the Kerman Magmatic Copper Belt (KMCB). It is related to a ~ 9 Ma granodiorite porphyry intrusion, with three main stages of hydrothermal activity. The homogenization temperatures for the fluid inclusions are in the ranges of 200–494 °C, and their salinities vary from 4.0 to 42.8 wt% NaCl equiv., which are typical magmatic-hydrothermal fluids. The δ34S values of sulfides range from −0.4 to +3.2 ‰ (V-CDT), and the δ34S values of anhydrite samples range from +11.6 to +16.8 ‰. The δ34S values of sulfides show a narrow range, implying a homogeneous sulfur source. The oxygen isotopic composition of hydrothermal water in equilibrium with quartz samples ranges from +3.4 to +6.0 ‰ (V -SMOW) consistent with the hydrothermal fluids having a magmatic signature, but diluted with meteoric waters in the main mineralizing stage. The most important factors responsible for metal precipitation in the Iju porphyry deposit are fluid boiling, oxygen fugacity decrease and cooling followed by dilution with meteoric water. The primary fluids of the Iju Cu deposit are characterized by relatively high temperature and moderate salinity, and are CO 2 -rich, indicating a typical post-collisional porphyry system. [ABSTRACT FROM AUTHOR]

[Display omitted] • FIs microthermometry is helpful for deciphering the PT condition of deformation. • The results highlight the correlation between microstructures and fluid inclusions. • Different types of Fls reflect different PT conditions during polyphase deformation. • The findings provide insights about the paleofluids evolution in the SSMB, SW Iran. An investigation into the correlation between microstructural characteristics and deformation temperatures of quartz in the middle crust is of utmost importance in yielding substantial knowledge of the nature of deformation zones. Mylonitic rocks from the Gol-e-Gohar Shear Zone were investigated to infer innovative insights into the ductile deformation pressure–temperature (PT) conditions of the Sanandaj–Sirjan metamorphic rocks within the Zagros, southwest Iran. This approach used a multi-method strategy including quartz c-axis fabrics, recrystallization mechanisms and fluid inclusions (Fls) data. Geothermobarometric analysis based on these data highlight deformational PT conditions ranging from ∼400 to ∼500 °C and P < 5 kbar that correspond to ductile deformation with greenschist to lower-amphibolite conditions at depth of ∼ 12–19 km. Measured opening angles of quartz c-axis fabric and dominance of basal < a > slip system indicate crystal plastic deformation occurred in T > 400 °C. Microstructures highlighting the occurrence of Grain Boundary Migration (GBM) confirm temperature of 500–600 °C. The deduced P–T–salinity Fls history of deformation-related fluid inclusions is highlighted by Fls (B-type) with H 2 O-CO 2 –rich metamorphic fluids. These fluids were trapped during ductile deformation in temperatures ranging from ∼ 355 to ∼ 535 °C and pressure of P < 5 kbar. The petrofabric analyses show that the mylonitic rock in the Gol-e-Gohar shear zone have undergone metamorphism at the amphibolite facies condition, and then followed by a retrograde greenschist facies metamorphism. These results emphasize the utility of microstructural and fluid inclusion techniques to constrain the history of mylonitic rocks exhumation in the deformation zones. [ABSTRACT FROM AUTHOR]

This study presents copper isotope compositions of mineralized whole-rock samples from the Kerman porphyry copper belt (KPCB) southeast of the Urumieh Dokhtar magmatic arc. Samples for this study were specifically collected from the Sar Cheshmeh, Meiduk, Iju, SarKuh, Darreh Zar, Bagh Khoshk, and Jebal Barez deposits and investigated to study the application of Cu isotopes to mineral exploration. While in the leached cap zone of the deposits, δ65Cu values range between −3.41 to 5.82 ‰ (avg. 0.42 ‰), in the supergene enriched zone of these deposits the relatively higher δ65Cu content ranges from 5.18 to 8.71 ‰ (avg. 7.17 ‰), and in the hypogene zone, the intermediate δ65Cu values range from 1.49 to 7.31 ‰ (avg: 4.36 ‰). Most measured δ65Cu values in these investigated porphyry copper deposit are positive, which indicates the presence of a Cu − enriched zone. In the enriched leached cap zones, the δ65Cu of the Darreh Zar and Sar Cheshmeh deposits are overall higher relative to the Iju, Meiduk, SarKuh, and Bagh Khoshk deposits, and these higher δ65Cu values are associated with the highest Cu grade and tonnage in the Sar Cheshmeh and Darreh Zar deposits. It is therefore plausible to conclude that the higher δ65Cu value in the leached areas are diagnostic of the high concentration of copper. These findings are complemented by the presence of Cu (II) carbonates, silicates, and Fe − oxides in each sample that has resulted in the enrichment of 65Cu, relative to the remnant sulfides with a wider copper isotope range. In addition, there is a general shift toward higher δ65Cu isotope values relative to the inferred precursor minerals. The overall apparent weathering and oxidative dissolution is likely to have generated isotopically heavier fluids and lighter residual minerals. The elevated δ65Cu of the bulk samples from porphyry Cu deposits in KPCB is consistent with a preferential loss of 63Cu into fluids during the segregation of aqueous fluid–melt. This is best explained by several pulses of hypogene magmatic fluid which led to repeated enrichment in 65Cu in the magmatic system. It is plausible to conclude that copper isotope values in these mineralized samples can be used as an effective exploration tool to identify buried porphyry Cu systems. • Copper isotopic composition of whole rock samples shows a wide range up to 8 ‰. • High Cu isotope can be an indicator for the presence of an inherited Cu–enriched magma. • Oxidative dissolution generate isotopically heavier fluids and lighter residual minerals. • Whole-rock Cu isotope seem closely related to the Cu grade and tonnage of KPCB deposits. • Whole-rock Cu isotope is a helpful tool for prospecting means ore exploration. [ABSTRACT FROM AUTHOR]

Abstract This investigation of leached caps in Meiduk and Parkam porphyry copper deposits (PCD) in Kerman Cenozoic magmatic arc (KCMA) of SW Iran indicated that the fertility of supergene enrichment zones may be inferred from the mineralogical and geochemical characteristics of their associated leached caps. That is, the indigenous mature leached caps characterized by strong leaching of Cu, large ion lithophile elements (LILEs), and high field strength elements (HFSEs), commonly form above intrusions where supergene enrichment is strongly developed. Mineralogically, these leached caps (e.g., SE Meiduk) are characterized by abundant hematite and minor goethite (Hem:Gt ≈ 5.48), whereas immature leached caps (e.g., NW Meiduk and Parkam) are associated with poorly developed supergene enrichment zones characterized by abundant goethite (Hem:Gt ≈ 0.56 for NW Meiduk and 0.38 for Parkam), boxwork textures, secondary copper minerals and remnant pyrite. Calculated rock quality designation (RQD) from drilling cores in Meiduk deposit also revealed the relation between joint density and the extent of supergene enrichment. Moreover, increasing the rare earth elements (REEs) content in the immature and fewer REEs concentration in the mature leached caps also reflects the fertility of supergene enrichment zone in PCDs. Highlights • The fertility of supergene zone is reflected in the mineralogical and geochemical characteristics of their associated leached caps. • Calculated rock quality designation (RQD) revealed the extent of supergene enrichment. • REEs are the best geochemical indicators for supergene enrichment development. [ABSTRACT FROM AUTHOR]

The purpose of this research is to provide an efficient method for simulating the Vibro-acoustic modulation (VAM) effect in beam-type structures. Contact acoustic nonlinearity (CAN) can be induced by support loosening, which is a common defect in engineering systems. The appearance of sidebands caused by wave intermodulation is the basis of VAM based Structural Health Monitoring (SHM). The VAM simulation can be used for high level SHM, such as damage imaging, to provide some insights into the intermodulation mechanism and influencing factors. In this research, the Fourier spectral element method (FSEM) is used to simulate and investigate the VAM effect for the beam structures. The clamped support is represented by an elastic foundation that can be released by lowering its stiffness. The transducers, which contained three piezoelectric patches, two for high and low frequency actuation and one for sensing, were also incorporated in the numerical model. The Lagrange multiplier method and the node-to-node contact strategy were used to formulate the contact problem. The forward increment Lagrange multipliers approach was utilized for time integration. The results are consistent with the previous studies on beams with loosened supports. Furthermore, the FSEM results were compared to their FEM counterparts to assess the former's efficacy. The impact of loosening intensity on VAM signals and damage metrics was investigated using the FSEM model. According to the results, the FSEM has a high convergence rate and accuracy, making it a good choice for improving VAM-based damage identification. • Modeling of contact nonlinearity in loose support using Fourier spectral element for beam. • Contact nonlinearity was modeled using Lagrange Multiplier and verified by experimental data. • Fourier spectral element simulation reduced computational time compared to FEM. • Accuracy of Fourier spectral element method to model vibro-acoustic modulation. • Investigating the contact mechanism as well as the growth of sidebands due to defect size evolution. [ABSTRACT FROM AUTHOR]

This study is a 2D basin modeling to determine the petroleum system (i.e. Cretaceous-Neogene play) of the Karanj and Parsi oilfields in the Southern Dezful Embayment, SW Iran. This system is characterized by occurrence of source rocks of Middle Cretaceous, Late Cretaceous and Paleocene to Eocene (Kazhdumi, Pabdeh and Gurpi Formation), reservoirs of Upper Cretaceous and Late Oligocene–Early Miocene (Ilam-Sarvak and Asmari formations), and seals of Paleocene and Miocene (Pabdeh and Gachsaran Formation). Considering temperature, transformation ratio and vitrinite reflectance, the maturity of source rocks (Kazhdumi, Pabdeh and Gurpi Formation) was investigated. A maturity history analysis showed that the maturity of Kazhdumi, Pabdeh and Gurpi Formation started during 70–60 and 4 Ma, respectively. Generation and expulsion of hydrocarbons started ~16 Ma in the Kazhdumi Formation and ~3 Ma in the Pabdeh Formation that continued up to the present. The analysis of the transformation ratio indicates transformation of significant amounts of Kazhdumi source rocks for generating hydrocarbons. Migration of hydrocarbons from the Kazhdumi Formation is mainly vertically upward. From Pabdeh Formation migration is both vertically upward (to the Asmari reservoir) and downwards (to the Ilam-Sarvak reservoir). However, some local traps have formed due to the hydrocarbon accumulation above the faults. Our results reveal that petroleum generation, migration and entrapment occurred at proper timing which facilitated the migration of hydrocarbons and their accumulation in the reservoirs. • This study is a 2D modeling to identify the petroleum system in SW Iran. • Generation and expulsion of hydrocarbons started ~16 Ma in the Kazhdumi Formation. • Some of the produced oil from Kazhdumi Source rock is cracked into gas. • Some traps have formed due to the hydrocarbon accumulation above the faults. [ABSTRACT FROM AUTHOR]

The present work attempts to discriminate between the geochemical features of magmatic-hydrothermal systems involved in the early stages of mineralization in high grade versus low grade porphyry copper systems, using chemical compositions of silicate and sulfide minerals (i.e., plagioclase, biotite, pyrite and chalcopyrite). The data indicate that magmatic plagioclase in all of the porphyry copper systems studied here has high An% and Al content with a significant trend of evolution toward AlAl 3 SiO 8 and □Si 4 O 8 endmembers, providing insight into the high melt water contents of the parental magmas. Comparably, excess Al and An% in the high grade deposits appears to be higher than that of selected low grade deposits, representing a direct link between the amounts of exsolving hydrothermal fluids and the potential of metal endowment in porphyry copper deposits (PCDs). Also, higher Al contents accompanied by elevated An% are linked to the increasing intensity of disruptive alteration (phyllic) in feldspars from the high grade deposits. As calculated from biotite compositions, chloride contents are higher in the exsolving hydrothermal fluids that contributed to the early mineralization stages of highly mineralized porphyry systems. However, as evidenced by scattered and elevated log ( f H 2 O)/( f HF) and log ( f H 2 O)/( f HCl) values, chloride contents recorded in biotite could be influenced by post potassic fluids. Geothermometry of biotite associated with the onset of sulfide mineralization indicates that there is a trend of increasing temperature from high grade to low grade porphyry systems. Significantly, this is coupled with a sharp change in copper content of pyrite assemblages precipitated at the early stages of mineralization such that Cu decreased with increasing temperature. Based on EMPA and detailed WDS elemental mapping, trace elements do not exhibit complex compositional zoning or solid solution in the sulfide structure. Nevertheless, significant amounts of Cu and Au are contained in pyrite assemblages as micro- to nano-sized inclusions, especially in the high grade fertile porphyry deposits. However, unexpectedly high concentrations of Te, Se, and Re may be associated with early stage of sulfide mineralization, especially when there is no epithermal lithocap. This may highlight the significance of trace metals partitioning in the sulfides formed at the early stages of mineralization in PCDs. [ABSTRACT FROM AUTHOR]

The Miocene Sarkuh porphyry Cu deposit is located in the southwestern part of Urumieh-Dokhtar Magmatic Arc (UDMA) in Iran. Compared with the neighboring giant Sarcheshmeh porphyry Cu deposit, this is a low-grade sub-economic porphyry Cu system (110 million tons @ 0.26 % Cu) characterized by an unusual abundance of magnetite. The present work tried to answer the question of whether or not there are differences in the hydrothermal system of Sarkuh, resulting in the lack of considerable mineralization. In this way, the mineral associations and EMPA data of magnetite were considered to distinguish the different stages of magnetite crystallization reflecting the magmatic-hydrothermal evolution of the Sarkuh deposit. They include (1) magmatic stage magnetite, including magnetite inclusions within primary silicate minerals (i.e., plagioclase and biotite), (2) pre-ore stage magnetite associated with potassic alteration assemblages, (3) main ore stage magnetite tightly associated with sulfide mineralization, and (4) late stage magnetite forming overgrowths on the sulfides. The results of EPMA analysis confirm that magnetite of these four stages differ in Mn, Fe, Ti, Mg, Al, Cr, and V concentrations. Higher V concentrations are found in the magmatic and pre-ore stages, whereas Al and Si reach the highest in the ore and late stages. Our data show that increasing fluid-rock interaction and changes in the oxygen fugacity, especially during the main ore stage extending to the late stage, are key factors controlling the trace element partitioning of magnetite. Most of ore stage magnetite formed at temperatures >500 °C and high temperatures prevailed during it. Magnetite crystallization after the main stage of sulfide mineralization accompanied by (partial) martitization indicate the increase of oxygen fugacity towards the late hydrothermal stage. This could explain why the ore and late stage magnetites show chemical similarities to those from sulfur-poor iron oxide copper‑gold (IOCG) deposits rather than porphyry deposits. • Sarkuh porphyry Cu deposit is characterized by unusual abundance of magnetite. • Four stages of magnetite crystallization could reflect the magmatic-hydrothermal evolution. • Al and Si reach the highest in the ore and late stages. • Ore and late stage magnetites show chemical similarities to sulfur-poor IOCG deposits. [ABSTRACT FROM AUTHOR]