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Start Over Author "Andresova A." Publisher elsevier b.v.
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2. Branched and cyclic alkyl groups in imidazolium-based ionic liquids: Molecular organization and physico-chemical properties.

Author

Andresova, A., Storch, J., Traïkia, M., Wagner, Z., Bendova, M., and Husson, P.

Subjects
*ALKYL group, *CYCLIC compounds, *IMIDAZOLES, *CHEMICAL synthesis, *IONIC liquids, *MOLECULAR structure
Abstract

Highlights: [•] Novel [C4C5Im][Tf2N] ionic liquids with a variation in structure of a C5 alkyl group were synthesised for the first time and characterized as to their thermophysical and transport properties. [•] Branching of the alkyl chain has no influence on the ionic liquid density. [•] Isopentyl and cyclopentyl groups increase the ionic liquid viscosity. [•] Suprisingly the cyclopenty-substituted ionic liquid shows the highest conductivity in spite of its high viscosity. This however is in agreement with a higher degree of its ion dissociation found from the experimental self-diffusion coefficients. [Copyright &y& Elsevier]

Published
2014
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