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The sealing capacities of shale, roof, and floor strata are essential for the preservation of shale gas. Sealing capacity development and its influence on shale gas composition and organic matter pore development are important but have not been addressed by existing studies. In this paper, the Upper Ordovician Wufeng-the first member of the Lower Silurian Longmaxi Fm. in the Yangtze region is selected as the study object. We dissected the J1 well in the Jiaoshiba block inside the Sichuan Basin and the Y6 well in the Youyang block outside the Sichuan Basin to analyze the gas components and carbon isotopes in recovered shale gas. In this study, two microscope techniques (i.e., FIB-SEM and FIB-HIM), porosity measurement, TOC content analysis, permeability tests, isothermal adsorption measurements, are utilized. The analytical results show that both the roof and floor strata have vertical sealing effects on the organic-rich shale due to their different physical properties compared to the shale. The shale overburden pressure increases with burial depth, and the adsorbed gas increases with increasing TOC content and thickness: all of these can lead to a decrease in permeability and an increase in self-sealing capacity. This paper determined the formation mechanism of the sealing capacity for shale, roof and floor strata. Furthermore, the control patterns of "sealing capacity strength" on the shale gas source and organic matter pore development are clarified. The main findings are as follows: when the shale, roof, and floor strata have a strong sealing capacity, only a small amount of liquid hydrocarbons can be discharged from the shale, but the natural gas formed due to liquid hydrocarbon cracking is abundant. Under such circumstances, shale gas has a mixed origin of liquid hydrocarbon cracked gas and kerogen cracked gas; the carbon isotopes are inverted; abundant pyrobitumen pores with high porosity and good connectivity are developed. When the sealing capacities are weak, the amount of liquid hydrocarbons discharged from the shale are high, and the amount of natural gas is low. The shale gas is mainly derived from kerogen cracking with weak or no carbon isotope inversion, and kerogen pores are small with poor connectivity. These findings will advance the study of shale gas formation mechanisms and provide a scientific basis for selecting shale gas exploration area. • Due to different physical properties, the roof and floor strata provide a seal for the organic-rich shale. • As the burial depth, TOC content, and the shale thickness increase, the shale has a stronger sealing capacity. • Sealing capacity plays an important role in the characteristics of shale gas and organic matter pore development. [ABSTRACT FROM AUTHOR]

In this paper, the original nature of organic matters is introduced for the first time to reevaluate the lower Permian (P 1) source rocks. The carbonate rocks in Maokou Formation (P 1 m) whose high organic carbon values were caused by external asphalt have poor hydrocarbon generation ability, but the argillaceous rocks in P 1 m have some, especially the recent discovered black shale in Gufeng deep-water facies in the north have good hydrocarbon generation ability. The black shale is 5–20 m thick and the measured average value of organic carbon can reach up to 7.24 wt%, which can greatly increase the hydrocarbon generation capacity in the north; The studies of natural gas sources of the lower Permian in eastern Sichuan basin show that the contribution of gas source is mainly Silurian. In the north, the lower Permian source rock is supplemented, while in the south, it's greatly affected by the coal-measure source rocks of Longtan Formation (P 2 l); Take the Wutan-1 well in Tanmuchang as an example to dissect the reservoir in syncline area. The Wutan-1 well has a tested daily production of more than 80 × 104 m3, and the paleotectonic evolution history shows that it was in the high position of the structure during the generation and expulsion peak of hydrocarbon. The fracture-vuggy lithologic reservoir of Wutan-1 well is favorable for hydrocarbon capture and later preservation. According to the above, the Tanmuchang syncline has a good spatio-temporal matching relationship, which is the key to hydrocarbon accumulation and exploration. This knowledge has expanded the exploration area of the Lower Permian Maokou Formation in eastern Sichuan, and more importantly, it brings much enlightenment to the exploration of the syncline areas in Sichuan basin and other basins at home and abroad. • The original nature of organic matters is introduced for the first time to reevaluate the lower Permian source rocks. • The black shale in Gufeng deep-water facies has hydrocarbon generation capacity in the north of the eastern Sichuan Basin. • The sources of natural gas in Maokou Formation are different between the north and the south in the eastern Sichuan Basin. • The syncline area of the Lower Permian Maokou Formation in eastern Sichuan has the potential for gas accumulation. [ABSTRACT FROM AUTHOR]