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The present study highlights the importance of examining the contribution of Saharan dust (SD) sources not only in terms of overall mass contribution but also in terms of composition, size distribution and inhaled dose. The effect of SD intrusions on PM and the respective major and trace metals mass concentrations and size distributions was investigated in a suburban site in Athens, Greece. SD events were associated, on average, with lower boundary layer heights (BLH) compared to the non-Sahara (nSD) dust days. During SD events, PM 1-10 concentrations showed an increasing trend with increasing atmospheric BLH, in contrary to the fine PM (PM 1 ). Generally, increased PM 1 and CO (i.e. anthropogenic origin) levels were observed for BLH lower than around 500 m. The average contribution of SD to PM 10 and PM 2.5 mass concentration was roughly equal to 30.9% and 19.4%, respectively. The mass size distributions of PM and specific major and trace elements (Na, Al, Si, S, Cl, K, Ca, Fe, and Zn) displayed a somewhat different behavior with respect to the mass origin (Algeria-Tunisia vs Libya-Egypt), affecting in turn the regional deposition of inhaled aerosol in the human respiratory tract (HRT). The average PM deposited mass in the upper and lower HRT was 80.1% (Head) and 26.9% (Lung; Tracheobronchial and Pulmonary region) higher for SD days than for nSD days. Higher doses were estimated in the upper and lower HRT for the majority of the elements, when SD intrusions occurred, supporting the increasingly growing interest in exploring the health effects of SD. Only the mass deposition for S, and Na in the lower HRT and Zn in the upper HRT was higher in the case of nSD., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

This work presents the results of a PM2.5 source apportionment study conducted in urban background sites from 16 European and Asian countries. For some Eastern Europe and Central Asia cities this was the first time that quantitative information on pollution source contributions to ambient particulate matter (PM) has been performed. More than 2200 filters were sampled and analyzed by X-Ray Fluorescence (XRF), Particle-Induced X-Ray Emission (PIXE), and Inductively Coupled Plasma Mass Spectrometry (ICP-MS) to measure the concentrations of chemical elements in fine particles. Samples were also analyzed for the contents of black carbon, elemental carbon, organic carbon, and water-soluble ions. The Positive Matrix Factorization receptor model (EPA PMF 5.0) was used to characterize similarities and heterogeneities in PM2.5 sources and respective contributions in the cities that the number of collected samples exceeded 75. At the end source apportionment was performed in 11 out of the 16 participating cities. Nine major sources were identified to have contributed to PM2.5: biomass burning, secondary sulfates, traffic, fuel oil combustion, industry, coal combustion, soil, salt and "other sources". From the averages of sources contributions, considering 11 cities 16% of PM2.5 was attributed to biomass burning, 15% to secondary sulfates, 13% to traffic, 12% to soil, 8.0% to fuel oil combustion, 5.5% to coal combustion, 1.9% to salt, 0.8% to industry emissions, 5.1% to "other sources" and 23% to unaccounted mass. Characteristic seasonal patterns were identified for each PM2.5 source. Biomass burning in all cities, coal combustion in Krakow/POL, and oil combustion in Belgrade/SRB and Banja Luka/BIH increased in Winter due to the impact of domestic heating, whereas in most cities secondary sulfates reached higher levels in Summer as a consequence of the enhanced photochemical activity. During high pollution days the largest sources of fine particles were biomass burning, traffic and secondary sulfates., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 The Authors. Published by Elsevier Ltd.. All rights reserved.)