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1. Mechanism of HDN over Mo and Nb−Mo carbide catalysts

Author

V. Teixeira da Silva, Jingguang G. Chen, S. Ted Oyama, and Viviane Schwartz

Subjects
inorganic chemicals, Elimination reaction, Chemistry, organic chemicals, Inorganic chemistry, Hydrodenitrogenation, Reactivity (chemistry), Catalysis, Carbide
Abstract

Comparison of the hydrodenitrogenation rate of a series of isomeric amines was performed over Mo2C, NbC, NbMo2−O−C and MoS2/SiO2 catalysts. It is shown that the reaction occurs mainly through an elimination mechanism and that the order of reactivity does not correlate with the surface acidity of the catalysts.

Published
2000

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