1. Synthesis, growth, structural, thermal and optical studies of pyrrolidinium-2-carboxylate-4-nitrophenol single crystals.
- Author
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Swarna Sowmya N, Sampathkrishnan S, Vidyalakshmi Y, Sudhahar S, and Mohan Kumar R
- Subjects
- Calorimetry, Differential Scanning, Crystallization, Hydrogen Bonding, Luminescence, Molecular Conformation, Proline chemical synthesis, Proline chemistry, Proton Magnetic Resonance Spectroscopy, Solubility, Solvents chemistry, Spectrophotometry, Ultraviolet, Spectroscopy, Fourier Transform Infrared, Spectrum Analysis, Raman, Thermogravimetry, Water chemistry, X-Ray Diffraction, Nitrophenols chemical synthesis, Nitrophenols chemistry, Optical Phenomena, Proline analogs & derivatives, Temperature
- Abstract
Organic nonlinear optical material, pyrrolidinium-2-carboxylate-4-nitrophenol (PCN) was synthesized and single crystals were grown by slow evaporation solution growth method. Single crystal X-ray diffraction analysis confirmed the structure and lattice parameters of PCN crystals. Infrared, Raman and NMR spectral analyses were used to elucidate the functional groups present in the compound. The thermal behavior of synthesized compound was studied by thermogravimetric and differential scanning calorimetry (TG-DSC) analyses. The photoluminescence property was studied by exciting the crystal at 360 nm. The relative second harmonic generation (SHG) efficiency of grown crystal was estimated by using Nd:YAG laser with fundamental wavelength of 1,064 nm., (Copyright © 2015 Elsevier B.V. All rights reserved.)
- Published
- 2015
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