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Understanding marine pollution in the South China Sea is crucial for preserving marine ecosystems and biodiversity. Despite extensive research on pollutants, there is a significant gap in knowledge about microplastics (MPs) in the archipelago region. This study focused on four typical islands, examining MPs in seawater and sediments, their distribution, and environmental risks. Most MPs (>90 %) were smaller than 2.5 mm, with black fiber-shaped polyethylene terephthalate MPs being predominant. MPs in seawater had lower abundance (5-12 items/L) compared to sediment (100-2600 items/kg) but showed richer polymer composition. Pollution load index (PLI) and risk index analysis indicated all regions were contaminated (PLI > 1), with the Zhongsha islands being the most polluted. Correlation analysis highlighted black, fibrous PET-like polymers with large particle sizes (>0.5 mm) as major contributors. This study could help to understand the MPs distribution and pollution in the archipelago region of the South China Sea., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Soil microbiomes drive many soil processes and maintain the ecological functions of terrestrial ecosystems. Microplastics (MPs, size < 5 mm) are pervasive emerging contaminants worldwide. However, how MPs affect soil microbial activity has not been well elucidated. This review article first highlights the effects of MPs on overall soil microbial activities represented by three soil enzymes, i.e., catalase, dehydrogenase, and fluorescein diacetate hydrolase (FDAse), and explores the underlying mechanisms and influencing factors. Abundant evidence confirms that MPs can change soil microbial activities. However, existing results vary greatly from inhibition to promotion and non-significance, depending on polymer type, degradability, dose, size, shape, additive, and aging degree of the target MPs, soil physicochemical and biological properties, and exposure conditions, such as exposure time, temperature, and agricultural practices (e.g., planting, fertilization, soil amendment, and pesticide application). MPs can directly affect microbial activities by acting as carbon sources, releasing additives and pollutants, and shaping microbial communities via plastisphere effects. Smaller MPs (e.g., nanoplastics, 1 to < 1000 nm) can also damage microbial cells through penetration. Indirectly, MPs can change soil attributes, fertility, the toxicity of co-existing pollutants, and the performance of soil fauna and plants, thus regulating soil microbiomes and their activities. In conclusion, MPs can regulate soil microbial activities and consequently pose cascading consequences for ecosystem functioning., Competing Interests: Declaration of Competing Interest ☒ The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. ☐ The authors declare the following financial interests/personal relationships which may be considered as potential competing interests:, (Copyright © 2024. Published by Elsevier Inc.)

This present study investigated pork bone-derived biochar as a promising amendment to reduce Cd accumulation and alleviate Cd-induced oxidative stress in rice. Micro/nanoscale bone char (MNBC) pyrolyzed at 400 °C and 600 °C was synthesized and characterized before use. The application rates for MNBCs were set at 5 and 25 g·kg -1 and the Cd exposure concentration was 15 mg·kg -1 . MNBCs increased rice biomass by 15.3-26.0% as compared to the Cd-alone treatment. Both types of MNBCs decreased the bioavailable Cd content by 27.4-54.8%; additionally, the acid-soluble Cd fraction decreased by 10.0-12.3% relative to the Cd alone treatment. MNBC significantly reduced the cell wall Cd content by 50.4-80.2% relative to the Cd-alone treatment. TEM images confirm the toxicity of Cd to rice cells and that MNBCs alleviated Cd-induced damage to the chloroplast ultrastructure. Importantly, the addition of MNBCs decreased the abundance of heavy metal tolerant bacteria, Acidobacteria and Chloroflexi, by 29.6-41.1% in the rhizosphere but had less impact on the endophytic microbial community. Overall, our findings demonstrate the significant potential of MNBC as both a soil amendment for heavy metal-contaminated soil remediation and for crop nutrition in sustainable agriculture., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

The speciation of arsenic (As) determines its biogeochemistry and ecotoxicity in soils. However, the approach to in situ monitor labile As (III) and As (V) in soils still requires more exploration. In this study, we developed a method for simultaneously obtaining in-situ data on labile As (III) and As (V) in soils using diffusive gradients in thin films (DGT) and high performance liquid chromatography-inductively coupled plasma mass spectrometry. The Fe 2 O 3 ∙xH 2 O DGT sampler exhibited rapid and simultaneous accumulation of As (III) and As (V) in solutions within 90 min. The high efficiency of simultaneous elution of As (III) (~84 %) and As (V) (~97 %) was achieved using 0.8 % H 3 PO 4 as eluent at 90 °C for 80 min. The method detection limits for As (III) and As (V) were 0.01 and 0.005 μg/L, respectively. This method was applied to reveal the labile As (III) and As (V) in soils in the water level fluctuation zones of the Three Gorges Reservoir, which is the largest reservoir in China. The concentrations of As (III) and As (V) measured by DGT varied with different sampling sites, ranging from 0.01 μg/L to 1.20 μg/L and from 0.01 μg/L to 0.26 μg/L, respectively. The labile As (III) exhibited the higher resupply rate from soil solid phase to soil solution than labile As (V). This study helps to achieve simultaneous in-situ quantification of labile As (III) and As (V) in soils, and will improve the understanding of As mobilization and ecotoxicity in soils., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Tomato (Solanum lycopersicum) seedlings were exposed by foliar or root applications to Zn in different nanoscale and non-nanoscale forms (40 mg Zn/L) under hydroponic conditions for 15 days. Under foliar exposure, ZnO QDs significantly promoted tomato growth, while ZnO NPs and BPs had lower impacts. ZnO QDs increased fresh weight and plant height by 42.02 % and 21.10 % relative to the untreated controls, respectively. The ionic control (ZnSO 4 ·7H 2 O, 176.6 mg/L) decreased fresh weight by 39.31 %. ZnO QDs also significantly increased the Chla/Chlb ratio, as well as carotenoids and protein content by 7.70 %, 8.90 % and 26.33 %, respectively, over the untreated controls, suggesting improvement in seedling photosynthetic performance. Antioxidant enzyme (POD, PPO and PAL) activities in ZnO QDs treated shoots were significantly decreased by 31.1 %, 17.8 % and 48.3 %, respectively, indicating no overt oxidative damage from exposure. Importantly, the translocation factor of Zn (TF Zn ) in the foliar exposure of the ZnO QDs treatment was 73.2 %, 97.1 % and 276.9 % greater than the NPs, BPs, and ionic controls, respectively. Overall, these findings clearly demonstrate that foliar spray of nanoscale nutrients at the appropriate concentration and size can significantly increase crop growth and be a sustainable approach to nano-enabled agriculture., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022. Published by Elsevier B.V.)

Microplastics (MPs) are verified to affect the fate of ammonia (NH 3 ) in agricultural soils. However, the impacts and mechanisms of MPs coupled with biochar (BC), a widely used agricultural conditioner, on NH 3 losses are mostly untapped. The aim of this study was to investigate the mechanisms of common MPs (i.e., polyethylene, polyester, and polyacrylonitrile) and straw-derived BC on NH 3 volatilization in rice-wheat rotation soils. Results showed that BC alone and MPs with BC (MPs + BC) reduced 5.5 % and 11.2-26.6 % cumulative NH 3 volatilization than the control (CK), respectively, in the rice season. The increased nitrate concentration and soil cation exchange capacity were dominant contributors to the reduced soil NH 3 volatilization in the rice season. BC and MPs + BC persistently reduced 44.5 % and 60.0-62.6 % NH 3 losses than CK in the wheat season as influenced by pH and nitrate concentration. Moreover, BC and MPs + BC increased humic acid-like substances in soil dissolved organic matter by an average of 159.1 % and 179.6 % than CK, respectively, in rice and wheat seasons. The increased adsorption of soil NH 4 + and the promotion of crop root growth were the main mechanisms of NH 3 reduction. Our findings partially revealed the mechanisms of the coexistence of MPs and BC on NH 3 mitigation in rice-wheat rotational ecosystems., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Microplastics (MPs) accumulation in soil ecosystems has become a worldwide issue. The influence of MPs on soil structures and contaminant transport has not been clearly unraveled. This study conducted soil column experiments covering four different treatments: soil without MPs (CK), soil with 0.5 wt% polyethylene (S+PE), soil with 0.5 wt% polyacrylonitrile (S+PAN), and soil with 0.5 wt% polyethylene terephthalate (S+PET). The interconnections between changes in soil structures and shifts in sorption efficiency for typical hydrophobic organic contaminants (e.g., phenanthrene (PHE)) and heavy metal (e.g., lead (Pb (II)) by soils induced by MPs were explored. MPs-added soils contained fewer macro-aggregates and lower aggregate stability compared to CK. Three MPs, particularly PE, promoted PHE sorption by soils but reduced Pb (II) sorption, which occurred in soils with or without dissolved organic carbon. The comparison between experimental and predicted sorption capacity, as well as the one-point sorption data of different aggregate sizes, showed that such variations in PHE and Pb (II) sorption were related to the shifts in soil aggregates besides from the physical mixture of soils with MPs. This finding is perspective to give an in-depth understanding of the effects of different MPs types on soil micro-environments and transport for contaminants., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Biochar has been regarded as an effective amendment for soil carbon sequestration and soil quality improvement. However, it remains unclear how pyrolysis temperature and biochar aging impact the responses of soil properties and CO 2 emissions to biochar addition. Here, we investigated the effect of biochar on soil properties and CO 2 emissions in a laboratory incubation using soils amended with/without fresh biochar produced at 300 (BC300), 450 (BC450), and 600 °C (BC600) and their corresponding naturally aged samples (aged in soil for 360 days). The results showed that biochar significantly increased soil total nitrogen (by 8-36%), available phosphorus (by 19-69%) and available potassium (by 1.5-4.2-fold) throughout the incubation. Both fresh and aged biochar promoted the formation of soil macroaggregate at the end of the incubation. Moreover, fresh and aged BC300 increased the soil dissolved organic matter (DOM) content, whereas for BC450 and BC600, at the beginning, the content of soil DOM was reduced, but the effects finally became insignificant. Generally, fresh biochar had no significant effect on soil enzyme activities and soil bacterial richness and diversity, but an inhibitory effect occurred in the aged samples. Both fresh and aged BC300 increased soil CO 2 emissions, which was due to the biochar-induced increase in soil DOM content and enrichment of copiotrophic bacteria (Proteobacteria) as well as the decline of oligotrophic bacteria (Acidobacteriota). A significant decrease in soil CO 2 emissions was observed after fresh BC450 and BC600 addition, owing to the biochar-induced decline in soil DOM content, while an opposite trend was found in aged samples, which could be attributed to the shift of the dominant soil phylum from Acidobacteriota to Proteobacteria. These findings enhance our understanding of biochar's potential to improve soil quality and sequester soil carbon., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

In this study, concentrations of disinfection byproducts (DBPs) and COVID-19 related pharmaceuticals in wastewater effluents and surface water were measured two weeks, three months and eight months after the lockdown in Wuhan. Little temporal variation in DBP concentrations suggested intensified disinfection during the COVID-19 pandemic had limited impacts on the occurrence of DBPs in the aquatic environment. In contrast, the pandemic led to a significant increase in concentrations of lopinavir and ritonavir in wastewater effluents and surface water. The high detection frequency of these pharmaceuticals in surface water after the lockdown highlighted their mobility and persistence in the aquatic environment. The initial ecological risk assessment indicated moderate risks associated with these pharmaceuticals in surface water. As the global situation is still rapidly evolving with a continuous surge in the number of confirmed COVID-19 cases, our results suggest a pressing need for monitoring COVID-19 related pharmaceuticals as well as a systematic evaluation of their ecotoxicities in the aquatic environment., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Pyrogenic dissolved organic matter (pyDOM) is the photolabile fraction in the dissolved organic matter pool. However, the molecular changes and reactive oxygen species generation of pyDOMs under continuous irradiation, and how these vary with feedstock type and pyrolysis temperature, are not well understood. In this study, the soluble fractions of 300 and 450 ºC biochars (pyDOM300 and pyDOM450) were subjected to photo-irradiation. PyDOM450 was of higher aromaticity, molecular variety, but lower unsaturation than pyDOM300. The molecular weight, aromaticity, and double bond equivalents of pyDOMs generally decreased after photo-irradiation. The degradation pattern of pyDOMs can be divided into two stages. In the initial 24 h, pyDOM300 degraded faster than pyDOM450, with the more profound transformation of condensed aromatics and carbohydrate into aliphatic/proteins, lignins, and tannins in pyDOM300. After 720 h irradiation, however, the degradation ratio of pyDOM450 (36.2-43.9%) exceeded that of pyDOM300 (23.7-30.3%), with the initially preserved condensed aromatics in pyDOM450 further transforming into aliphatic/proteins and tannins. This was potentially attributed to the generation of more reactive oxygen species (·OH and 1 O 2 ) in pyDOM450. This study uncovered the photodegradation mechanisms of pyDOMs at molecular scale and helped to understand their cycling and effects on environment., (Copyright © 2021 Elsevier B.V. All rights reserved.)

The function of biochar (BC) as an eco-friendly adsorbent for environmental remediation is gaining much attention. However, the pristine BC had limited abilities for the removal of As (III, V). Towards this issue, this study synthesized biochar/micro-nanosized α-MnO 2 (BM) composites with different mass ratios of biochar to MnO 2 . Comprehensive characterizations confirmed the successful loading of micro-nanosized α-MnO 2 onto the BC surface and the obvious specific surface area enhancement (7.5-13.5 times) of BM relative to BC. BM composites exhibited 5.0-13.0 folds higher removal capacity for As (III, V) than pristine BC since the composites gave full play to the oxidation contributed by micro-nanosized α-MnO 2 substrate and adsorption functions provided by the Mn-OH, BC-COOH, and BC-OH functional groups. Moreover, BM was well reused maintaining a relatively high removal efficiency for As (III, V). Regardless of reaction time and initial As (III) concentration (C 0 ), the removal of As (III) by pristine BC was negligibly contributed by the oxidized As (V) remaining in solutions, with the relative contribution <15.0%. For the BM composites, relative contribution of adsorbed As (III, V) dominated over that of oxidation to mobile As (V) remaining in solution, and exhibited the decreasing trend with increasing C 0 . These findings demonstrated BM as a promising candidate in remediating As (III, V)-polluted water, and provide mechanistic insights into the role of oxidation and adsorption in As (III, V) removal., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Microplastics (MPs), as an emerging pollutant, may cause deleterious changes to the nitrogen cycle in terrestrial ecosystems. However, single impact of MPs and synergistic effects of MPs with hydrochar on ammonia (NH 3 ) volatilization and soil microbiome in paddy fields has been largely unexplored. In this study, polyethylene (PE), polyacrylonitrile (PAN) and straw-derived hydrochar (HBC) were selected for observations in an entire rice cycle growth period. Results showed that under the condition of 0.5% (w/w) MPs concentration, presence of MPs alone and co-existence of MPs and HBC (MPs + HBC) unexpectedly mitigated cumulative NH 3 volatilization from paddy soil compared with the control with no MPs or HBC addition. MPs + HBC increased NH 3 volatilization by 37.8-46.2% compared with MPs alone, indicating that co-existence of MPs and HBC weaken the mitigation effect of MPs on NH 3 volatilization. Additionally, results of nitrogen cycle related microorganisms closely related to NH 3 volatilization demonstrated that MPs + HBC altered the bacterial community structure and species diversity. These findings provide an important opportunity to advance our understanding of the impacts of MPs in agricultural environment and soils, and provide a sound theoretical basis for rationalizing the application of HBC in soil with MPs., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Plastic pollution has become a global environmental threat, and its potential to affect the bioavailability and toxicity of pharmaceuticals to aquatic organism are of growing concern. However, little is known regarding the combined toxicity of micro/nano-plastics and pharmaceuticals to benthic organisms in sediments. Thus, we employed a freshwater benthic bivalve, Corbicula fluminea (C. fluminea), to investigate the individual and co-toxicity of model plastics, microscopic fluorescent polystyrene (PS) (PS nano-plastic (PS-NP) and PS micro-plastic (PS-MP), 80 nm and 6 μm, respectively) and the common antibiotic ciprofloxacin (CIP) in formulated sediments. Our results suggest that oxidative damage and neurotoxicity were confirmed to occur in C. fluminea in all the treatments. The oxidative damage in the digestive glands reduced the clam ability to scavenge free radicals, causing severe tissue damage to the digestive glands of C. fluminea. Filtration rates of C. fluminea were significantly decreased in a concentration-dependent manner across all the treatments, which might be due to the inhibition of acetylcholinesterase activities. Interactions between CIP and micro/nano-plastic were observed, whereby the presence of PS decreased the toxicity of CIP in the digestive glands but aggravated the C. fluminea siphoning inhibition rate in the nano-plastic co-treatments group; in addition, the CIP toxicity to C. fluminea decreased because that the concentration of free dissolved CIP was lowered by micro/nano-PS. Taken together, the current study could contribute greatly to evaluating the ecological risk of CIP and PS in aquatic environments and sheds light on potential issues of food safety caused by both emerging pollutants., Competing Interests: Declaration of competing interest We declare that we do not have any commercial or associative interest that represents a conflict of interest in connection with the work submitted., (Copyright © 2021. Published by Elsevier B.V.)

Owing to its superior energy-saving function and strong potential to be applied as a soil amendment and fertilizer, hydrochar has gained wide attention in recent years. However, hydrochar contains greater amounts of labile fractions than traditional biochar and may exacerbate the short-term greenhouse effect. To lower the risk of greenhouse gas release due to labile fractions, optimize parameters must be determined to produce hydrochar without carbohydrate carbon. In addition, the effects of varying feedstocks and process conditions on hydrochar structure as well as its dissolved organic matter (DOM) must be investigated. Spartina alterniflora and pig manure were used to produce two hydrochars (HSAs and HPMs) and their corresponding DOM samples (DSAs and DPMs) at various production temperatures (T p ) and reaction times (t r ). The carbohydrate vanishing points (CVPs) were 265 °C-1 h, 250 °C-2 h, and 245 °C-4 h for the HSAs and 260 °C-1 h, 250 °C-2 h, and 250 °C-4 h for the HPMs. With the isolation of DOM, 1.09-4.33% organic carbon of the hydrochar was released. The aromaticity of DSAs decreased with increasing T p and t r . The molecular weights of the DSAs and DPMs decreased with increasing T p and t r . This study uncovered hydrochar's molecular structure as well as the content and properties of its labile fractions. Results can be used to help design specific hydrochars for potential applications, based on the trend of the molecular change under the condition of the studied parameters optimization to produce hydrochar in this study., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Biochar has emerged as a useful tool to reduce the bioavailability of heavy metals in contaminated soils. However, limited research has been directed towards determining the effects of pyrolysis conditions and feedstock types of biochar on the bioavailability of heavy metals in biochar-treated soils. This work evaluated the efficacy of plant- and manure-derived hydrochar and pyrochar for alleviating Cd bioavailability in soils using conventional chemical extraction, diffusive gradients in thin films (DGT) and plant uptake. For each feedstock type, hydrochar showed lower maximum adsorption capacity than pyrochar. As determined by diethylenetriamine pentaacetic acid, BCR extraction and DGT measurement, pyrochar significantly decreased the theoretical bioavailability of Cd. Moreover, a slight decrease in the ability of soil to resupply Cd to the solution was detected. Also, pyrochar induced a substantial reduction in Cd uptake in ryegrass. Corresponding to the high sorption capacity, swine solid-derived 450 °C pyrochar was the most effective in alleviating Cd bioavailability in soils, indicating its great potential for remediating Cd-contaminated soils. Additionally, the bioavailable Cd amount determined by DGT had the best correlation with the Cd content in ryegrass, showing that DGT technology could better represent the effects of biochars on Cd phytoavailability in the studied soil., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Arsenic (As) contamination in sediments has been reported worldwide. However, few studies have investigated As contamination on a national scale in China. This study aims to address this gap by analyzing the existing literature on As contamination and sediment samples collected from ten main river basins: the Songhua River Basin (SRB), Liao River Basin (LRB), Hai River Basin (HRB), Yellow River Basin (YRB), Huai River Basin (HuRB), Yangtze River Basin (YtRB), Pearl River Basin (PRB), Southeastern River Basin (SeRB), Southwestern River Basin (SwRB), and Northwestern River Basin (NwRB). Regional geochemical baseline (RGB) values of As in the sediments of river basins were calculated to estimate human contributions of As using normalization and cumulative frequency distribution curves. The established RGB values in the SRB, YtRB, and PRB were higher than the corresponding regional soil background (RSB), possibly because of the high intensity of human activities in the SRB, YtRB, and PRB. Taking RGB and RSB values as the background references, contamination assessment yielded important information on As contamination in China. With high As contributions from Yunnan province, the PRB suffered from the highest level of contamination, and the mean human contribution of As in the PRB was 64.4%. The contamination levels in the less developed southwestern regions were even higher than in some river basins in economically developed regions (e.g., YRB). In addition, As in the PRB and YtRB was found to be partially contributed by industrial wastewater discharge, and the response of As contamination in sediments to industrial wastewater discharge was analyzed. The temporal change (2004-2016) of As in sediments from the PRB, YtRB, and YRB corresponded well with that of As discharged in wastewater within the corresponding river basins. This study thus serves as a valuable foundation for policies focused on ameliorating As contamination in China., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Source identification of trace metals in the water environment is important in understanding its environmental behavior and in the prevention and remediation of further pollution. Here, the regional geochemical baseline (RGB) and Pb isotopic ratios are combined to decipher the anthropogenic contribution rate, main anthropogenic source, and transport pathway of trace metals in sediments collected from the largest freshwater lake in northern China, Baiyangdian (BYD) Lake. The established RGB values of Cr, Ni, Cu, Zn, Cd, and Pb were 63.0, 27.8, 24.7, 46.1, 0.18, and 22.0 mg/kg, respectively, which were slightly different from the regional soil background values. Based on the RGB and actual concentrations of trace metals in the lake sediments, the calculated average anthropogenic contribution were lower than 20% except for Cd. Compared with the other trace metals, Cd was the element most impacted by anthropogenic input, which was mainly caused by the point source pollution in some sites. The risk assessment (geo-accumulation index and potential ecological risk) using the RGB as the regional background values showed that BYD sediments were uncontaminated by the trace metals, and at low ecological risk from the trace metals. The results of these two risk assessments further validated the assessment of the anthropogenic contribution by the RGB. In addition, Pb isotopic ratios result showed that coal combustion was the main potential source of anthropogenic Pb in the BYD sediments and atmospheric deposition was the main transport pathway. This study tried to combine the geochemical baseline and Pb isotopic composition to identify the anthropogenic input of trace metals in the sediments. It will provide a new insight into assessing the anthropogenic contributions, identifying the main anthropogenic sources, and transport pathways of trace metals in water environment., (Copyright © 2018 Elsevier Inc. All rights reserved.)

Lead (Pb) contamination was recognized in China early in the 1920s. However, the response of Pb contamination in sediments to China's rapid economic and social development remains uncertain to date. We conducted a literature review of over 1000 articles from 1990 to 2016 and the first national-scale survey of Pb contamination in China. A literature review showed that available research in China focused on the economically highly developed river basins, including the Pearl River Basin (PRB), Yellow River Basin (YRB), and Yangtze River Basin (YtRB), whereas those in the less developed southeastern, southwestern, and northwestern river basins received limited attention. The YtRB and YRB had higher Pb contamination levels than other basins, corresponding with the rapid economic development in those regions. However, the less economically developed river basins in the southeastern and northwestern regions of China were also contaminated by Pb. Analysis of 146 studies in the PRB, YRB, and YtRB revealed that Pb contamination in PRB sediments showed a tendency to improve over time, whereas that from the YtRB exhibited a tendency to worsen. For the YRB, there was a slight increase from 1990 to 2006 and a decreasing trend from 2007 to 2014. The overall temporal trend in Pb levels in PRB and YRB sediments corresponded with that of the Pb discharged in wastewater in the surrounding cities, indicating that industrial wastewater discharge was possibly one of the main anthropogenic sources of Pb in those sediments. For the YtRB, the increasing trend in Pb concentrations was related to the considerably high atmospheric Pb emissions in the surrounding cities and its geographical characteristics. These findings suggested that China should develop systematic and consistent approaches for monitoring Pb contents in sediments and adopt a regional economic development policy focusing on pollution prevention., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Phosphorus (P) in biochar serves as both a P source for plant growth and a contributor to water eutrophication, thus prioritizing the efficient management of P in biochar. This study employed solid- and solution- state 31 P-nuclear magnetic resonance and X-ray diffraction analyses to explore the impact of feedstock and heating treatment temperature (HTT) on P species of biochars. The effects of ambient temperature, coexisting anions, pH and nutrient solution on P release were also investigated to study the effect of various environmental factors on P release from biochars. P species in both plant- and manure- derived biochars were dominated by inorganic orthophosphate and pyrophosphate (mainly calcium-bound-phosphates). The HTT of biochar showed a negative impact upon its pyrophosphate content. Compared with plant biochars, manure biochars contained higher P but had a lower release degree. Release of P from biochars was controlled by diffusion-dissolution process and was enhanced by higher ambient temperature, co-existing anions, and both acidic and alkaline conditions but inhibited by coexisting Hoagland nutrients. Anion-induced increase in P release was more significant for plant biochars than manure biochars. These findings help to adjust favorable environmental conditions for the full utilization of P in biochars., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Assessing biochar's ability to resist oxidation is fundamental to understanding its potential to sequester carbon. Chemical oxidation exhibits good performance in estimating the oxidation resistance of biochar. Herein, oxidation resistance of 14 types of biochars produced from four feedstocks at different pyrolysis conditions (hydrothermal versus thermal carbonization) was investigated via hydrogen peroxide oxidation with varying concentrations. The oxidation resistance of organic carbon (C) of hydrochars was relatively higher than that of 250°C pyrochars (P250) but was comparable to that of 450°C pyrochars (P450). Both hydrochars and P450 from ash-rich feedstocks contained at least three different C pools (5.9-18.3% labile, 43.2-56.5% semi-labile and 26.9-45.9% stable C). Part (<33%) of aromatic C within 600°C pyrochars (P600) was easily oxidizable, which consisted of amorphous C. The influence of pyrolysis temperature upon oxidation resistance of biochars depended on the feedstock. For ash-rich feedstock (rice straw, swine manure and poultry litter), the oxidation resistance of biochars was determined by both aromaticity and mineral components, and mineral protection was regulated by pyrolysis conditions. The amorphous silicon within hydrochars and P450 could interact with C, preventing C from being oxidized, to some extent. Nevertheless, this type of protection did not occur for P250 and P600., (Copyright © 2017 Elsevier B.V. All rights reserved.)

The oxidation of biochar in the natural environment has been widely observed. However, its influence on the sorption of hydrophobic organic compounds (HOCs) by biochars, especially biochars with high contents of minerals, remains poorly understood. In this study, sorption of phenanthrene (PHE) by grass straw-based biochars (GRABs) and animal waste-based biochars (ANIBs) produced at 450°C before and after oxidation with HNO 3 was investigated. The biochar samples were characterized using elemental analysis, X-ray photoelectron spectroscopy, 13 C nuclear magnetic resonance, and CO 2 adsorption. Characterization results demonstrate that HNO 3 treatment of biochars caused O enrichment, loss of alkyl C, and rise of aromaticity. The organic C-normalized surface area (CO 2 -SA/OC) of both GRABs and ANIBs generally increased after oxidation. The sorption nonlinearity of PHE by the biochars was weakened after HNO 3 treatment. The sorption capacity of PHE by oxidized GRABs was consistently elevated compared with the untreated samples, indicating that the high sorption capacity of PHE by GRABs may be maintained for a long time after being added into soils. By contrast, PHE sorption by ANIBs was unchanged or attenuated after oxidation. Polar groups facilitated the sorption of PHE by GRABs, while inhibited that by ANIBs. Pore-filling and π-π electron donor-acceptor interactions regulated PHE sorption by GRABs. Our results imply that GRABs are promising sorbents for environmental applications in view of their long-lasting sorption capacity., (Copyright © 2017 Elsevier B.V. All rights reserved.)

The South-to-North Water Diversion Project, one of China's largest water diversion projects, has aroused widespread concerns about its potential ecological impacts, especially the potential release of trace metals from shoreline soils into Miyun Reservoir (MYR). Here, riparian soil samples from three elevations and four types of land use were collected. Soil particle size distributions, contents and chemical fractionations of trace metals and lead (Pb) isotopic compositions were analyzed. Results showed that soil texture was basically similar in four types of land use, being mainly composed of sand, with minor portions of clay and silt, while recreational land contained more abundant chromium (Cr), copper (Cu), zinc (Zn) and cadmium (Cd), suggesting a possible anthropogenic source for this soil pollution. The potential ecological risk assessment revealed considerable contamination of recreational land, with Cd being the predominant contaminant. Chemical fractionations showed that Cu, arsenic (As), Pb and Cd had potential release risks. Additionally, the 206 Pb/ 207 Pb and 208 Pb/ 207 Pb values of soils were similar to those of coal combustion. By combining principal component analysis (PCA) with Pb isotopic results, coal combustion was identified as the major anthropogenic source of Zn, Cr, Cu, Cd and Pb. Moreover, isotope ratios of Pb fell in the scope of aerosols, indicating that atmospheric deposition may be the primary input pathway of anthropogenic Zn, Cr, Cu, Cd and Pb. Therefore, controlling coal combustion should be a priority to reduce effectively the introduction of additional Zn, Cu, Cd, and Pb to the area in the future., (Copyright © 2017 Elsevier Inc. All rights reserved.)

The importance of the composition of soil organic matter (SOM) for carbon (C) cycling is still under debate. Here a single soil source was used to examine the specific influence of its composition on stability ((14)C activity) of SOM fractions while constraining other influential C turnover factors such as mineral, climate and plant input. The following SOM fractions were isolated from two soil samples: four humic acids, two humins, non-hydrolyzable carbon, and the demineralized fraction. We examined the isotope ratios of SOM fractions in relation to composition (such as aliphatic and aromatic C content) using solid state (13)C nuclear magnetic resonance (NMR) and thermal analysis. The Δ(14)C values of the fractions isolated from both an albic soil (SOMs-A) and a black soil (SOMs-B) correlated negatively with their peak temperature of decomposition and the temperature where half of the total heat of reaction was evolved, implying a potential link between thermal and biogeochemical stability of SOM fractions. Aryl C contents of SOMs-A determined using (13)C NMR varied inversely with δ(15)N values and directly with δ(13)C values, suggesting that part of aryl C of SOMs-A might be fire-derived. The Δ(14)C values of SOMs-A correlated positively with aliphatic C content and negatively with aromatic C content. We therefore concluded that fire-derived aromatic C in SOMs-A appeared to be more stable than microbially-derived aliphatic C. The greater decomposition of SOMs-B fractions weakened the relationship of their Δ(14)C values with alkyl and aryl C contents. Hence, the role of the composition of SOM fractions in regulating stability might be dependent on the source of specific C forms and their stage of decomposition., (Copyright © 2015 Elsevier B.V. All rights reserved.)