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The current technique of hydrogen generation and cooling production raises climatic problems, which calls for the investigation of cleaner alternatives. No research has been conducted to propose and analyze a solar thermal power cycle-based water electrolysis for on-site production of hydrogen and the detailed exergy analysis of a series flow double-effect absorption chilling machine employed for large solar cooling. In this regard, a helically coiled tube embedded central receiver is used in the heliostat field for the simultaneous production of solar cooling and green hydrogen to meet the increasing needs of energy and fuel sustainably. The combined system is composed of four sub-systems including a heliostat field, LiBr–H2O operated series-flow double effect absorption refrigeration cycle (DEARC), organic Rankine cycle (ORC), and proton exchange membrane (PEM) electrolyzer. The system was examined from energy and exergy perspectives in the Engineering Equation Solver (EES) using library data of REFPROP for obtaining the thermodynamic properties of working fluids. The results of the thermodynamic model for the combined system are validated. Furthermore, the effect of ambient temperature, solar irradiation, and type of ORC working fluid on the hydrogen and cooling production, and the overall energy and exergy efficiency of the combined system are examined. A computational fluid dynamics simulation applying ANSYS-FLUENT was used to examine how coil curvature ratio and coil torsion affect solar heat transfer fluid (SHTF) pressure and temperature leaving the receiver. The coil curvature ratio affects temperature increase more than coil torsion. Solar heat transfer fluid outlet temperature increases by 36.9 % when the coil curvature ratio increases from 0.063 to 0.095 at direct normal irradiations (DNI) 1200 W/m2, input temperature of 92°C, and coil torsion of 0.032. The response of the cogeneration cycle to varying operating parameters is examined. Application of R141b as the ORC fluid results in a large increase of cooling exergy efficiency from 14.98 % to 63.48 % when the ambient temperature is increased from 15 °C to 45 °C whereas the exergy efficiency of the combined system is marginally improved. The exergy distribution presents for ORC operating on R141b, out of 100 % input solar exergy, 16.42 % is generated as hydrogen exergy and 13.67 % cooling exergy, 66.79 % is the exergy destroyed, and the rest 3.12 % is exergy loss. Exergy analysis is utilized to identify the sources of losses in useful energy within the components of the system considered and provides a more realistic and meaningful assessment than the traditional energy analysis. The results justify a need for the promotion of exergy analysis through policy decisions in the context of the global energy and environment crisis.