1. Characterizations of thermal stability and electrical performance of Au-Ni coating on CuCrZr substrate for high vacuum radio-frequency contact application
- Author
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Yuntao Song, Qingquan Xi Yang, Zhaoxi Chen, Patrick Mollard, Leonel Ferreira, Julien Hillairet, R. Volpe, Florent Fesquet, Caroline Hernandez, Gilles Lombard, Raphaël Laloo, Karl Vulliez, Viviane Turq, Jean-Michel Bernard, Commissariat à l'Energie Atomique et aux énergies alternatives - CEA (FRANCE), Centre National de la Recherche Scientifique - CNRS (FRANCE), Chinese Academy of Sciences (CHINA), Institut National Polytechnique de Toulouse - INPT (FRANCE), Université Toulouse III - Paul Sabatier - UT3 (FRANCE), Organisation Européenne pour la Recherche Nucléaire - CERN (SWITZERLAND), Laboratoire d'étanchéité Maestral (Pierrelatte, France), Institut de Recherche sur la Fusion par confinement Magnétique (IRFM), Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Centre interuniversitaire de recherche et d'ingenierie des matériaux (CIRIMAT), Centre National de la Recherche Scientifique (CNRS)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Institut de Chimie du CNRS (INC), Institute of Plasma Physics, Chinese Academy of Sciences (ASIPP), Laboratoire d'Etanchéité (LE), European Organization for Nuclear Research (CERN), Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT), and Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
- Subjects
Thermonuclear fusion ,Materials science ,Scanning electron microscope ,contact resistance ,Matériaux ,Ultra-high vacuum ,FOS: Physical sciences ,02 engineering and technology ,Applied Physics (physics.app-ph) ,engineering.material ,7. Clean energy ,01 natural sciences ,Diffusion ,Coating ,[PHYS.PHYS.PHYS-PLASM-PH]Physics [physics]/Physics [physics]/Plasma Physics [physics.plasm-ph] ,0103 physical sciences ,Materials Chemistry ,Composite material ,Electroplating ,010302 applied physics ,Thermal aging ,Contact resistance ,diffusion ,[SPI.PLASMA]Engineering Sciences [physics]/Plasmas ,Metals and Alloys ,Physics - Applied Physics ,Surfaces and Interfaces ,Fusion power ,021001 nanoscience & nanotechnology ,Physics - Plasma Physics ,Electrical contacts ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,Keyword: Au-Ni coating ,Plasma Physics (physics.plasm-ph) ,Au-Ni coating ,[SPI.ELEC]Engineering Sciences [physics]/Electromagnetism ,Plasmas ,engineering ,Other ,thermal aging ,0210 nano-technology - Abstract
Radio-frequency (RF) contacts—which are an example of electrical contacts—are commonly employed on accelerators and nuclear fusion experimental devices. RF contacts with a current load of 2 kA for steady-state operation were designed for application to the International Thermonuclear Experimental Reactor (ITER) device. In contrast to the typical working conditions of general commercial electrical contacts, those of RF contacts employed on fusion devices include high vacuum, high temperature, and neutron radiation. CuCrZr is currently of interest as a base material for the manufacture of louvers of RF contacts, which has excellent thermal and electrical properties and has low creep rate at 250 °C. In this study, a hard Au coating (Au-Ni) was electroplated on CuCrZr samples and the samples were then subjected to thermal aging treatment at 250 °C for 500 h in order to simulate the vacuum-commissioning process of the ITER. The effects of thermal aging on the hardness, elastic modulus, crystallite size, and compositions of the coating were investigated via microstructural and mechanical characterizations of the coating material. Metal atom migration in different coating layers during thermal aging was characterized and evaluated via scanning electron microscopy/energy dispersive X-ray spectroscopy observations of the cross-sectional surfaces, and the obtained results could be used to directly select the coating thickness for the final RF contact component. The contact resistance—an important parameter of the RF contact—was measured in a dedicated testbed built to simulate fusion reactor conditions between CuCrZr pins and stainless steel plates coated with Au-Ni and Rh, respectively. Radio-frequency (RF) contacts-which are an example of electrical contacts-are commonly employed on accelerators and nuclear fusion experimental devices. RF contacts with a current load of 2 kA for steady-state operation were designed for application to the International Thermonuclear Experimental Reactor (ITER) device. In contrast to the typical working conditions of general commercial electrical contacts, those of RF contacts employed on fusion devices include high vacuum, high temperature, and neutron radiation. CuCrZr is currently of interest as a base material for the manufacture of louvers of RF contacts, which has excellent thermal and electrical properties and has low creep rate at 250 {\textdegree}C. In this study, a hard Au coating (Au-Ni) was electroplated on CuCrZr samples and the samples were then subjected to thermal aging treatment at 250 {\textdegree}C for 500 h in order to simulate the vacuum-commissioning process of the ITER. The effects of thermal aging on the hardness, elastic modulus, crystallite size, and compositions of the coating were investigated via microstructural and mechanical characterizations of the coating material. Metal atom migration in different coating layers during thermal aging was characterized and evaluated via scanning electron microscopy/energy dispersive X-ray spectroscopy observations of the cross-sectional surfaces, and the obtained results could be used to directly select the coating thickness for the final RF contact component. The contact resistance-an important parameter of the RF contact-was measured in a dedicated testbed built to simulate fusion reactor conditions between CuCrZr pins and stainless steel plates coated with Au-Ni and Rh, respectively.
- Published
- 2018
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