1. UV-cross-linked poly(ethylene oxide carbonate) as free standing solid polymer electrolyte for lithium batteries
- Author
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David Mecerreyes, Leire Meabe, Tan Vu Huynh, Luca Porcarelli, Daniele Mantione, Michel Armand, Luke A. O'Dell, Chunmei Li, Haritz Sardon, Maria Forsyth, and European Commission
- Subjects
free-standing polymer ,lithium conductivity ,Materials science ,General Chemical Engineering ,Polycarbonate, Poly(ethylene oxide), Solid polymer electrolyte, Free-standing polymer, electrolyteIonic conductivity, Lithium conductivity, Lithium transference number, 7Li NMR, Lithium battery ,Oxide ,chemistry.chemical_element ,electrolyteIonic conductivity ,02 engineering and technology ,Electrolyte ,010402 general chemistry ,7. Clean energy ,01 natural sciences ,chemistry.chemical_compound ,Electrochemistry ,Ionic conductivity ,poly(ethylene oxide) ,Polycarbonate ,lithium battery ,Ethylene oxide ,solid polymer electrolyte ,021001 nanoscience & nanotechnology ,Lithium battery ,7Li NMR ,0104 chemical sciences ,lithium transference number ,Chemical engineering ,chemistry ,polycarbonate ,13. Climate action ,visual_art ,visual_art.visual_art_medium ,Lithium ,0210 nano-technology ,Lithium Cation - Abstract
The supporting information is attached. Aliphatic polycarbonates have emerged as promising polymer electrolytes due to their combination of moderate ionic conductivity and high lithium transference numbers. However, the mechanical properties of the aliphatic polycarbonates polymer electrolytes are usually weak due to the low molecular weight achieved and plasticization effect of the added lithium salt. In this article, we present a copolymer having poly(ethylene oxide) segments linked by carbonate groups with cross-linkable methacrylic pendant groups. Once the polymer and the lithium salt were mixed, the poly(ethylene oxide carbonate) was cross-linked by UV light producing a free standing solid polymer electrolyte (SPE). Different SPE formulations were designed by varying the LiTFSI concentration within the polymer matrix showing the highest ionic conductivity of 1.3·10−3 S cm−1 and a lithium transference number of 0.59 at 70 °C. 7Li solid-state NMR experiments were used to correlate the lithium cation environment and dynamics with ionic conductivity. At the same temperature the electrochemical stability window was analyzed, and a reasonable value of 4.9 V was achieved. The study was complemented by mechanical and thermal stability measurements. Finally, the optimized UV-cross-linked poly(ethylene oxide carbonate) was tested as electrolyte in lithium metal symmetric cell at 70 °C, showing low over-potential values and a stable solid electrolyte interphase layer. We are grateful to the financial support of the European Research Council by Starting Grant Innovative Polymers for Energy Storage (iPes) 306250 and the Basque Government through ETORTEK Energigune 2013 and IT 999-16. Leire Meabe thanks Spanish Ministry of Education, Culture and Sport for the predoctoral FPU fellowship received to carry out this work. The authors would like to thank the European Commission for their financial support through the project SUSPOL-EJD 642671 and the Gobierno Vasco/Eusko Jaurlaritza (IT 999-16). The authors thank for technical and human support provided by SGIker of UPV/EHU for the NMR facilities of Gipuzkoa campus.
- Published
- 2019