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Sediment traps were deployed in the Tema Harbour to estimate the settling fluxes of silt-clay particles and associated metals (Fe, Mn, Pb, Cr, Cu, Zn, Ni, Hg, Sn and As) and characterise their potential ecotoxicological risks. The mean daily settling fluxes of the silt-clay particles and associated metals ranged from 42.7 to 85.0gm -2 d -1 and 1.3×10 -2 to 49.4mgm -2 d -1 , respectively, and were characterised by large fluctuations at each station. The silt-clay and metal fluxes strongly correlated, indicating the important role of the silt-clay particles in metal transport and distribution in the harbour. Geochemical indices indicated anthropogenic influences on the harbour as the Pb, Cr, Zn, Hg, Sn and As content in the settling silt-clay particles exceeded their average crustal concentrations. Sediment quality guidelines indicated these metals pose appreciable ecotoxicological risks, particularly As. Increasing temporal trends in As necessitates increased pollution control efforts at the harbour., (Copyright © 2017 Elsevier Ltd. All rights reserved.)

Settling fluxes and sediment accumulation rates in coastal Tema Harbour (Ghana) were investigated by the combined analyses of results in sediment traps and sediment cores. Sediment traps were deployed at 5 stations within the Tema Harbour at two sampling depths and were retrieved every two weeks till the end of 12weeks to estimate the Settling Fluxes (SFs). Four sediment cores from the harbour were analysed for their radioactivity ( 7 Be, 234 Th, 210 Pb, 212 Pb, 226 Ra, 40 K and 137 Cs) profiles to quantify Sediment Accumulation Rates (SARs). The sediment cores exhibited variable bulk density profiles, indicating highly dynamic and non-steady sedimentation conditions. 7 Be-derived gross-estimates of very recent SARs using the constant flux-constant sedimentation (CF-CS) model were in the range of 2.5-9.0g·cm -2 ·y -1 . These values were much lower than the estimated average SFs (15.2-53.8g·cm -2 ·y -1 ), indicating sediment resuspension plays an important role. On a decadal time scale, conventional 210 Pb sediment dating models did not allow any estimation of SARs in the Tema Harbour. Thus, the 210 Pb-based TERESA model was applied to depict a reliable scenario for sedimentation with time-averaged SARs in the range of 1.4-3.0g·cm -2 ·y -1 and fluxes of matter contributed by the marine inflow and local sources. Sediment accretion rates of 1.7-3cm·y -1 were also inferred, which may pose a moderate problem of sustainability for the Tema Harbour. This study reveals how the geochemical behaviour of different radionuclides with Gamma spectrometry in the marine environment can be used to obtain reliable information on the complex dynamics of Suspended Particulate Matter (SPM), even in a very disturbed and anthropic environment as a coastal harbour area where (1) conventional 210 Pb-based dating methods fail and (2) the use of sediment traps and 234 Th and 7 Be profiles in sediment cores show serious constraints., (Copyright © 2017 Elsevier B.V. All rights reserved.)

This study assessed DDTs, HCHs and PAHs contamination in sediments from the Tema Harbour (Ghana) and the associated ecotoxicological risks. The results showed widespread DDTs, HCHs and PAHs contamination in the harbour sediments with mean concentrations ranging from 6.0-12.8, 2.8-12.7 and 2750-5130μg·kg -1 d·w, respectively. The silt-clay and total organic carbon contents of the sediments poorly correlated with the pollutant concentrations. DDTs and HCHs contamination relate to past use of DDT and lindane, which under the anoxic harbour conditions resulted in disproportionately higher concentrations of p,p'-DDD and γ-HCH in the sediments. No conclusion could be drawn on the sources of PAHs as either petrogenic or pyrogenic. The pollutant concentrations in the harbour sediments, particularly γ-HCH, may pose high ecotoxicological risks. In comparison to a previous study, this study indicates there has been a considerable reduction in PAH contamination in the Tema Harbour since the last major oil spill in 2007., (Copyright © 2016 Elsevier Ltd. All rights reserved.)