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This study examines the mechanistic processes governing multiphase flow of a water-cosolvent-NAPL system in saturated porous media. Laboratory batch and column flushing experiments were conducted to determine the equilibrium properties of pure NAPL and synthetically prepared NAPL mixtures as well as NAPL recovery mechanisms for different water-ethanol contents. The effect of contact time was investigated by considering different steady and intermittent flow velocities. A modified version of multiphase flow simulator (UTCHEM) was used to compare the multiphase model simulations with the column experiment results. The effect of employing different grid geometries (1D, 2D, 3D), heterogeneity and different initial NAPL saturation configurations was also examined in the model. It is shown that the change in velocity affects the mass transfer rate between phases as well as the ultimate NAPL recovery percentage. The experiments with low flow rate flushing of pure NAPL and the 3D UTCHEM simulations gave similar effluent concentrations and NAPL cumulative recoveries. Model simulations over-estimated NAPL recovery for high specific discharges and rate-limited mass transfer, suggesting a constant mass transfer coefficient for the entire flushing experiment may not be valid. When multi-component NAPLs are present, the dissolution rate of individual organic compounds (namely, toluene and benzene) into the ethanol-water flushing solution is found not to correlate with their equilibrium solubility values., (Copyright © 2012 Elsevier B.V. All rights reserved.)

This paper examines the potential for enhanced NAPL recovery from the subsurface through the combined application of hot water and cosolvent flushing. Batch experiments were conducted to determine the effect of temperature on fluid properties and the multiphase behavior of the ethanol-water-toluene system and to assess the impact of temperature on the capillary, Bond and total trapping numbers and on flooding stability. Column flooding experiments were also conducted to evaluate toluene NAPL recovery efficiency for different ethanol contents and flushing solution temperatures. The ethanol content considered ranged from 20 to 100% by mass, while the flushing solution temperatures were varied from 10 to 40°C. It is shown that small variations in the system temperature can strongly influence the solubilization, mobilization and stability of the multiphase system, but that the impact of temperature on the enhanced NAPL recovery is also dependent on the ethanol content of the flushing solution. The impact of hot water on NAPL recovery was most pronounced at intermediate ethanol contents (40-60% by mass) where the increase in system temperature led to enhanced NAPL solubilization as well as NAPL mobilization. This study demonstrates that coupling of hot water with in situ cosolvent flooding is a potentially effective remedial alternative that can optimize NAPL recovery while reducing the amount of chemicals injected into the subsurface., (Copyright © 2010 Elsevier B.V. All rights reserved.)