Search

(abridged) Far-infrared (FIR) line emission provides key information about the gas cooling and heating due to shocks and UV radiation associated with the early stages of star formation. Gas cooling via FIR lines might, however, depend on metallicity. We aim to quantify the FIR line emission and determine the spatial distribution of the CO rotational temperature, ultraviolet (UV) radiation field, and H2 number density toward the embedded cluster Gy 3-7 in the CMa-l224 star-forming region, whose metallicity is expected to be intermediate between that of the LMC and the Solar neighborhood. By comparing the total luminosities of CO and [O I] toward Gy 3-7 with values found for low- and high-mass protostars extending over a broad range of metallicities, we also aim to identify the possible effects of metallicity on the FIR line cooling within our Galaxy. We studied SOFIA/FIFI-LS spectra of Gy 3-7 covering several FIR lines. The spatial extent of CO high-J (J>14) emission resembles that of the elongated 160 um continuum emission detected with Herschel. The CO transitions from J=14-13 to J=16-15 are detected throughout the cluster and show a median rotational temperature of 170+/-30 K on Boltzmann diagrams. Comparisons to other protostars observed with Herschel show a good agreement with intermediate-mass sources in the inner Galaxy. Assuming an origin of the [O I] and high-J CO emission in UV-irradiated C-shocks, we obtained pre-shock H2 number densities of 10^4-5 cm-3 and UV radiation field strengths of 0.1-10 Habing fields. Far-IR line observations reveal ongoing star formation in Gy 3-7, dominated by intermediate-mass Class 0/I young stellar objects. The ratio of molecular-to-atomic far-IR line emission shows a decreasing trend with bolometric luminosities of the protostars. However, it does not indicate that the low-metallicity has an impact on the line cooling in Gy 3-7., 26 pages, 23 figures

Studies of deuterated isotopologues of complex organic molecules can provide important constraints on their origin in regions of star formation. In particular, the abundances of deuterated species are very sensitive to the physical conditions in the environment where they form. Due to the low temperatures in regions of star formation, these isotopologues are enhanced to significant levels, making detections of multiply-deuterated species possible. However, for complex organic species, only the multiply-deuterated variants of methanol and methyl cyanide have been reported so far. The aim of this paper is to initiate the characterisation of multiply-deuterated variants of complex organic species with the first detection of doubly-deuterated methyl formate, CHD₂OCHO. We use ALMA observations from the Protostellar Interferometric Line Survey (PILS) of the protostellar binary IRAS 16293-2422, in the spectral range of 329.1 GHz to 362.9 GHz. We report the first detection of doubly-deuterated methyl formate CHD₂OCHO in the ISM. The D/H ratio of CHD₂OCHO is found to be 2-3 times higher than the D/H ratio of CH₂DOCHO for both sources, similar to the results for formaldehyde from the same dataset. The observations are compared to a gas-grain chemical network coupled to a dynamical physical model, tracing the evolution of a molecular cloud until the end of the Class 0 protostellar stage. The overall D/H ratio enhancements found in the observations are of the same order of magnitude as the predictions from the model for the early stages of Class 0 protostars. However, the higher D/H ratio of CHD₂OCHO compared to the D/H ratio of CH2₂DOCHO is still not predicted by the model. This suggests that a mechanism is enhancing the D/H ratio of singly- and doubly-deuterated methyl formate that is not in the model, e.g. mechanisms for H-D substitutions.

Context. Methyl isocyanide (CH₃NC) is the isocyanide with the largest number of atoms confirmed in the interstellar medium (ISM),but it is not an abundant molecule, having only been detected towards a handful of objects. Conversely, its isomer, methyl cyanide (CH₃CN), is one of the most abundant complex organic molecules detected in the ISM, with detections in a variety of low- and high-mass sources. Aims.The aims of this work are to determine the abundances of methyl isocyanide in the solar-type protostellar binary IRAS 16293–2422 and to understand the stark abundance differences observed between methyl isocyanide and methyl cyanide in the ISM. Methods. We use Atacama Large Millimeter/submillimeter Array (ALMA) observations from the Protostellar Interferometric Line Survey (PILS) to search for methyl isocyanide and compare its abundance with that of its isomer methyl cyanide. We use a new line catalogue from the Cologne Database for Molecular Spectroscopy (CDMS) to identify methyl isocyanide lines. We also model the chemistry with an updated version of the three-phase chemical kinetics model MAGICKAL, presenting the first chemical modelling of methyl isocyanide to date. Results. We detect methyl isocyanide for the first time in a solar-type protostar, IRAS 16293–2422 B, and present upper limits for itscompanion protostar, IRAS 16293–2422 A. Methyl isocyanide is found to be at least 20 times more abundant in source B compared tosource A, with a CH₃CN/CH₃NC abundance ratio of 200 in IRAS 16293–2422 B and >5517 in IRAS 16293–2422 A. We also present the results of a chemical model of methyl isocyanide chemistry in both sources, and discuss the implications for methyl isocyanide formation mechanisms and the relative evolutionary stages of both sources. The chemical modelling is unable to match the observed CH₃CN/CH₃NC abundance ratio towards the B source at densities representative of that source. The modelling, however, is consistent with the upper limits for the A source. There are many uncertainties in the formation and destruction pathways of methyl isocyanide,and it is therefore not surprising that the initial modelling attempts do not reproduce observations. In particular, it is clear that some destruction mechanism of methyl isocyanide that does not destroy methyl cyanide is needed. Furthermore, these initial model results suggest that the final density plays a key role in setting the abundance ratio. The next steps are therefore to obtain further detections of methyl isocyanide in more objects, as well as undertaking more detailed physico-chemical modelling of sources such as IRAS16293.

Context. Nitrogen chemistry in protoplanetary disks and the freeze-out on dust particles is key for understanding the formation of nitrogen-bearing species in early solar system analogs. In dense cores, 10% to 20% of the nitrogen reservoir is locked up in ices such as NH3, NH4+ and OCN−. So far, ammonia has not been detected beyond the snowline in protoplanetary disks. Aims. We aim to find gas-phase ammonia in a protoplanetary disk and characterize its abundance with respect to water vapor. Methods. Using HIFI on the Herschel Space Observatory, we detected for the first time the ground-state rotational emission of ortho-NH3 in a protoplanetary disk around TW Hya. We used detailed models of the disk’s physical structure and the chemistry of ammonia and water to infer the amounts of gas-phase molecules of these species. We explored two radial distributions (extended across the disk and confined to

CONTEXT: Hydrides are simple compounds containing one or a few hydrogen atoms bonded to a heavier atom. They are fundamental precursor molecules in cosmic chemistry and many hydride ions have become observable in high quality for the first time thanks to the Herschel Space Observatory. Ionized hydrides such as CH⁺ and OH⁺ (and also HCO⁺), which affect the chemistry of molecules such as water, provide complementary information on irradiation by far-UV (FUV) or X-rays and gas temperature. AIMS: We explore hydrides of the most abundant heavier elements in an observational survey covering young stellar objects (YSOs) with different mass and evolutionary state. The focus is on hydrides associated with the dense protostellar envelope and outflows, contrary to previous work that focused on hydrides in diffuse foreground clouds. METHODS: Twelve YSOs were observed with HIFI on Herschel in six spectral settings providing fully velocity-resolved line profiles as part of the Water in star-forming regions with Herschel (WISH) program. The YSOs include objects of low (Class 0 and I), intermediate, and high mass, with luminosities ranging from 4 L⊙ to 2 × 105 L⊙. RESULTS: The targeted lines of CH⁺, OH⁺, H₂O⁺+, C⁺, and CH are detected mostly in blue-shifted absorption. H₃O⁺ and SH⁺ are detected in emission and only toward some high-mass objects. The observed line parameters and correlations suggest two different origins related to gas entrained by the outflows and to the circumstellar envelope. The derived column densities correlate with bolometric luminosity and envelope mass for all molecules, best for CH, CH⁺, and HCO⁺. The column density ratios of CH⁺/OH⁺ are estimated from chemical slab models, assuming that the H₂ density is given by the specific density model of each object at the beam radius. For the low-mass YSOs the observed ratio can be reproduced for an FUV flux of 2–400 times the interstellar radiation field (ISRF) at the location of the molecules. In two high-mass objects, the UV flux is 20–200 times the ISRF derived from absorption lines, and 300–600 ISRF using emission lines. Upper limits for the X-ray luminosity can be derived from H₃O⁺ observations for some low-mass objects. CONCLUSIONS: If the FUV flux required for low-mass objects originates at the central protostar, a substantial FUV luminosity, up to 1.5 L⊙, is required. There is no molecular evidence for X-ray induced chemistry in the low-mass objects on the observed scales of a few 1000 AU. For high-mass regions, the FUV flux required to produce the observed molecular ratios is smaller than the unattenuated flux expected from the central object(s) at the Herschel beam radius. This is consistent with an FUV flux reduced by circumstellar extinction or by bloating of the protostar.

Water probes the dynamics in young stellar objects (YSOs) effectively, especially shocks in molecular outflows. It is a key molecule for exploring whether the physical properties of low-mass protostars can be extrapolated to massive YSOs. As part of the WISH key programme, we investigate the dynamics and the excitation conditions of shocks along the outflow cavity wall as function of source luminosity. Velocity-resolved Herschel-HIFI spectra of the H2O 988, 752, 1097 GHz and 12CO J=10-9, 16-15 lines were analysed for 52 YSOs with bolometric luminosities (L_bol) ranging from 10^5 L_sun. The profiles of the H2O lines are similar, indicating that they probe the same gas. We see two main Gaussian emission components in all YSOs: a broad component associated with non-dissociative shocks in the outflow cavity wall (cavity shocks) and a narrow component associated with quiescent envelope material. More than 60% of the total integrated intensity of the H2O lines (L_H2O) comes from the cavity shock component. The H2O line widths are similar for all YSOs, whereas those of 12CO 10-9 increase slightly with L_bol. The excitation analysis of the cavity shock component, performed with the non-LTE radiative transfer code RADEX, shows stronger 752 GHz emission for high-mass YSOs, likely due to pumping by an infrared radiation field. As previously found for CO, a strong correlation with slope unity is measured between log(L_H2O) and log(L_bol), which can be extrapolated to extragalactic sources. We conclude that the broad component of H2O and high-J CO lines originate in shocks in the outflow cavity walls for all YSOs, whereas lower-J CO transitions mostly trace entrained outflow gas. The higher UV field and turbulent motions in high-mass objects compared to their low-mass counterparts may explain the slightly different kinematical properties of 12CO 10-9 and H2O lines from low- to high-mass YSOs., Abridged abstract, 31 pages, 18 figures, 12 tables, accepted in Astronomy & Astrophysics

We performed a sensitive search for the ground-state emission lines of ortho- and para-water vapor in the DM Tau protoplanetary disk using the Herschel/HIFI instrument. No strong lines are detected down to 3σ levels in 0.5 km s-1 channels of 4.2 mK for the 110–101 line and 12.6 mK for the 111–000 line. We report a very tentative detection, however, of the 110–101 line in the wide band spectrometer, with a strength of Tmb = 2.7 mK, a width of 5.6 km s-1 and an integrated intensity of 16.0 mK km s-1. The latter constitutes a 6σ detection. Regardless of the reality of this tentative detection, model calculations indicate that our sensitive limits on the line strengths preclude efficient desorption of water in the UV illuminated regions of the disk. We hypothesize that more than 95–99% of the water ice is locked up in coagulated grains that have settled to the midplane.