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This study analyses the variability and trends of ultraviolet-B (UV-B, wavelength 280–320 nm) radiation that can cause DNA damage. The variability and trends caused by climate change due to enhanced greenhouse gas (GHG) concentrations. The analysis is based on DNA-active irradiance, total ozone, total cloud cover, and surface albedo calculations with the European Centre for Medium-Range Weather Forecasts – Hamburg (ECHAM)/Modular Earth Submodel System (MESSy) Atmospheric Chemistry (EMAC) chemistry–climate model (CCM) free-running simulations following the RCP 6.0 climate scenario for the period 1960–2100. The model output is evaluated with DNA-active irradiance ground-based measurements, satellite SBUV (v8.7) total-ozone measurements, and satellite MODerate-resolution Imaging Spectroradiometer (MODIS) Terra cloud cover data. The results show that the model reproduces the observed variability and change in total ozone, DNA-active irradiance, and cloud cover for the period 2000–2018 quite well according to the statistical comparisons. Between 50∘ N–50∘ S, the DNA-damaging UV radiation is expected to decrease until 2050 and to increase thereafter, as was shown previously by Eleftheratos et al. (2020). This change is associated with decreases in the model total cloud cover and negative trends in total ozone after about 2050 due to increasing GHGs. The new study confirms the previous work by adding more stations over low latitudes and mid-latitudes (13 instead of 5 stations). In addition, we include estimates from high-latitude stations with long-term measurements of UV irradiance (three stations in the northern high latitudes and four stations in the southern high latitudes greater than 55∘). In contrast to the predictions for 50∘ N–50∘ S, it is shown that DNA-active irradiance will continue to decrease after the year 2050 over high latitudes because of upward ozone trends. At latitudes poleward of 55∘ N, we estimate that DNA-active irradiance will decrease by 8.2 %±3.8 % from 2050 to 2100. Similarly, at latitudes poleward of 55∘ S, DNA-active irradiance will decrease by 4.8 % ± 2.9 % after 2050. The results for the high latitudes refer to the summer period and not to the seasons when ozone depletion occurs, i.e. in late winter and spring. The contributions of ozone, cloud, and albedo trends to the DNA-active irradiance trends are estimated and discussed.

We calculate the variation of spectral solar irradiance in the umbral shadow of the total solar eclipse of 21 August 2017 and compare it to observations. Starting from the Sun's and Moon's positions, we derive a realistic profile of the lunar shadow at the top of the atmosphere, including the effect of solar limb darkening. Subsequently, the Monte Carlo model MYSTIC (Monte Carlo code for the phYSically correct Tracing of photons In Cloudy atmospheres) is used to simulate the transfer of solar radiation through the Earth's atmosphere. Among the effects taken into account are the atmospheric state (pressure, temperature), concentrations of major gas constituents and the curvature of the Earth, as well as the reflectance and elevation of the surrounding area. We apply the model to the total solar eclipse on 21 August 2017 at a position located in Oregon, USA, where irradiance observations were performed for wavelengths between 306 and 1020 nm. The influence of the surface reflectance, the ozone profile, the mountains surrounding the observer and aerosol is investigated. An increased sensitivity during totality is found for the reflectance, aerosol and topography, compared to non-eclipse conditions. During the eclipse, the irradiance at the surface not only depends on the total ozone column (TOC) but also on the vertical ozone distribution, which in general complicates derivations of the TOC from spectral surface irradiance. The findings are related to an analysis of the prevailing photon path and its difference compared to non-eclipse conditions. Using the most realistic estimate for each parameter, the model is compared to the irradiance observations. During totality, the relative difference between model and observations is less than 10 % in the spectral range from 400 to 1020 nm. Slightly larger deviations occur in the ultraviolet range below 400 and at 665 nm.

Measurements of spectral irradiance between 306 and 1020 nm were performed with a GUVis-3511 multi-channel filter radiometer at Smith Rock State Park, Oregon, during the total solar eclipse of 21 August 2017. The radiometer was equipped with a shadowband, allowing the separation of the global (sun and sky) and direct components of solar radiation. Data were used to study the wavelength-dependent changes in solar irradiance at Earth's surface. Results were compared with theoretical predictions using three different parameterizations of the solar limb darkening (LD) effect, which describes the change in the solar spectrum from the Sun's center to its limb. Results indicate that the LD parameterization that has been most widely used during the last 15 years underestimates the LD effect, in particular at UV wavelengths. The two alternative parameterizations are based on two independent sets of observations from the McMath–Pierce solar telescope. When these parameterizations are used, the observed and theoretical LD effects agree to within 4 % for wavelengths larger than 400 nm and occultation of the solar disk of up to 97.8 %. Maximum deviations for wavelengths between 315 and 340 nm are 7 %. These somewhat larger differences compared to the visible range may be explained with varying aerosol conditions during the period of observations. The aerosol optical depth (AOD) and its wavelength dependence was calculated from measurements of direct irradiance. When corrected for the LD effect, the AOD decreases over the period of the eclipse: from 0.41 to 0.34 at 319 nm and from 0.05 to 0.04 at 1018 nm. These results show that AODs can be accurately calculated during an eclipse if the LD effect is corrected. The total ozone column (TOC) was derived from measurements of global irradiance at 306 and 340 nm. Without correction for the LD effect, the retrieved TOC increases by 20 DU between the first and second contact of the eclipse. With LD correction, the TOC remains constant to within natural variability (±2.6 DU or ±0.9 % between first and second contact and ±1.0 DU or ±0.3 % between third and fourth contact). In contrast to results of observations from earlier solar eclipses, no fluctuations in TOC were observed that could be unambiguously attributed to gravity waves, which can be triggered by the supersonic speed of the Moon's shadow across the atmosphere. Furthermore, systematic changes in the ratio of direct and global irradiance that could be attributed to the solar eclipse were not observed, in agreement with results of three-dimensional (3-D) radiative transfer (RT) models. Our results advance the understanding of the effects of solar LD on the spectral irradiance at Earth's surface, the variations in ozone during an eclipse, and the partitioning of solar radiation in direct and diffuse components.

A GUV multifilter radiometer was set up at Marambio, 64° S 56° W, Antarctica, in 2017. The instrument measures continuously ultraviolet (UV) radiation, visible (VIS) radiation and photosynthetically active radiation (PAR). The measurements are designed for providing high quality long-term time series which can be used to assess the impact of global climate change in the Antarctic region. The quality assurance includes regular absolute calibrations and solar comparisons performed at the site and at Sodankylä, Finland. The actual measurements continue the time series measured at Marambio with NILU-UV radiometers during 2000–2010 as part of the Antarctic NILU-UV network. They are optimal for assessing the effects of the ongoing stratospheric ozone recovery on the ecosystem as the data products include information on radiation at various wavelengths ranging from UV to VIS so that changes on biologically effective radiation due to ozone can be separated from those due to other factors. The final data products are total ozone, PAR, VIS radiation at 555 nm, UV index, UV irradiance at 5 channels, UVB and UVA dose rate/daily dose, and biologically weighted UV dose rate/ daily dose, including 10 different action spectra. The data from the last five days and the daily maximum UV index time series are plotted and updated daily on the web page fmiarc.fmi.fi/sub_sites/GUVant/. The first two years of UV measurements were very different in terms of the results: The monthly average of daily maximum UVB dose rates were clearly higher in 2018 than in 2017 during the period from October to December. The largest difference was observed in October, when the average of daily maximum UVB dose rates was 7.6 kWm−2 and 10.2 kWm−2 in 2017 and 2018, respectively. The monthly averages were close to each other for all the three months in 2018, while in 2017 the monthly average of October was lower than those of November and December. VIS and PAR time series show that daily maxima in 2018–2019 exceed those in 2017–2018 during the late spring and the summer (mid-November–January). The studied dataset is freely accessible at https://doi.org/10.5281/zenodo.3553634 (Lakkala et al.,2019).

We calculate the variation of spectral solar irradiance in the umbral shadow of the total solar eclipse of August 21, 2017 and compare it to observations. Starting from the sun's and moon's positions, we derive a realistic profile of the lunar shadow at the top of the atmosphere, including the effect of solar limb darkening. Subsequently, the Monte-Carlo model MYSTIC is used to simulate the transfer of solar radiation through the earth's atmosphere. Among the effects taken into account are the atmospheric state (pressure, temperature), concentrations of major gas constituents and the curvature of the earth, as well as the reflectance and elevation of the surrounding area. We apply the model to the total solar eclipse on August 21, 2017 at a position located in Oregon, where irradiance observations were performed for wavelengths between 306 nm and 1020 nm. The influence of the surface reflectance, the ozone profile and mountains surrounding the observer is investigated. An increased sensitivity during totality is found for the reflectance and topography, compared to non-eclipse conditions. During the eclipse, the irradiance at the surface does not only depend on the total ozone column (TOC) but also the vertical ozone distribution, which in general complicates derivations of the TOC from spectral surface irradiance. The findings are related to an analysis of the prevailing photon path and its difference compared to non-eclipse conditions. Using the most realistic estimate for each parameter, the model is compared to the irradiance observations. During totality, the relative difference between model and observations is less than 10 % in the spectral range from 400 nm to 1020 nm. Slightly larger deviations occur in the ultraviolet range below 400 nm and at 665 nm.

Measurements of spectral irradiance between 306 and 1020 nm were performed with a GUVis-3511 multi-channel filter radiometer at Smith Rock State Park, Oregon, during the total solar eclipse of 21 August 2017. The radiometer was equipped with a shadowband, allowing to separate the global (sun and sky) and direct components of solar radiation. Data were used to study the wavelength-dependent changes of solar irradiance at Earth's surface. Results were compared with theoretical predictions using three different parameterizations of the solar limb darkening (LD) effect, which describes the change of the solar spectrum from the Sun's center to its limb. Results indicate that the LD parameterization that has been most widely used during the last 15 years underestimates the LD effect, in particular at UV wavelengths. The two alternative parameterizations are based on two independent sets of observations from the McMath-Pierce Solar Telescope. When these parameterizations are used, the observed and theoretical LD effects agree to within 4 % for wavelengths larger than 400 nm and occultation of the solar disk of up to 97.8 %. Maximum deviations for wavelengths between 315 and 340 nm are 7 %. These somewhat larger differences compared to the visible range may be explained with varying aerosol conditions during the period of observations. Aerosol optical depth (AOD) and its wavelength dependence was calculated from measurements of direct irradiance. When corrected for the LD effect, AOD monotonically decreases over the period of the eclipse: from 0.41 to 0.32 at 319 nm and from 0.05 to 0.04 at 1018 nm. These results show that AODs can be accurately calculated during an eclipse if the LD effect is corrected. The total ozone column (TOC) was derived from measurements of global irradiance at 306 and 340 nm. Without correction for the LD effect, the retrieved TOC increases by 20 DU between the 1st and 2nd contact of the eclipse. With LD correction, the TOC remains constant to within natural variability (±2.6 DU or ±0.9 % between 1st and 2nd contact and ±1.0 DU or ±0.3 % between 3rd and 4th contact). In contrast to results of observations from earlier solar eclipses, no fluctuations in TOC were observed that could be attributed to gravity waves, which can be triggered by the supersonic speed of the Moon's shadow across the atmosphere. Furthermore, systematic changes in the ratio of direct and global irradiance that could be attributed to the solar eclipse were not observed. This finding agrees with results of three-dimensional radiative transfer models but contradicts reports from earlier observations, which indicate that the diffuse-to-direct ratio may change by 30 %. Our results advance the understanding of the effects of solar LD on the spectral irradiance at Earth's surface, the variations of ozone during an eclipse, and the partitioning of solar radiation in direct and diffuse components.

The 19 channel rotating shadow band radiometer GUVis-3511 built by Biospherical Instruments is introduced as an instrument which is able to provide automated ship borne measurements of the direct, diffuse and global spectral irradiance components without a requirement for stabilization. Several direct sun products, including spectral direct beam transmittance, aerosol optical depth, Angström exponent, and precipitable water can be derived from these observations. The individual steps of the data analysis are described, and the different sources of uncertainty are discussed. The total uncertainty of the observed direct beam transmittances is estimated to be 4.24 % at 95 % CI for ship borne operation. The calibration is identified as the dominating contribution to the total uncertainty. A comparison of direct beam transmittance with those obtained from a Cimel sun photometer at a land site and a manually operated Microtops II sun photometer on a ship is presented, yielding relative deviations of less than 3 % and 4 % on land and on ship, respectively, for most channels and in agreement with our previous uncertainty estimate. These numbers demonstrate that the instrument is well suited for ship borne operation, and the applied methods for motion correction work accurately. Based on spectral direct beam transmittance, aerosol optical depth at 510 nm can be retrieved with an uncertainty of 0.0032 for a 95 % CI. Only minor deviations occur due to the different methods used for estimating Rayleigh scattering and gas absorption optical depths, as implemented by AERONET and in our processing. Relying on the cross-calibration of the 940 nm water vapor channel with the Cimel sun photometer, the column amount of precipitable water has been estimated with an uncertainty of +−0.034 cm. More research is needed to estimate the accuracy of the instrument for low sun (solar zenith angles larger than 70°) and during periods with strong swell.

Spectral ultraviolet (UV) irradiance has been observed near Barrow, Alaska (71° N, 157° W) between 1991 and 2011 with an SUV-100 spectroradiometer. The instrument was historically part of the US. National Science Foundation's UV Monitoring Network and is now a component of NSF's Arctic Observing Network. From these measurements, trends in monthly average irradiance and their uncertainties were calculated. The analysis focuses on two quantities, the UV Index (which is affected by atmospheric ozone concentrations) and irradiance at 345 nm (which is virtually insensitive to ozone). Uncertainties of trend estimates depend on variations in the data due to (1) natural variability, (2) systematic and random errors of the measurements, and (3) uncertainties caused by gaps in the time series. Using radiative transfer model calculations, systematic errors of the measurements were detected and corrected. Different correction schemes were tested to quantify the sensitivity of the trend estimates on the treatment of systematic errors. Depending on the correction method, estimates of decadal trends changed between 1.5% and 2.9%. Uncertainties in the trend estimates caused by error sources (2) and (3) were set into relation with the overall uncertainty of the trend determinations. Results show that these error sources are only relevant for February, March, and April when natural variability is low due to high surface albedo. This method of addressing measurement uncertainties in time series analysis is also applicable to other geophysical parameters. Trend estimates varied between −14% and +5% per decade and were significant (95.45% confidence level) only for the month of October. Depending on the correction method, October trends varied between −11.4% and −13.7% for irradiance at 345 nm and between −11.7% and −14.1% for the UV Index. These large trends are consistent with trends in short-wave (0.3–3.0 μm) solar irradiance measured with pyranometers at NOAA's Barrow Observatory and can be explained by a change in snow cover over the observation period: analysis of pyranometer data indicates that the first day of fall when albedo becomes larger than 0.6 after snow fall, and remains above 0.6 for the rest of the winter, has advanced with a statistically significant trend of 13.6 ± 9.7 days per decade.