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The long-term stability of soil organic carbon (SOC) is controlled by stabilization mechanisms, among which physical stabilization through microaggregate (

We present a multi-proxy approach to reconstruct Middle Bronze Age (MBA, 1600-1250 BCE) land use practices in the north-western Alpine foreland (SW Germany, Hegau). We combined biogeochemical proxies from multi-layered colluvial deposits and archaeobotanical and archaeozoological data within and in the surrounding of the archaeologically well-documented settlement site of Anselfingen. Offsite pollen data from two peat bogs were used to place the onsite and near-site vegetation and land use data to a regional context.Phases of colluvial deposition were reconstructed by optically stimulated luminescence (OSL) and radiocarbon (AMS 14C) dating. The first phase of major colluviation could be correlated with MBA land use followed by phases of colluvial deposition during the Iron Age, the Medieval period, and modern times. Charcoal spectra from colluvial deposits and archaeological structures indicate MBA forest management favoring Quercus in the surrounding area north of the settlement. The analysis of faecal biomarker (5ß-stanols up to 40 %) and excavated pig bones (up to 14 %) suggest the presence of a forest pasture mainly used for pig farming. In the surrounding area south of the settlement, an arable field with a buried MBA plough horizon (2Apb) could be verified by soil micromorphological features such as very dusty clay coatings and a banded microstructure and by high concentrations of grass phytoliths from leaves and stems. Agricultural practices (e.g. ploughing) focused on five staple cereal crops (Hordeum distichon/vulgare, Triticum dicoccum, Triticum monococcum, Triticum spelta, Triticum aestivum/turgidum) as indicated by the onsite archaeobotanical records. Stilted pantries, reconstructed from MBA post-holes, were interpreted as storage facilities, while excavated heat stones are likely to indicate post-harvest processing of cereal crops and other agrarian products. Higher levels of urease activity compared to microbial biomass carbon (up to 2.1 µg N µg Cmic-1), and input of herbivorous animal faeces indicate livestock husbandry on fallow land or manuring practices. The suites of polycyclic aromatic hydrocarbons (PAHs) and their spatial distribution indicate the use of fire for various purposes, e.g. for landscape opening and maintenance, for domestic burning and for technical applications. The offsite pollen data support the onsite and near-site vegetation change. During the MBA, fire played a major role in shaping the landscape (peak of micro-charcoal during the MBA in the offsite pollen records) and anthropogenic activities promoted oak dominated forest vegetation at the expense of natural beech forests. This approves a broad regional human influence in the north-western Alpine foreland during the MBA.Our data allow in-depth insights into the MBA subsistence economy on a local and regional scale, which was not limited to settlements at lakeshore sites. The MBA in the north-western Alpine foreland was a period of establishing settlements with sophisticated land management and land use practices also at low and mid altitude inland sites. We could further show that colluvial deposits are promising archives for the reconstruction of past land use practices.

In order to assess the intrinsic heterogeneity of paddy soils, a set of biogeochemical soil parameters was investigated in five field replicates of seven paddy fields (50, 100, 300, 500, 700, 1000, and 2000 yr of wetland rice cultivation), one flooded paddy nursery, one tidal wetland (TW), and one freshwater site (FW) from a coastal area at Hangzhou Bay, Zhejiang Province, China. All soils evolved from a marine tidal flat substrate due to land reclamation. The biogeochemical parameters based on their properties were differentiated into (i) a group behaving conservatively (TC, TOC, TN, TS, magnetic susceptibility, soil lightness and colour parameters, δ13C, δ15N, lipids and n-alkanes) and (ii) one encompassing more labile properties or fast cycling components (Nmic, Cmic, nitrate, ammonium, DON and DOC). The macroscale heterogeneity in paddy soils was assessed by evaluating intra- versus inter-site spatial variability of biogeochemical properties using statistical data analysis (descriptive, explorative and non-parametric). Results show that the intrinsic heterogeneity of paddy soil organic and minerogenic components per field is smaller than between study sites. The coefficient of variation (CV) values of conservative parameters varied in a low range (10% to 20%), decreasing from younger towards older paddy soils. This indicates a declining variability of soil biogeochemical properties in longer used cropping sites according to progress in soil evolution. A generally higher variation of CV values (>20–40%) observed for labile parameters implies a need for substantially higher sampling frequency when investigating these as compared to more conservative parameters. Since the representativeness of the sampling strategy could be sufficiently demonstrated, an investigation of long-term carbon accumulation/sequestration trends in topsoils of the 2000 yr paddy chronosequence under wetland rice cultivation restricted was conducted. Observations cannot be extrapolated to global scale but with coastal paddy fields developed on marine tidal flat substrates after land reclamation in the Zhejiang Province represent a small fraction (2 sequestration potential when marine tidal wetland substrate developed to 2000 yr old paddy soil.