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The transfer of carbon from land to the near-coastal ocean is increasingly being recognized in global carbon budgets. However, a more direct transfer of terrestrial carbon to the deep-sea is comparatively overlooked. Among systems that connect coastal to deep-sea environments, the Congo Submarine Canyon is of particular interest since the canyon head starts 30 km into the Congo River estuary, which delivers ~7 % of the total organic carbon from the world's rivers. However, carbon and sediment transport mechanisms that operate in the Congo Canyon, and submarine canyons more globally, are poorly constrained compared to rivers because monitoring of deep-sea canyons remains challenging. Using a novel array of acoustic instruments, sediment traps and cores, this study seeks to understand the hydrodynamic processes that control delivery of particulate organic carbon via the Congo Submarine Canyon to the deep-sea. We show that particulate organic carbon transport in the canyon-axis is modulated by two processes. First, we observe periods where the canyon dynamics are dominated by tides, which induce a background oscillatory flow (speeds of up to 0.15 m/s) through the water column, keeping muds in suspension, with a net upslope transport direction. Second, fast-moving (up to 8 m/s) turbidity currents occur for 35 % of the time during monitoring periods and transport both muddy and sandy particulate organic carbon at an estimated transit flux that is more than ten times the flux induced by tides. Remarkably, organic carbon transported and deposited in the submarine canyon has a similar isotopic composition to organic carbon in the Congo River, and in the deep-sea fan at 5 km of water depth. Episodic turbidity currents, together with background tidal currents thus promote efficient transfer of river-derived particulate organic carbon in the Congo Submarine Fan, leading to some of the highest terrestrial carbon preservation rates observed in marine sediments globally. [ABSTRACT FROM AUTHOR]

In mountain ranges, earthquakes can trigger widespread landsliding and mobilize large amounts of organic carbon by eroding soil and vegetation from hillslopes. Following a major earthquake, the landslide-mobilized organic carbon can be exported from river catchments by physical sediment transport processes or stored within the landscape where it may be degraded by heterotrophic respiration. The competition between these physical and biogeochemical processes governs a net transfer of carbon between the atmosphere and sedimentary organic matter, yet their relative importance following a large landslide-triggering earthquake remains poorly constrained. Here, we propose a model framework to quantify the post-seismic redistribution of soil-derived organic carbon. The approach combines predictions based on empirical observations of co-seismic sediment mobilization with a description of the physical and biogeochemical processes involved after an earthquake. Earthquake-triggered landslide populations are generated by randomly sampling a landslide area distribution, a proportion of which is initially connected to the fluvial network. Initially disconnected landslide deposits are transported downslope and connected to rivers at a constant velocity in the post-seismic period. Disconnected landslide deposits lose organic carbon by heterotrophic oxidation, while connected deposits lose organic carbon synchronously by both oxidation and river export. The modeling approach is numerically efficient and allows us to explore a large range of parameter values that exert a control on the fate of organic carbon in the upland erosional system. We explore the role of the climatic context (in terms of mean annual runoff and runoff variability) and rates of organic matter degradation using single pool and multi-pool models. Our results highlight the fact that the redistribution of organic carbon is strongly controlled by the annual runoff and the extent of landslide connection, but less so by the choice of organic matter degradation model. In the context of mountain ranges typical of the southwestern Pacific region, we find that model configurations allow more than 90 % of the landslide-mobilized carbon to be exported from mountain catchments. A simulation of earthquake cycles suggests efficient transfer of organic carbon out of a mountain range during the first decade of the post-seismic period. Pulsed erosion of organic matter by earthquake-triggered landslides is therefore an effective process to promote carbon sequestration in sedimentary deposits over thousands of years. [ABSTRACT FROM AUTHOR]

Oxidative weathering of sedimentary rocks can release carbon dioxide (CO2) to the atmosphere and is an important natural CO2 emission. Two mechanisms operate -- the oxidation of sedimentary organic matter and the dissolution of carbonate minerals by sulfuric acid. It has proved difficult to directly measure the rates at which CO2 is emitted in response to these weathering processes in the field, with previous work generally using methods which track the dissolved products of these reactions in rivers. Here we design a chamber method to measure CO2 production during the oxidative weathering of shale bedrock, which can be applied in erosive environments where rocks are exposed frequently to the atmosphere. The chamber is drilled directly into the rock face and has a high surface-area-to-volume ratio which benefits measurement of CO2 fluxes. It is a relatively low-cost method and provides a long-lived chamber (several months or more). To partition the measured CO2 fluxes and the source of CO2, we use zeolite molecular sieves to trap CO2 "actively" (over several hours) or "passively" (over a period of months). The approaches produce comparable results, with the trapped CO2 having a radiocarbon activity (fraction modern, Fm) ranging from FmD0.05 to FmD 0.06 and demonstrating relatively little contamination from local atmospheric CO2 (FmD1.01). We use stable carbon isotopes of the trapped CO2 to partition between an organic and inorganic carbon source. The measured fluxes of rockderived organic matter oxidation (171-5 mgCm river chemistry in rivers around the world. The high oxidative weathering fluxes are consistent with the high erosion rate of the study region. We propose that our in situ method has the potential to be more widely deployed to directly measure CO2 fluxes during the oxidative weathering of sedimentary rocks, allowing for the spatial and temporal variability in these fluxes to be determined. [ABSTRACT FROM AUTHOR]

Oxidative weathering of sedimentary rocks can release carbon dioxide (CO2) to the atmosphere and is an important natural CO2 emission. Two mechanisms operate - the oxidation of sedimentary organic matter and the dissolution of carbonate minerals by sulphuric acid. It has proved difficult to directly measure the rates of these weathering processes in the field, with previous work generally using indirect methods which track the dissolved products of these reactions in rivers. Here we design a chamber method to measure CO2 production during the oxidative weathering of shale bedrock, which can be applied in erosive environments where rocks are exposed frequently to the atmosphere. The chamber is drilled directly into the rock face and is a relatively low cost method to provide a long-lived (several months or more), oxygenated environment in contact with a surface area of potential reactant. To partition the measured CO2 fluxes and the source of CO2, we use zeolite molecular sieves to trap CO2 actively (over several hours) or passively (over a period of months). The approaches produce comparable results, with the trapped CO2 having a fraction modern ranging from 0.05 to 0.06 and demonstrating relatively little contamination from local atmospheric CO2 (fraction modern of 1.01). We use stable isotopes of the trapped CO2 to partition between an organic and inorganic carbon source. The measured fluxes of rock-derived organic matter oxidation and carbonate dissolution by sulphuric acid from a single chamber were high, but consistent with the high erosion rate of the study region (of ~ 5 mm yr-1). We propose our in situ method has the potential to be more widely deployed to directly measure CO2 fluxes during the oxidative weathering of sedimentary rocks, allowing for the spatial and temporal variability in these fluxes to be determined. [ABSTRACT FROM AUTHOR]