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An in-depth examination of rheology within the deep sections of polar ice sheets is essential for enhancing our understanding of glacial flow. In this study, we investigate the crystalline textural properties of the 3035-m-long Antarctic deep ice core, with a particular emphasis on its lowermost 20 %. We examine the crystal orientation fabric (COF) and compare it with various other properties from the ice core. In the uppermost approximately 80 % thickness zone (UP80 %), the clustering strength of single pole COF steadily increased, reaching its possible maximum at the bottom of the UP80 %. Below 1800 m in the UP80 %, layers with more or fewer dusty impurities exhibit slower or faster growth of cluster strength. This situation continued until 2650 m. In the remaining lowermost approximately 20 % thickness zone (LO20 %), the trend of the COF clustering strength changed around 2650 m and exhibited substantial fluctuations below this depth. In more impurity-rich layers, stronger clustering is maintained. In impurity-poor layers, relaxation of the COF clustering occurred due to the emergence of new crystal grains with c -axis orientation distinctly offset from the existing cluster, and dynamic recrystallization related to this emergence. The less impure layers show apparent features of bulging and migrating grain boundaries. We argue that the substantial deformational regime of polar ice sheets involves dislocation creep in both UP80 % and LO20 %, with dynamic recrystallization playing a critical role in the LO20 %, particularly in impurity-poor layers, to recover a potential of COF available for the continuation of dislocation-creep-based deformation. Furthermore, we observe that layers and cluster axes of COF rotate meridionally due to rigid-body rotation caused by simple shear strain above subglacial slopes. These features provide vital clues for the development of the 3D structure of polar ice sheets in the deeper part, leading to inhomogeneous deformation between layers in various thickness scales, and the formation of folds, faults and mixing depending on the layers. [ABSTRACT FROM AUTHOR]

To investigate regional and temporal variations in the sources and atmospheric transport processes for mineral dust deposited on the Greenland Ice Sheet, we analysed the morphology and mineral composition of dust in an ice core from northeastern Greenland (East Greenland Ice-Core Project, EGRIP), representing the period from 1910 to 2013, using scanning electron microscopy and energy-dispersive X-ray spectroscopy, and compared the results with those previously obtained for an ice core from northwestern Greenland (SIGMA-D). The composition of the SIGMA-D ice-core dust, comprising mostly silicate minerals, varied on a multi-decadal timescale due to an increased contribution of minerals originating from local ice-free areas during recent warming periods. In contrast, for the EGRIP ice-core dust, also consisting mostly of silicate minerals, there was relatively low compositional variation among the samples, suggesting that the mineral sources have not changed dramatically over the past 100 years. The subtle variation in the EGRIP ice-core mineral composition is likely due to a minor contribution of local dust. The type of silicate minerals differed significantly between the two ice cores; micas and chlorite, which form in cold dry regions, were abundant in the EGRIP ice core, whereas kaolinite, which forms in warm humid regions, was abundant in the SIGMA-D ice core. This indicates that the EGRIP ice-core dust likely originated from different geological sources than those for the SIGMA-D dust. A back-trajectory analysis indicated that the ice-core dust was transported from Northern Eurasia and North America to the EGRIP site, and that the contribution from each source was likely smaller and larger, respectively, than those for the SIGMA-D ice core. Furthermore, the higher illite content in the EGRIP ice core suggests dust transportation from Asian deserts. Although the back-trajectory analysis suggests that most of the air mass that arrived at the EGRIP site came from the Greenland coast, the mineral grain size and composition results showed that the local dust contribution was likely small. [ABSTRACT FROM AUTHOR]

Black carbon (BC) particles in the Arctic contribute to rapid warming of the Arctic by heating the atmosphere and snow and ice surfaces. Understanding the source contributions to Arctic BC is therefore important, but they are not well understood, especially those for atmospheric and snow radiative effects. Here we estimate simultaneously the source contributions of Arctic BC to near-surface and vertically integrated atmospheric BC mass concentrations (MBC_SRF and MBC_COL), BC deposition flux (MBC_DEP), and BC radiative effects at the top of the atmosphere and snow surface (RE BC_TOA and RE BC_SNOW) and show that the source contributions to these five variables are highly different. In our estimates, Siberia makes the largest contribution to MBC_SRF , MBC_DEP , and RE BC_SNOW in the Arctic (defined as >70 ∘ N), accounting for 70 %, 53 %, and 41 %, respectively. In contrast, Asia's contributions to MBC_COL and RE BC_TOA are largest, accounting for 37 % and 43 %, respectively. In addition, the contributions of biomass burning sources are larger (29 %–35 %) to MBC_DEP , RE BC_TOA , and RE BC_SNOW , which are highest from late spring to summer, and smaller (5.9 %–17 %) to MBC_SRF and MBC_COL , whose concentrations are highest from winter to spring. These differences in source contributions to these five variables are due to seasonal variations in BC emission, transport, and removal processes and solar radiation, as well as to differences in radiative effect efficiency (radiative effect per unit BC mass) among sources. Radiative effect efficiency varies by a factor of up to 4 among sources (1471–5326 W g -1) depending on lifetimes, mixing states, and heights of BC and seasonal variations of emissions and solar radiation. As a result, source contributions to radiative effects and mass concentrations (i.e., RE BC_TOA and MBC_COL , respectively) are substantially different. The results of this study demonstrate the importance of considering differences in the source contributions of Arctic BC among mass concentrations, deposition, and atmospheric and snow radiative effects for accurate understanding of Arctic BC and its climate impacts. [ABSTRACT FROM AUTHOR]

The crystal orientation fabric (COF) of a polar ice sheet has a significant effect on the rheology of the ice sheet. With the aim of better understanding the deformation regime of ice sheets, the work presented here investigates the COF in the upper 80 % of the Dome Fuji Station ice core in East Antarctica. Dielectric anisotropy (Δε) data were acquired as a novel indicator of the vertical clustering of COF resulting from vertical compressional strain within the dome. The Δε values were found to exhibit a general increase with depth, but with fluctuations over distances in the order of 10–10 2 m. In addition, significant decreases in Δε were found to be associated with depths corresponding to three major glacial to interglacial transitions. These changes in Δε are ascribed to variations in the deformational history caused by dislocation motion occurring from near-surface depths to deeper layers. Fluctuations in Δε over distances of less than 0.5 m exhibited a strong inverse correlation with Δε at depths greater than approximately 1200 m, indicating that they were enhanced during the glacial-interglacial transitions. The Δε data also exhibited a positive correlation with the concentration of chloride ions and an inverse correlation with the amount of dust particles in the ice core at greater depths corresponding to decreases in the degree of c axis clustering. Finally, we found that fluctuations in Δε persisted to approximately 80 % of the total depth of the ice sheet. These data suggest that the factors determining the deformation of ice include the concentration of chloride ions and the amount of dust particles, and that the layered contrast associated with the COF is preserved all the way from the near-surface to a depth corresponding to approximately 80 % of the thickness of the ice sheet. These findings provide important implications regarding further development of the COF under the various stress-strain configurations that the ice will experience in the deepest region, approximately 20 % of the total depth from the ice/bed interface. [ABSTRACT FROM AUTHOR]

Records of chemical impurities from ice cores enable us to reconstruct the past deposition of aerosols onto polar ice sheets and alpine glaciers. Through this they allow us to gain insight into changes of the source, transport and deposition processes that ultimately determine the deposition flux at the coring location. However, the low concentrations of the aerosol species in the ice and the resulting high risk of contamination pose a formidable analytical challenge, especially if long, continuous and highly resolved records are needed. Continuous flow analysis, CFA, the continuous melting, decontamination and analysis of ice-core samples has mostly overcome this issue and has quickly become the de facto standard to obtain high-resolution aerosol records from ice cores after its inception at the University of Bern in the mid-1990s. Here, we present continuous records of calcium (Ca2+), sodium (Na+), ammonium (NH4+), nitrate (NO3-) and electrolytic conductivity at 1 mm depth resolution from the NGRIP (North Greenland Ice Core Project) and NEEM (North Greenland Eemian Ice Drilling) ice cores produced by the Bern Continuous Flow Analysis group in the years 2000 to 2011. Both of the records were previously used in a number of studies but were never published in full 1 mm resolution. Alongside the 1 mm datasets we provide decadal averages, a detailed description of the methods, relevant references, an assessment of the quality of the data and its usable resolution. Along the way we will also give some historical context on the development of the Bern CFA system. The data is available in full 1 mm and 10-year-averaged resolution on PANGAEA (https://doi.org/10.1594/PANGAEA.935838 ,) [ABSTRACT FROM AUTHOR]

Records of chemical impurities from ice cores enable us to reconstruct the past deposition of aerosols onto the polar ice sheets and alpine glaciers. Through that, they allow us to gain insight into changes of the source, transport and deposition processes that ultimately determine the deposition flux at the coreing location. However, the low concentrations of the aerosol species in the ice and the resulting high risk of contamination poses a formidable analytical challenge, especially if long, continuous and highly resolved records are needed. Continuous Flow Analysis, CFA, the continuous melting, decontamination and analysis of ice-core samples has mostly overcome this issue and has quickly become the de-facto standard to obtain high-resolution aerosol records from ice cores after its inception at the University of Bern in the mid 90s. Here we present continuous records of calcium (Ca2+), sodium (Na+), ammonium (NH4+), nitrate (NO3−1) and electrolytic conductivity at 1 mm depth resolution from the NGRIP (North Greenland Ice Core Project) and NEEM (North Greenland Eemian Ice Drilling) ice cores produced by the Bern Continuous Flow Analysis group in the years 2000 to 2011. Both of the records have previously been used in a number of studies but have never been published in the full 1 mm resolution. Alongside the 1 mm datasets we provide decadal averages, a detailed description of the methods, relevant references, an assessment of the quality of the data and its usable resolution. Along the way we will also give some historical context on the development of the Bern CFA system. [ABSTRACT FROM AUTHOR]

Our study is the first to demonstrate a high-temporal-resolution record of mineral composition in a Greenland ice core over the past 100 years. To reconstruct past variations in the sources and transportation processes of mineral dust in northwestern Greenland, we analysed the morphology and mineralogical composition of dust in the SIGMA-D ice core from 1915 to 2013 using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS). The results revealed that the ice core dust consisted mainly of silicate minerals and that the composition varied substantially on multi-decadal and inter-decadal scales, suggesting that the ice core minerals originated from different geological sources in different periods during the past 100 years. The multi-decadal variation trend differed among mineral types. Kaolinite, which generally formed in warm and humid climatic zones, was abundant in colder periods (1950–2004), whereas mica, chlorite, feldspars, mafic minerals, and quartz, which formed in arid, high-latitude, and local areas, were abundant in warmer periods (1915–1949 and 2005–2013). Comparison to Greenland surface temperature records indicates that multi-decadal variation in the relative abundance of these minerals was likely affected by local temperature changes in Greenland. Trajectory analysis shows that the minerals were transported mainly from the western coast of Greenland in the two warming periods, which was likely due to an increase in dust sourced from local ice-free areas as a result of shorter snow/ice cover duration in the Greenland coastal region during the melt season caused by recent warming. Meanwhile, ancient deposits in northern Canada, which were formed in past warmer climates, seem to be the best candidate during the colder period (1950–2004). Our results suggest that SEM–EDS analysis can detect variations in ice core dust sources during recent periods of low dust concentration. [ABSTRACT FROM AUTHOR]

Our study is the first to demonstrate a high-temporal-resolution record of mineral composition in a Greenland ice core over the past 100 years. To reconstruct the past variations in the sources and transportation processes of mineral dust in northwestern Greenland, we analyzed the morphology and mineralogical composition of dust in an ice core from 1915 to 2013 using Scanning Electron Microscopy (SEM) and Energy-Dispersive X-ray Spectroscopy (EDS). Analysis of the SEM-EDS reveals that the ice core dust mainly consisted of silicate minerals and the composition varied substantially on multi-decadal and inter-decadal scales, suggesting that the geological origin of the ice core minerals changed periodically during the past 100 years. The multi-decadal variation trend differed among mineral types: kaolinite generally formed in low- or middle-latitude areas were abundant in the colder periods (1950 to 2000), whereas mica, chlorite, feldspars, mafic minerals, and quartzes formed in arid, high-latitude, and local areas were abundant in the warmer periods (1915 to 1949 and 2005 to 2013). This indicates that the multi-decadal variation of the relative abundance of the minerals can be attributed to the local temperature changes in Greenland. The trajectory analysis shows that the minerals were mainly transported from the western coast of Greenland in the two warming periods, which was likely due to an increase of dust sourced from local ice-free areas. On the other hand, the abundant kaolinite was likely derived from old sediments at higher latitudes in North America, rather than from low and middle latitudes. [ABSTRACT FROM AUTHOR]

Air in polar ice cores provides unique information on past climatic and atmospheric changes. We developed a new method combining wet extraction, gas chromatography and mass spectrometry for high-precision, simultaneous measurements of eight air components (CH4 , N2O and CO2 concentrations; δ 15N , δ 18O , δ O2/N2 and δ Ar/N2 ; and total air content) from an ice-core sample of ∼ 60 g. The ice sample is evacuated for ∼ 2 h and melted under vacuum, and the released air is continuously transferred into a sample tube at 10 K within 10 min. The air is homogenized in the sample tube overnight at room temperature and split into two aliquots for mass spectrometric and gas chromatographic measurements. Care is taken to minimize (1) contamination of greenhouse gases by using a long evacuation time, (2) consumption of oxygen during sample storage by a passivation treatment on sample tubes, and (3) fractionation of isotopic ratios with a long homogenization time for splitting. Precision is assessed by analyzing standard gases with artificial ice and duplicate measurements of the Dome Fuji and NEEM ice cores. The overall reproducibility (1 SD) of duplicate ice-core analyses are 3.2 ppb , 2.2 ppb and 2.9 ppm for CH4 , N2O and CO2 concentrations; 0.006 ‰, 0.011 ‰, 0.09 ‰ and 0.12 ‰ for δ 15N , δ 18O , δ O2/N2 and δ Ar/N2 ; and 0.63 mLSTPkg-1 for total air content, respectively. Our new method successfully combines the high-precision, small-sample and multiple-species measurements, with a wide range of applications for ice-core paleoenvironmental studies. [ABSTRACT FROM AUTHOR]

Air in polar ice cores provides various information on past climatic and atmospheric changes. We developed a new method combining wet extraction, gas chromatography and mass spectrometry, for high-precision, simultaneous measurements of eight air components (CH4, N2O and CO2 concentrations, δ15N, δ18O, δO2/N2, δAr/N2 and total air content) from an ice core sample of ~60g. The ice sample is evacuated for ~2 hours and melted under vacuum, and the released air is continuously transferred into a sample tube at 10K within 10 minutes. The air is homogenized in the sample tube overnight at room temperature, and split into two aliquots for mass spectrometric and gas chromatographic measurements. Cares are taken to minimize contamination of greenhouse gases with long evacuation time, consumption of oxygen during sample storage by passivation treatment on sample tubes, and fractionation of isotopic ratios with long homogenization time for splitting. Precisions are assessed by analysing standard gases with artificial ice, and by duplicate measurements of the Dome Fuji and NEEM ice cores. The overall reproducibility (one standard deviation) from duplicate ice-core analyses are 3.2ppb, 2.2ppb and 3.1ppm for CH4, N2O and CO2 concentrations, 0.006, 0.010, 0.09 and 0.12‰ for δ15N, δ18O, δO2/N2 and δAr/N2, and 0.67mlSTPkg-1 for total air content, respectively. Our new method successfully combines the high-precision, small-sample and multiple-species measurements, with a wide range of applications for ice-core paleoenvironmental studies. [ABSTRACT FROM AUTHOR]