1. 金属有机框架衍生钛酸锂及其电化学性能研究.
- Author
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陈川, 钱森, 丁 一, 姚天浩, 郭经红, and 王红康
- Abstract
Lithium titanate (Li Ti5 ()I2) is a promising anode material due to its unique features of uzero strain" and high charge and discharge platform. However? its intrinsic low electron and ion conductivity bring severe polarization to Lid Tir)()I2 upon charge/discharge. With the objective of solving the as-mentioned issues? in this paper? a facile synthesis route of metal-organic framework derived porous Lii Ti()12 was presented via solvothermal and calcination. When tested as an anode material for lithium-ion battery? it delivered high stability (120.3 mAh/g at ().5 A/g after 700 cycles) as well as rate performance (67.4 mAh/g at 2 八/g),and the polarization decreased with the cycles going on. The excellent electrochemical performance could be ascribed to more active sites and shortened ion diffusion path provided by the porous structure derived from metal-organic framework. The structural changed during cycles offered better electron and ion transfer kinetics? therefore? leading to low polarization. More importantly,this preparation method may also be applied for other Ti-based anode materials (such as TiNb NavTiO; etc.). [ABSTRACT FROM AUTHOR]
- Published
- 2020
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