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The Shuangjianzishan vein-type Ag-Pb-Zn deposit in the southern Great Xing'an Range (GXR), NE China, is hosted in the slate of the Lower Permian Dashizhai Formation intruded by granite porphyry. In this paper, U–Pb zircon ages and bulk-rock and isotope (Sr, Nd, Pb and Hf) compositions are reported to investigate the derivation, evolution and geodynamic setting of this granite porphyry. It is closely associated with Pb-Zn-Ag mineralization in the southern GXR and contains important geological information relating to regional tectonic evolution. Laser ablation – inductively coupled plasma – mass spectrometry (LA-ICP-MS) zircon U–Pb dating yields an emplacement age of 131 ± 1 Ma for the granite porphyry. Bulk-rock analyses show that the Shuangjianzishan granite porphyry is characterized by high Si, Na and K contents but low Mg and Fe contents, and that the enrichment of Zr, Y and Ga suggests an A-type granite affinity. Most of the studied samples have relatively low 87Sr/86Sr values (0.70549–0.70558), with positive ϵNd(t) (0.71–0.88) and ϵHf(t) (4.9–6.9) values. The Sr–Nd isotope modelling results, in combination with the young TDM2 ages of Nd and Hf (850–864 and 668–778 Ma, respectively), reveal that the Shuangjianzishan granite porphyry may be derived from the melting of mantle-derived juvenile component, with minor lower crustal components; this finding is also supported by Pb isotopic compositions. Considering the widespread presence of granitoids with coeval volcanic rocks and regional geology data, we propose that the Shuangjianzishan granite porphyry formed in a post-orogenic extensional environment related to the upwelling of asthenospheric mantle following the closure of the Mongol–Okhotsk Ocean. [ABSTRACT FROM AUTHOR]

The Liziyuan goldfield is located along the northern margin of the western part of the Qinling Orogen (WQO). The goldfield consists of five gold-only deposits hosted by metavolcanic rocks, and one polymetallic (Au–Ag–Pb) deposit hosted by the Tianzishan Monzogranite. As the Liziyuan goldfield appears to be spatially and temporally related to the Jiancaowan Porphyry, the study of the deposit provides a crucial insight into the relationship between tectonic-magmatic events and gold metallogenesis in the WQO. In this paper, we present whole-rock major and trace element geochemistry, and in situ zircon U–Pb and Lu–Hf isotopic data from the Tianzishan Monzogranite and Jiancaowan Porphyry. The two granitic plutons are enriched in LILEs and LREEs, depleted in HFSEs and have zircon εHf(t) values between −14.1 and −5.1 for the Tianzishan Monzogranite and between −21.0 and −8.4 for the Jiancaowan Porphyry. These characteristics indicate that the granites are derived from the crust. The Tianzishan Monzogranite has LA-ICP-MS zircon U–Pb ages of 256.1 ± 3.7 to 260.0 ± 2.1 Ma, which suggests that it was emplaced in the WQO during the convergence of the North and South (Yangtze) China cratons in the early stage of the Qinling Orogeny. In contrast, the porphyry has a LA-ICP-MS zircon U–Pb age of 229.2 ± 1.2 Ma, which is younger than the peak collision age, but corresponds to the widespread Late Triassic post-collisional granitic plutons in the WQO. The Tianzishan Monzogranite has somewhat higher Sr contents (196–631 ppm), lower Y (2.23–19.6 ppm) and Yb (0.20–2.01 ppm) contents, and a positive Eu/Eu* averaging 1.15. These characteristics suggest the pluton was derived from partial melting of the thickened crust. In contrast, the relatively higher MgO content (0.85–2.08 wt%) and Mg no. (43.4–58.2) of the Jiancaowan Porphyry indicates that insignificant amounts of subcontinental lithospheric mantle-derived mafic melts were involved in the generation of the magma. The Liziyuan goldfield is hosted by faults in greenschist-facies metamorphic rocks. Fluid inclusion studies suggest that gold was precipitated from CO2-rich, low-salinity and medium temperature fluids. This feature is consistent with the other orogenic gold deposits throughout the world. The field relationships and zircon U–Pb ages of the two granitic plutons suggest that gold mineralization is coeval with or slightly younger than the emplacement of the Jiancaowan Porphyry. Therefore, both the porphyry and deposit formed during the post-collisional stage of the Qinling Orogen. [ABSTRACT FROM PUBLISHER]

Middle Neoproterozoic igneous rocks are widespread in South China, but their petrogenesis and tectonic implications are still highly controversial. The Guangfeng middle Neoproterozoic volcani-sedimentary succession was developed on a rare Sibaoan metamorphic basement (the Tianli Schists) in the southeastern Yangtze Block, South China. This paper reports geochronological, geochemical and Nd isotopic data for the volcanic rocks in this succession. The volcanic rocks consist of alkaline basalts, andesites and peraluminous rhyolites. SHRIMP U-Pb zircon age determinations indicate that they were erupted at 827 ± 14 Ma, coeval with a widespread episode of anorogenic magmatism in South China. Despite showing Nb-Ta depletion relative to La and Th, the alkaline basalts are characterized by highly positive ϵNd(T) values (+3.1 to +6.0), relatively high TiO2 and Nb contents and high Zr/Y and super-chondritic Nb/Ta ratios, suggesting their derivation from a slab melt-metasomatized subcontinental lithospheric mantle source in an intracontinental rifling setting. The andesites have significantly negative ϵNd(T) values (-9.3 to -11.1) and a wide range of SiO2 contents (57.6-65.6 %). They were likely generated by the mixing of fractionated basaltic melts with felsic melts derived from the Archaean metasedimentary rocks in the middle to lower crust. The rhyolites are highly siliceous and peraluminous. They are characterized by depletion in Nb, Ta, Sr, P and Ti and relatively high ϵNd(T) values (-3.0 to -4.8), broadly similar to those of the adjacent c. 820 Ma peraluminous granitoids derived from the Mesoproterozoic to earliest Neoproterozoic sedimentary source at relatively shallow levels. We conclude that the Guangfeng volcanic suite is a magmatic response of variant levels of continental lithosphere (including lithospheric mantle and the lower-middle to upper crust) to the middle Neoproterozoic intracontinental rifling possibly caused by mantle plume activity. [ABSTRACT FROM AUTHOR]

Typical ophiolitic rock assemblages such as siliciclastic rocks, basalts and gabbros, together with the subduction-related intermediate-acidic intrusive rocks, are newly discovered in the Tongjiang-Fuyuan area of the Heilongjiang Provence, NE China. To determine the formation age and genesis of the mafic rocks (basalts and gabbros) and intermediate-acidic intrusive rocks (granodiorites) in the area, as well as their geodynamic settings, the whole-rock geochemical analysis and zircon LA-ICP-MS U-Pb dating were carried out. Zircon U-Pb results suggest that the granodiorites are 93–95 Ma and gabbro is 95 Ma, respectively. Geochemical results show that the gabbros and basalts exhibit characteristics of ocean island basalt (OIB) affinity and are typically related to having originated from mantle plumes. While the granodiorites show the nature of the island-arc magmatic rocks and may originate from the lower crust. Based on the coeval igneous rock associations and regional tectonic evolution, we conclude that the late Cretaceous magmatic rocks in the Tongjiang-Fuyuan area are the product of continuous subduction of the Palaeo-Pacific plate and reflect the subduction rollback process of the Palaeo-Pacific plate. [ABSTRACT FROM AUTHOR]

The provenance and tectonic setting of the Lower–Middle Triassic clastic sediments from the Napo basin, South China, have been examined here using detrital modes, whole-rock geochemistry and detrital zircon U–Pb ages. Field investigations indicate that these sediments consist of fan delta, slope and turbidity fan facies with dominantly southward palaeocurrent directions. Detrital modes and geochemical characteristics of the clastic rocks indicate that they were derived from mixed magmatic arc and Palaeozoic successions in a continental island arc setting, with no significant sediment recycling. The U–Pb age spectra of sandstone detrital zircons from different stratigraphic positions are similar, with one major group (300–230 Ma), two subordinate groups (400–320 Ma and 480–420 Ma, respectively) and two scattered groups (1200–800 Ma and 2000–1700 Ma, respectively). Thus, we consider that the north late Permian – Middle Triassic volcanic rocks and the uplifted Palaeozoic sedimentary/volcanic sequences constituted the predominant sources. The detritus derived from the late Permian Emeishan mafic rocks is subordinate and limited. The pre-Devonian zircons are likely sedimentary-recycled or magmatic-captured instead of directly derived from the early Palaeozoic orogen (e.g. Yunkai massif) and Neoproterozoic Jiangnan orogen because of the topographic barrier of a magmatic arc and carbonate platform. Considering the spatial and temporal distribution characteristics of the volcanic arc and ophiolite, we suggest that the Triassic Napo basin was a fore-arc basin within a continental island arc setting, which developed in response to the northward subduction of the Babu–Cao Bang branch ocean beneath the South China Block. [ABSTRACT FROM AUTHOR]

The widespread occurrence of late Mesozoic volcanic rocks in SE China is associated with widespread mineralization. Most geologists have accepted the model of Pacific plate subduction beneath the eastern Asian continent, but there are still controversies, especially the initial timing of the tectonic transition. In order to understand the tectonic evolution of the palaeo-Pacific plate subduction, an integrated study of zircon U–Pb, Lu–Hf isotope compositions and whole-rock geochemistry was carried out for Mesozoic volcanic rocks in eastern Fujian Province. According to the field observations and zircon U–Pb ages, these volcanic rocks can be divided into three phases: an early stage of Late Jurassic volcanic rocks (Phase 1, 159–153 Ma), a late stage of Late Jurassic volcanic rocks (Phase 2, 152–146 Ma) and an early stage of Early Cretaceous volcanic rocks (Phase 3, 143–139 Ma). Overall, these volcanic rocks are composed of intermediate–acid pyroclastic rocks and lava, with high SiO2, Na2O, K2O and Al2O3 contents, belonging to the high-K calc-alkaline and peraluminous series, with enrichment in large ion lithophile and light rare earth elements but depletion in high-field-strength elements and heavy rare earth elements. However, the Phase 1 and 2 volcanic rocks contain different zircon Hf isotopic compositions and whole-rock geochemistry to the Phase 3 volcanic rocks, implying that they have a different petrogenesis. Our study combined with previous research shows that the decreasing zircon ϵHf(t) values of the Middle–Late Jurassic volcanic rocks indicate a decreasing mantle-derived material contribution. On the contrary, the majority of the Early Cretaceous volcanic rocks have variable ϵHf(t) values, requiring varied degrees of involvement of juvenile components in their origin. Thus, we consider that the Late Jurassic volcanic rocks were generated in a compressional tectonic environment during the early stage (> 146 Ma) of palaeo-Pacific subduction. In contrast, the Cretaceous volcanic rocks were formed in an extensional tectonic setting during a later stage (< 143 Ma) of subduction. [ABSTRACT FROM AUTHOR]

The Yangtze Block in South China constitutes an important Precambrian landmass in the present East Asian continent. The Neoproterozoic sedimentary successions of the Hengdan Group in the NW Yangtze Block record essential information for deciphering the Neoproterozoic tectonics along the NW margin. However, its depositional age, provenance and tectonic properties remain uncertain. Here, a combined analysis of detrital zircon U–Pb dating and geochemistry is performed on representative samples from the Hengdan Group. Concordant dating results of samples from the bottom and upper parts constrain the maximum depositional age at c. 720 Ma. Detrital zircon age patterns of samples reveal a uniformly pronounced age peak at c. 915–720 Ma, which is consistent with the magmatic pulses in domains at the NW end of the Yangtze Block. In addition, these samples display left-sloping post-Archaean Australian shale (PAAS)-normalized rare-earth element patterns and variable trace element patterns, resembling sediments accumulated in a basin related to an active continental margin geodynamic setting. Provenance analysis reveals that the main sources featured intermediate to felsic components, which experienced rapid erosion and sedimentation. These integrated new investigations, along with previous compilations, indicate that the Hengdan Group might have been deposited in a fore-arc basin controlled by subduction beneath the Bikou Terrane. Thus, such interpretation further supports proposals for subduction-related tectonics along the western margin of the Yangtze Block during the early Neoproterozoic. [ABSTRACT FROM AUTHOR]

The Duobagou Permian–Triassic granites of the Dunhuang orogenic belt are of great importance in understanding the tectonic evolution of the southernmost Central Asian Orogenic Belt. LA-ICP-MS U–Pb zircon ages indicate that Permian–Triassic granitic intrusions from the Duobagou area formed at 276–274 Ma and 246 ± 1 Ma. These granites have high SiO2, Na2O and K2O, but low Al2O3, CaO and MgO contents and belong mainly to the high-K calc-alkaline I-type granite series. Based on whole-rock geochemistry and Sr–Nd and zircon Hf isotopes, the Duobagou Permian–Triassic granites were dominantly derived from the partial melting of lower continental crust formed during late Palaeoproterozoic to Mesoproterozoic times in a post-collisional extensional setting. Permian granites with zircon ϵHf(t) values of −5.4 to +3.1 and Hf model ages of TDM2 = 1.14–1.70 Ga indicate the involvement of a mantle component in their petrogenesis. Triassic granites with higher zircon ϵHf(t) values (+0.5 to +3.8) and TDM2 = 1.08–1.31 Ga suggest more juvenile sources caused by a greater contribution of mantle-derived melts, indicating a significant crustal growth. Regional extension from lithospheric delamination and heating from asthenospheric upwelling were proposed to have triggered the partial melting of lower crust, resulting in the generation of the Permian–Triassic magmatism. This may have been the mechanism for the significant crustal growth during Permian and Triassic times in the southernmost Central Asian Orogenic Belt. [ABSTRACT FROM AUTHOR]

The North Qilian orogenic belt in North China has been defined as a subduction–collision zone between the Alxa Block and the Qilian Block. We present petrography, zircon U–Pb geochronology, major- and trace-element geochemistry, and Sr–Nd–Pb–Hf isotope analysis for the Yushigou diabase from the Longshoushan area, which is located SW of the Alxa Block, aiming to understand its petrogenetic link to subduction processes. The Yushigou diabase belongs to the tholeiite series, and shows enrichment in light rare earth and large-ion lithophile elements, and a depletion in heavy rare earth and high-field-strength elements. Laser ablation – inductively coupled plasma – mass spectrometry U–Pb zircon dating yielded an emplacement age of 414 ± 9 Ma, with an ϵHf(t) value in the range of −10.3 to 1.8. The whole-rock initial 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios of the diabase range over 16.811–17.157, 15.331–15.422 and 37.768–37.895, respectively. The (87Sr/86Sr)i ratios vary between 0.7086 and 0.7106, and ϵNd(t) values vary between −14.4 and −13.4, which are significantly higher than the ϵHf(t) value (Nd–Hf decoupling). An interpretation of the elemental and isotopic data suggests that the Yushigou diabase was derived from partial melting of an enriched mantle I (EM-I) -type lithospheric mantle in the spinel–garnet transitional zone. Based on the geochemical features and previous regional geological data, we propose that the Silurian magmatism was most likely triggered by slab break-off after the closure of the North Qilian Ocean, and ancient continental materials from the subduction slab metasomatized the overlying lithospheric mantle during exhumation. [ABSTRACT FROM AUTHOR]

We report new U–Pb zircon age data, zircon in situ oxygen isotope, mineral chemistry, whole-rock geochemistry and Sr–Nd isotopic compositions from the Early Devonian ultrapotassic Gucheng pluton in the North China Craton, and discuss its petrogenesis. The Gucheng pluton is exposed in the northern part of the North China Craton and forms a composite intrusion, consisting of K-feldspar-bearing clinopyroxenite, clinopyroxene-bearing syenite and alkali-feldspar syenite. Mineral phases in these lithologies include clinopyroxene (Wo43–48En19–35Fs18–38), sanidine (An0Ab3–11Or89–97), and subordinate titanite, andradite and Na-feldspar. These rocks show homogeneous Sr but variable Nd isotopic compositions, and have relatively high zircon in situ oxygen isotopes (δ18O = 5.2–6.7). The Gucheng plutonic rocks formed through fractional crystallization and accumulation from ultrapotassic magmas, which were originated from partial melting of metasomatic vein systems in the subcontinental lithospheric mantle of the North China Craton. These vein networks developed as a result of the reactions of fluids derived from subducted pelitic sediments on the downgoing Palaeo-Asian ocean floor with the enriched, subcontinental lithospheric mantle peridotites. Sensitive high-resolution ion microprobe (SHRIMP) U–Pb zircon dating has revealed a crystallization age of 415 Ma for the timing of the emplacement of the Gucheng pluton that marks the early stages of alkaline magmatism associated with the Andean-type continental margin evolution along the northern edge of the North China Craton facing the Palaeo-Asian Ocean. [ABSTRACT FROM AUTHOR]

The Zhangguangcai Range in the Xing'an Mongolian Orogenic Belt, NE China, contains Early Jurassic (c. 188 Ma) Dabaizigou (DBZG) porphyritic dolerite. Compared with other island-arc mafic rocks, the DBZG dolerite is characterized by high trace-element contents, relatively weak Nb and Ta enrichments, and no Zr, Hf or Ti depletions, similar to OIB-type rocks. Analysed rocks have (87Sr/86Sr)i ratios of 0.7033–0.7044, relatively uniform positive ɛNd(t) values of 2.3–3.2 and positive ɛHf(t) values of 8.5–17.1. Trace-element and isotopic modelling indicates that the DBZG mafic rocks were generated by partial melting of asthenospheric mantle under garnet- to spinel-facies conditions. The occurrence of OIB-like mafic intrusion suggests significant upwelling of the asthenosphere in response to lithospheric attenuation caused by continental rifting. These processes occurred in an incipient continental back-arc environment in the upper plate of a palaeo-Pacific slab subducting W–NW beneath East Asia. [ABSTRACT FROM AUTHOR]

The North Qilian Orogenic Belt is on the northeastern margin of the Tibetan Plateau. It is connected with the Alxa Block in the north and the Tethyan orogenic assemblage in the south. The Lower Silurian Angzanggou Formation, deposited in the northern area of the North Qilian Orogenic Belt, is the most important for revealing the architecture and orogenic processes of the North Qilian Belt. Provenance analysis of the Angzanggou Formation can reveal not only the tectonic evolution of the central orogenic belt of China but also Palaeozoic Asia plate reconstructions. Petrographic analysis indicated that the compositional and textural maturity of the sandstones was low. The detrital composition of the Angzanggou Formation samples consists of quartz (8–14 %), feldspar (6–29 %) and lithic fragments (56–86 %). The sandstones could be classified as litharenites or feldspathic litharenites. The detrital modal composition suggests that these sandstones were probably deposited in a fore-arc basin. The element ratios and some discrimination diagrams based on geochemistry indicate that felsic and intermediate rocks were the main source rocks. The SiO2/Al2O3 ratio, the index of chemical variability and the Th/Sc versus Zr/Sc discrimination diagram suggest that the compositional maturity and degree of recycling were moderate to low. The index of alteration (CIA) and the A–CN–K diagram indicate the intensity of weathering was moderate. The discrimination diagrams based on major and trace elements and petrographic discrimination diagrams imply that the Angzanggou Formation rocks were derived from a continental island arc, and a sedimentary cover probably overlaid the volcanic arc. Therefore, we infer that during Early Silurian time the North Qilian Belt sediments accumulated in a fore-arc basin. [ABSTRACT FROM AUTHOR]

The Wulanba granite, consisting of biotite monzogranite and syenogranite, is located in the southern part of the Great Xing'an Range, NE China. Whole-rock major- and trace-element geochemistry suggests the Wulanba granite is a high-K–shoshonitic, slightly peraluminous and highly differentiated I-type granite. The Sr–Nd–Hf isotopes indicate that it originated from partial melting of juvenile crust derived from the depleted mantle with a minor input of old crust. The relatively young T2DM and tDM2 ages indicate it was most likely derived from a Late Neoproterozoic to Early Palaeozoic source. We have demonstrated that the biotite monzogranite is the ore-related intrusion of the Haobugao Zn–Fe mineralization based on the following geological, geochronological and geochemical evidence: (1) the chalcopyrite/pyrite in the biotite monzogranite and the continuous mineralization of drill core ZK2508; (2) the consistence of the emplacement age of the biotite monzogranite (~141–140/138 Ma) with the skarn mineralization age (~142 Ma); and (3) the presence of rich ore-forming elements (Fe–Zn–Cu) in the biotite monzogranite, and the similar Pb compositions of the sulfides from the Haobugao deposit and the biotite monzogranite. Compared to the barren syenogranite, the fertile biotite monzogranite is more oxidized, while the edges of the apatite grains in the biotite monzogranite are more oxidized than the centres. The average F/Cl ratio of the fertile biotite monzogranite (~123.45) is much higher than that of the barren syenogranite (~73.98). We conclude that these differences reflect unique geochemical signatures, and the geochemical composition of the apatite can be used to infer the economic potential of granites. [ABSTRACT FROM AUTHOR]

The Yuanjiacun banded iron formation (BIF) is hosted in lower Proterozoic metamorphic strata, and its structures are dominated by bands or streaks. Based on their differences in mineral compositions, the iron ores can be subdivided into haematite quartzite, magnetite quartzite, stilpnomelane magnetite quartzite and stilpnomelane haematite quartzite. The geochemical characteristics of the surrounding rocks show that the protoliths consisted of argillaceous and arenaceous sedimentary rocks. The predominant provenance was a high-maturity felsic sedimentary terrane. The absence of syn-depositional igneous rocks and the tectonic setting discrimination diagrams indicate that the Yuanjiacun BIF formed in a passive continental margin setting. Negligible terrigenous materials were involved in the precipitation of the Yuanjiacun BIF. The precipitation of the Yuanjiacun BIF was predominantly controlled by the mixing of seawater and hydrothermal fluids. Its metallogenic material originated from the leaching of mafic oceanic crust by hydrothermal fluids. The observed Ce anomaly deficiency and heavy Fe isotope enrichment indicate that the Yuanjiacun BIF formed in an anoxic marine environment. In a redox-stratified palaeo-ocean, the Yuanjiacun BIF formed in reducing seawater below the oxidation–reduction transition zone. The Si and O isotope compositions of quartz suggest that the formation of the Yuanjiacun BIF was closely related to submarine hydrothermal activity. The Si and Fe erupted from the seafloor and precipitated by supersaturation and biological oxidation under anoxic conditions, respectively. [ABSTRACT FROM AUTHOR]

The Steptoean Positive Carbon Isotope Excursion (SPICE) is globally distributed in late Cambrian sedimentary records but controversially heterogeneous in its magnitudes. Here we use multiple geochemical proxies to investigate the late Cambrian carbonates from the Tangwangzhai section in North China, which were deposited in a shallow coastal environment with three depositional sequences (S1–S3). Each sequence comprises a transgressive systems tract (TST) and a highstand systems tract (HST). The REE + Y and trace element records are consistent with the depositional condition and indicate that terrigenous influence was more significant in the TST than HST. δ13Ccarb and δ34SCAS are low in the TST relative to HST, consistent with the scenario that terrigenous inputs were profoundly aggressive to seawater by introducing 13C-depleted and 34S-depleted materials. Within the TST of S2, the SPICE excursion shows a scaled-down δ13Ccarb positive shift (∼1.7 ‰) relative to its general records (∼4–6 ‰); the corresponding δ34SCAS show no positive excursion. This 'atypical' SPICE record is attributed to enhanced 13C-depleted and 34S-depleted terrigenous influence during the TST, which would reduce the amplitude of δ13Ccarb excursion, and even obscure δ34SCAS excursion. Meanwhile the subaerial unconformity at the base of TST would also cause a partially missing and a 'snapshot' preservation. Our study confirms significant local influence to the SPICE records, and further supports the heterogeneity and low sulphate concentrations of the late Cambrian seawater, because of which the SPICE records may be vulnerable to specific depositional conditions (e.g. sea-level, terrigenous input). [ABSTRACT FROM AUTHOR]

The Hudesheng mafic–ultramafic intrusions are located in the Oulongbuluke Block, north of the Qaidam Block in Qinghai Province, NW China. We carried out a detailed study of the intrusions, including field observations, petrology, zircon U–Pb geochronology, Lu–Hf isotopes, bulk-rock major- and trace-element geochemistry, and mineral compositions, to provide a better understanding of their properties and the regional tectonic evolution. Zircon U–Pb dating on gabbro and pyroxenite samples yielded ages of 465 and 455 Ma, respectively. Geochemical data, in conjunction with the field observations and petrological features, suggest that the complex is Alaskan-type and the magma was derived from a depleted mantle source that was hydrous picritic basalt in composition and influenced by crustal contamination and slab-derived fluid metasomatism. Based on all the chronological, petrological, mineralogical and geochemical and regional geological data, we conclude that the palaeo-ocean closed diachronously from west to east between the Qaidam and Oulongbuluke blocks, and that the ocean in the east of the North Qaidam region closed after ∼455 Ma. [ABSTRACT FROM AUTHOR]

Geochronological, elemental and isotopic data of the Dashizhuzi granites and lamprophyre dykes from the eastern Hebei – western Liaoning on the northern North China Craton (NCC) provide an insight into the nature of their magma sources and subcontinental lithospheric mantle. The Dashizhuzi granites have an emplacement age of 226 Ma. They have enriched lithospheric mantle type 1 (EM1-like) Sr–Nd isotopic compositions, and have distinctive features of high Na2O and Sr and low Y with high Sr/Y and (La/Yb)N ratios. These characteristics show that the Dashizhuzi granites originated directly from melting of mafic lower crust composed of pre-existing ancient crustal and enriched mantle-derived juvenile crustal materials at normal continental crustal depth of 33–40 km. The lamprophyre dykes are dated at 167 Ma, and can be divided into two groups. The Group 1 dykes have variable Sr–Nd isotopic compositions and mid-ocean-ridge basalt (MORB-) like Th/U, Ba/Th and Ce/Pb ratios, whereas the Group 2 dykes have enriched Sr–Nd isotopic compositions and notable high Co, Cr, MgO and low Al2O3 characteristics. These distinctive features suggest that the Group 1 dykes were derived from a relatively fertile lithospheric mantle source (garnet-facies amphibole-bearing lherzolite) which has experienced variable degrees of asthenospheric mantle-derived melt–peridotite interaction prior to melting. However, the Group 2 dykes were derived from an ancient garnet-facies phlogopite and/or amphibole-bearing lherzolite lithospheric mantle. Thinning of the Early Mesozoic lithospheric mantle beneath the northern NCC is dominantly through melt–peridotite interaction and thermo-mechanical erosion prior to Middle Jurassic time. The chemical compositions have been modified at the bottom of the lithospheric mantle through melt–peridotite interaction processes. [ABSTRACT FROM AUTHOR]

We report two newly identified Ordovician ophiolite belts in west Junggar, NW China: Tajin–Tarbahatai–Kujibai–Honguleleng (TTKH) and Tangbale–Baijiantan–Baikouquan (TBB) ophiolitic belts. These two ophiolitic belts provide constraints for the Palaeozoic reconstruction of Central Asia and the geological evolution of this region. The TTKH and TBB ophiolitic belts are dismembered parts of different ophiolitic belts which represent relics of Ordovician oceanic floor; they subducted to the north under the Chingiz–Tarbahatai arc and to the south under the Junggar plate, respectively. The Baijiantan–Baikouquan ophiolite mélanges comprise the major part of the TBB. Flat rare Earth element (REE) patterns with positive Eu anomalies and insignificant depletion of high-field-strength elements (HFSE) relative to melts of primitive mantle suggest a mid-ocean-ridge basalt (MORB) origin for the metagabbro. Lherzolite samples define a Sm–Nd isotopic isochron with age of 474 Ma and ɛNd(t) of +8.9. Lherzolite samples with positive ɛNd(t) values of +8.8 to +9.1 and initial 87Sr/86Sr ratios of 0.7037–0.7040 are rather homogeneous in Sr–Nd isotopic composition, whereas metagabbro samples show wider Sr–Nd isotopic compositional ranges with ɛNd(t) of +5.9 to +11.0. The Sm–Nd isotopic isochron age (c. 380 Ma) for garnet amphibolite samples, consistent with a zircon U–Pb age (c. 385 Ma) for metagabbro, represents a magmatic event prior to subduction. Thermodynamic calculations for garnet amphibolite yield a clockwise pressure–temperature path with peak metamorphic condition of c. 15 kbar and 520–560°C at 342 Ma, indicating a subduction-channel setting. The Rb–Sr isochron ages (335 Ma, 333 Ma) for metagabbro represent a metamorphic event during exhumation. [ABSTRACT FROM AUTHOR]

The Chehugou granite-hosted molybdenum deposit is typical of the Xilamulun metallogenic belt, which is an important Mo–Ag–Pb–Zn producer in China. A combination of major and trace element, Sr and Nd isotope, and zircon U–Pb isotopic data are reported for the Chehugou batholith to constrain its petrogenesis and Mo mineralization. The zircon SIMS U–Pb dating yields mean ages of 384.7 ± 4.0 Ma and 373.1 ± 5.9 Ma for monzogranite and syenogranite and 265.6 ± 3.5 Ma and 245.1 ± 4.4 Ma for syenogranite porphyry and granite porphyry, respectively. The Devonian granites are calc-alkaline with K2O/Na2O ratios of 0.44–0.52, the Permian granites are alkali-calcic with K2O/Na2O ratios of 1.13–1.25, and the Triassic granites are calc-alkaline and alkali-calcic rocks with K2O/Na2O ratios of 0.78–1.63. They are all enriched in large-ion lithophile elements (LILEs) and depleted in high-field-strength elements (HFSEs) with negative Nb and Ta anomalies in primitive mantle-normalized trace element diagrams. They have relatively high Sr (189–1256 ppm) and low Y (3.87–5.43 ppm) concentrations. The Devonian granites have relatively high initial Sr isotope ratios of 0.7100–0.7126, negative ɛNd(t) values of −12.3 to −12.4 and 206Pb/204Pb ratios of 16.46–17.50. In contrast, the Permian and Triassic granitoids have relatively low initial 87Sr/86Sr ratios (0.7048–0.7074), negative ɛNd(t) values of −10.1 to −13.1 and 206Pb/204Pb ratios of 17.23–17.51. These geochemical features suggest that the Devonian, Permian and Triassic Chehugou granitoids were derived from ancient, garnet-bearing crustal rocks related to subduction of the Palaeo-Asian Ocean and subsequent continent–continent collision between the North China and Siberian plates. [ABSTRACT FROM AUTHOR]

The Quanzhou (QZ) and Huacuo (HC) gabbro–granite complexes on the southeast coast of Fujian, South China, are important components of a Late Mesozoic calc-alkaline volcanic–plutonic belt in the region. The complexes provide an excellent opportunity to investigate the genetic relationships between acid and basic magmas, and their interactions within the intrusive environment. The complexes are composed mainly of monzogranite and biotite granodiorite in the QZ complex, and biotite granite in the HC complex, with lesser amounts of hornblende gabbro. Zircon U–Pb dating provides consistent crystallization ages of 109 ± 1 Ma and 108 ± 1 Ma for the QZ gabbros and monzogranites, and an age of 111 ± 1 Ma for the HC gabbro, which is contemporaneous with the spatially associated HC granites. Both the mafic and felsic intrusions in these complexes are enriched in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs), and are depleted in high-field-strength elements (HFSEs; e.g. Nb and Ta). They show similarly homogeneous Sr–Nd isotopic compositions. All these factors indicate a close genetic relationship between the gabbroic and granitic rocks in the QZ and HC complexes. Although the enriched Sr–Nd isotopic signatures of the QZ and HC gabbros seemingly point to an enriched mantle source (EM-1), they have highly variable zircon Hf isotopic compositions, with εHf(t) values ranging from negative to positive (specifically –4.6 to +6.1 for the QZ gabbros and –4.8 to +11.6 for the HC gabbros). We interpret the parental basic magmas of these gabbros to have received contributions from a depleted mantle source and crustal components. Contributions from such a depleted mantle source resulted in the growth of juvenile basaltic lower crust, the partial melting of which generated the parental felsic magmas of the QZ and HC complexes. Furthermore, based on a synthesis of petrography, geochronology, elemental and isotopic geochemistry and tectonics, we propose that break-off and rollback of the Late Mesozoic subducted Palaeo-Pacific Plate triggered the upwelling of asthenospheric mantle below the coastal area of the South China Block, which induced extension of the overlying continental lithosphere, and finally initiated the large-scale Late Yanshanian magmatism in the study area. [ABSTRACT FROM PUBLISHER]

The Xiaofangshen mafic stock is a hornblende gabbroic body emplaced in the Faku dome of northern Liaoning within the continental interior of the North China-Mongolian plate. Zircon U-Pb SHRIMP dating yields an emplacement age of 241 ± 6 Ma. These gabbroic rocks exhibit strong enrichment in large ion lithophile elements (e.g. Th, U) and light REE, slightly negative Eu anomalies, and pronounced depletion in high field strength elements (e.g. Nb, Ta, Zr, Ti). They show a relatively narrow range of isotopic compositions with initial 87Sr/86Sr ratios of 0.7053 to 0.7055, ϵNd(t) values of +0.40 to +0.68 and zircon ϵHf(T) values from +5.0 to +7.4. These geochemical features suggest that they might have been derived from partial melting of a subduction-related metasomatized lithospheric mantle source, which is tectonically affiliated to the Xing-Meng orogenic belt. Combined with our previous geochronological dating on the predominantly granitic intrusions from the Faku dome, it is inferred that the northern Liaoning block has a tectonic affinity with the Phanerozoic accretionary orogenic belt. This revelation further leads to the proposition that the Chifeng-Kaiyuan fault likely represents the Mesozoic lithospheric boundary between the North China craton and the Xing-Meng orogenic belt in northern Liaoning. The Xiaofangshen gabbros, together with the Triassic mafic-ultramafic cumulates and granulite xenoliths and the Triassic alkaline intrusions within the continental interior of the newly amalgamated North China--Mongolian Plate, constitute an important post-orogenic to within-plate anorogenic magmatic province, in response to the continued magmatic underplating caused by lithospheric delamination and hot asthenosphere upwelling. [ABSTRACT FROM AUTHOR]

The Rutog granitic pluton lies in the Gangdese magmatic arc in the westernmost part of the Lhasa Terrane, NW Tibet, and has SHRIMP zircon U-Pb ages of c. 80 Ma. The pluton consists of granodiorite and monzogranite with SiO[sub2] ranging from 62 to 72 wt % and Al2 03 from 15 to 17 wt%. The rocks contain 2.33-4.93 wt% K[sub2]O and 3.42-5.52 wt% Na[sub2]O and have Na[sub2]O/K[sub2]O ratios of 0.74-2.00. Their chondrite-normalized rare earth element (REE) patterns are enriched in LREE ((La/Yb)n = 15 to 26) and do not show significant Eu anomalies (SEu = 0.68-1.15). On a primitive mantle-normalized trace element diagram, the rocks are rich in large ion lithophile elements (LILE) and poor in high field strength elements (HFSE), HREE and Y. Their Sr/Y ratios range from 15 to 78 with an average of 30. The rocks have constant initial [sup87]Sr/[sup86]Sr ratios (0.7045 to 0.7049) and slightly positive ϵ[subNd](t) values (+0.1 to +2.3), similar to I-type granites generated in an arc setting. The geochemistry of the Rutog pluton is best explained by partial melting of a thickened continental crust, triggered by underplating of basaltic magmas in a mantle wedge. The formation of the Rutog pluton suggests fiat subduction of the Neo-Tethyan oceanic lithosphere from the south. Crustal thickening may have occurred in the Late Cretaceous prior to the India-Asia collision. [ABSTRACT FROM AUTHOR]

The Neoproterozoic mafic rocks in western Hunan, South China, form a NNE-striking mafic rock belt for which outcrops are found predominantly in Guzhang, Qianyang and Tongdao. Samples from Qianyang and Tongdao yielded ion microprobe U-Pb zircon ages of 747 ± 18 Ma and 772 ± 11 Ma, respectively. The mafic rocks are geochemically divided into two subtypes. Ultramafic rocks from Tongdao are depleted in Nb and Ti, with decoupled Nd-Hf isotopes, and geochemical features similar to the c. 761 Ma mafic-ultramafic rocks from Longsheng, northern Guangxi. Their εNd(t) value is -2.91, implying an enriched mantle source. Alkaline mafic rocks from Qianyang and Guzhang have high values of TiQ2, total alkali, some high field strength elements and (La/Yb)N, and low Zr/Nb, LaiNb, Sm/Nd and 143Nd/144Nd ratios as well as coupled Nd-Hf isotopes. They are geochemically similar to ocean island basalts and show fractional crystallization of Fe-Ti oxides, olivine and pyroxene in the mafic magma. The c. 760 Ma mafic rocks in western Hunan may be the products of post-orogenic magmatism. After the Jinningian (Sibao) orogenic process, the upwelling of the deep asthenospheric mantle caused by the break-off and detachment of the subducted oceanic slab led to extension in the area. The extension might have taken place earlier in the Tongdao and Longsheng areas, which led to the partial melting of the lithospheric mantle that had been metasomatized during early oceanic subduction to generate a relatively large amount of sub-alkaline rocks. However, the less alkaline mafic rocks in Qianyang and Guzhang might have been generated in the relatively later stage of the extension, and may have resulted from a small degree of partial melting of the asthenospheric mantle. [ABSTRACT FROM AUTHOR]

Cretaceous mafic dykes in Fujian province, SE China provide an opportunity to examine the nature of their mantle source and the secular evolution of the Mesozoic lithospheric mantle beneath SE China. The mafic rocks have SiO2 ranging from 47.42 to 55.40 wt %, AI203 from 14.0 wt % to 20.4 wt %, CaO from 4.09 to 11.7 wt % and total alkaline (K2O+Na20) from 2.15 wt % to 6.59 wt %. Two types are recognized based on their REE and primitive mantle-normalized trace element patterns. Type-A is the dominant Mesozoic mafic rock type in SE China and is characterized by enrichment of light rare earth elements (LREE) ((La/Yb)n = 2.85-19.0) and arc-like trace element geochemistry. Type-P has relatively flat REE patterns ((La/Yb)n = 1.68-3.43) and primitive mantle-like trace element patterns except for enrichment of Rb, Ba and Pb. Type-A samples show EMII signatures on the Sr-Nd isotopic diagram, whereas type-P rocks have high initial 143Nd/144Nd ratios (0.5126-0.5128) relative to the type-A rocks (143Nd/144Nd = 0.5124-0.5127). The type-A rocks have 207Pb/204Pb ranging from 15.47 to 15.67 and 206Pb/204Pb from 18.26 to 18.52. All the type-A rocks show a negative correlation between 143Nd/144Nd and 206Pb/204Pb ratios and a positive relationship between 87Sr/86Sr and 206Pb/204Pb ratios, indicating mixing of a depleted mantle source and an EMII component. Geochemical modelling shows that the parental magmas were formed by 5-15 % partial melting of a spinel lherzolite, and contaminated by less than 1% melt derived from subducted sediment. The type-P magmas were derived from a mantle source unmodified by subduction components. The wide distribution of type-A dykes in SE China suggests that subduction-modified lithospheric mantle was extensive beneath the Cathaysia Block. Geochemical differences between Mesozoic and Cenozoic mafic rocks indicate that lithospheric thinning beneath SE China occurred in two episodes: firstly by heterogeneous modification by subducted components in early Mesozoic times, and later by chemical--mechanical erosion related to convective upwelling of the asthenosphere during Cenozoic times. [ABSTRACT FROM AUTHOR]