1. Efficient chemical stabilization of tannery wastewater pollutants in a single step process: Geopolymerization
- Author
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Giacomo Boldrini, Caterina Sgarlata, Isabella Lancellotti, Luisa Barbieri, Marco Giorgetti, Michela Ciabocco, Silvia Zamponi, Mario Berrettoni, and Cristina Leonelli
- Subjects
Tannery ,Alkali activation ,Leaching test ,Waste stabilization/solidification ,Chromium-containing liquor ,Environmental technology. Sanitary engineering ,TD1-1066 - Abstract
Abstract The treatment of tannery wastewaters is a complex task due to the complexity of the waste: a mixture of several pollutants, both anionic and cationic as well as organic macromolecules which are very hard to treat for disposal all together. Geopolymers are a class of inorganic binders obtained by alkali activation of aluminosilicate powders at room temperature. Such activation process leads to a cement like matrix that drastically decreases mobility of several components via entrapment. This process taking place in the matrix can be hypothesized to be the in-situ formation of zeolite structures. In this work we use a metakaolin based geopolymer to tackle the problem directly in an actual industrial environment. To obtain a geopolymer, the metakaolin was mixed with 10 wt% of wastewater added with sodium hydroxide and sodium silicate as activating solutions. This process allowed a rapid consolidation at room temperature, the average compressive strength was between 14 and 43 MPa. Leaching tests performed at different aging times confirm a high immobilization efficiency close to 100%. In particular, only the 0.008 and 2.31% of Chromium and Chlorides respectively are released in the leaching test after 7 months of aging.
- Published
- 2021
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