1. Local polarization and valence distribution in LaNiO3 / LaMnO3 heterostructures
- Author
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Yusuke Wakabayashi, Miho Kitamura, Masato Anada, Koji Horiba, Kazuki Nagai, Satoshi Sakaguchi, and Hiroshi Kumigashira
- Subjects
Diffraction ,Physics ,Valence (chemistry) ,biology ,Condensed matter physics ,Heterojunction ,Substrate (electronics) ,biology.organism_classification ,Condensed Matter::Materials Science ,Electric field ,Lanio ,Condensed Matter::Strongly Correlated Electrons ,Intensity (heat transfer) ,Perovskite (structure) - Abstract
The inside of the electrical double layer at perovskite oxide heterointerfaces is examined. Here, we report the local polarization and valence distribution in ${\mathrm{LaNiO}}_{3}$/${\mathrm{LaMnO}}_{3}$ and ${\mathrm{LaMnO}}_{3}$/${\mathrm{LaNiO}}_{3}$ bilayers on a ${\mathrm{SrTiO}}_{3}$ (001) substrate. Simultaneous measurements of two aspects of the structure are realized by using Bayesian inference based on resonant- and nonresonant-surface x-ray diffraction data. The results show that the average Mn valences are ${\mathrm{Mn}}^{3.12+}$ and ${\mathrm{Mn}}^{3.19+}$ for the two samples. The intensity of their local electric field is $\ensuremath{\sim}1$ GV/m and the direction of the field points from ${\mathrm{LaMnO}}_{3}$ to ${\mathrm{LaNiO}}_{3}$.
- Published
- 2021