1. Magnetic phase diagram for the mixed-valence Eu oxide EuTi1−xAlxO3 (0≤x≤1)
- Author
-
Ryo Kajihara, Toshiaki Saito, Kosuke Nishina, Eiji Wada, Shuto Koshikawa, Daisuke Akahoshi, Hideki Kuwahara, and Takuro Nagase
- Subjects
010302 applied physics ,Physics ,Valence (chemistry) ,Oxide ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Magnetic phase diagram ,01 natural sciences ,chemistry.chemical_compound ,Crystallography ,Ferromagnetism ,chemistry ,0103 physical sciences ,Antiferromagnetism ,Curie temperature ,Condensed Matter::Strongly Correlated Electrons ,0210 nano-technology ,Ground state ,Phase control - Abstract
We have investigated the magnetic properties of ${\mathrm{EuTi}}_{1\ensuremath{-}x}{\mathrm{Al}}_{x}{\mathrm{O}}_{3}$ with $0\ensuremath{\le}x\ensuremath{\le}1$ and established a detailed magnetic phase diagram. Substitution of ${\mathrm{Ti}}^{4+}$ with ${\mathrm{Al}}^{3+}$, which oxidizes magnetic ${\mathrm{Eu}}^{2+}$ $(J=7/2)$ into nonmagnetic ${\mathrm{Eu}}^{3+}$ $(J=0)$, turns the antiferromagnetic insulating ground state $(x=0)$ into the ferromagnetic (FM) insulating one $(0.10\ensuremath{\le}x\ensuremath{\le}0.50)$. The ${\mathrm{Eu}}^{2+}/{\mathrm{Eu}}^{3+}$ mixed valence is indispensable for the FM behavior. In $0.10\ensuremath{\le}x\ensuremath{\le}0.33$, the Curie temperature ${T}_{\mathrm{C}}$ has a plateau at $\ensuremath{\sim}4$ K, and the FM correlation is most enhanced around $x=0.25$. In $0.33\ensuremath{\le}x\ensuremath{\le}1,{\mathrm{Al}}^{3+}$ substitution suppresses the FM correlation due to the dilution of magnetic ${\mathrm{Eu}}^{2+}$ ions. Our present results would provide useful information for magnetoelectric phase control of ${\mathrm{EuTiO}}_{3}$-based compounds.
- Published
- 2017
- Full Text
- View/download PDF