1. H1NMR electron-nuclear cross relaxation in thin films of hydrogenated amorphous silicon
- Author
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G. Ganguly, D.E. Carlson, Tining Su, P. C. Taylor, Parameswar Hari, and David C. Bobela
- Subjects
Stretched exponential function ,Amorphous silicon ,Materials science ,Silicon ,Condensed matter physics ,Dangling bond ,Spin–lattice relaxation ,Order (ring theory) ,chemistry.chemical_element ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials ,chemistry.chemical_compound ,Paramagnetism ,chemistry ,Relaxation (physics) ,Condensed Matter::Strongly Correlated Electrons - Abstract
We investigate the spin-lattice relaxation of the dipolar order in $^{1}\mathrm{H}$ NMR in hydrogenated amorphous silicon $(a\text{\ensuremath{-}}\mathrm{Si}:\mathrm{H})$. We find that the relaxation is dominated by the cross relaxation between the hydrogen nuclei and the paramagnetic states. The relaxation is inhomogeneous, and can be described as a stretched exponential function. We proposed a possible mechanism for this relaxation. This mechanism applies to a rather broad range of paramagnetic states, including the deep neutral defects (dangling bonds), the light-induced metastable defects, the defects created by doping, and the singly occupied, localized band-tail states populated by light at low temperatures. The cross relaxation is only sensitive to the bulk spin density, and the surface spins have a negligible effect on the relaxation.
- Published
- 2007
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