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CdSe/CdS heterostructured nanocrystals with quasi-type-II band alignments provide an interesting platform for studying the photoluminescence (PL) blinking associated with their unique morphologies. By using simultaneous measurements of the PL intensity, lifetime, and polarization anisotropy, we reveal the role of the electron delocalization during the blinking of single CdSe/CdS dot-in-rods. We found that a significant change in the PL polarization anisotropy distinguishes between two kinds of charged excitons with different electron delocalizations. We report our observation of unique polarized PL blinking governed by the band alignments and the Coulomb interactions between the charges inside and outside the dot-in-rod. [ABSTRACT FROM AUTHOR]

We investigate photoluminescence (PL) spectra and dynamics of clean silicon photonic crystal nanocavities at 10 K. A sharp emission peak due to the nanocavity mode has the largest intensity when the energy of the nanocavity mode is equal to the emission energy of the electron-hole droplets (EHDs). Time-resolved PL spectroscopy indicates that the PL lifetime of the EHD is reduced to as short as 1.2 ns by the nanocavity mode. A careful analysis of the lifetimes indicates that the radiative recombination rate for EHD is enhanced by a factor of larger than 5 by the Purcell effect. [ABSTRACT FROM AUTHOR]

The photoluminescence (PL) lifetime and quantum yield (QY) of the two-photon cascade emission (TPCE) provide critical information for assessing the quality of optoelectronic devices. The QY of TPCE has been conventionally evaluated by second-order photon correlation, g(2), measurements under weak-excitation conditions in single nanocrystals (NCs). Here, we report that by measuring simultaneously both the g(2) and PL-decay curves, the QY of the TPCE can be determined even under strong-excitation conditions. With this technique, the effect of ionization on the QY of the TPCEs in single CdSe/ZnS NCs, which appears under strong-excitation condition, can be revealed. The obtained QYs were compared with the PL lifetime of the first and second photon emissions. We demonstrate that even for ionized NCs, the radiative recombination rates during TPCE are almost proportional to the product of the numbers of electrons and holes. [ABSTRACT FROM AUTHOR]

The sequential two-photon emission process known as biexciton cascade emission is a characteristic phenomenon that occurs in photoexcited semiconductor nanocrystals (NCs). This process occurs when a biexciton state is created in the NCs; thus, the occurrence of the process is related to the photoabsorption properties of the NCs. This paper presents a simple equation that connects the photoabsorption of single NCs and the biexciton cascade emission. The equation is found to be independent of the quantum yields of photoluminescence (PL). With this equation and using an analysis of second-order photon correlation, the absolute absorption cross section s of the single NCs can be evaluated, obtaining values on the order of 10-14cm². This analysis shows that ionization during PL blinking does not affect the validity of the relation, indicating that the evaluation of σ, based on the equation, is applicable for various NCs with unique structures. [ABSTRACT FROM AUTHOR]

The absorption spectrum represents an important aspect of single semiconductor nanocrystals (NCs), revealing the morphology and orientation of the NCs. By conducting quantitative photoluminescence excitation spectroscopy based on a single-photon counting method, we succeed in clarifying the absorption cross-section spectrum of neutral excitons in single CdSe/ZnS NCs. With the values of the absorption cross section, we reveal that the intensity saturation of the neutral-exciton emission can be explained by considering the Poisson statistics for incident photons and by the small quantum yield of the biexciton emission. We also evaluated quantitatively the biexciton emission contribution and the ionization rate of NCs that appear at increased incident photon fluxes. [ABSTRACT FROM AUTHOR]